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The results show that the Zn complex can be partially intercalated into the double helix of DNA due to the planarity of the benzimidazole ring and the bulky structure of the complex.

实验结果表明,由于配合物的八面体构型以及苯并咪唑环的平面性,其与DNA作用方式可能为部分插入。

Benzofuran skeleton is an important heterocyclic in nature exist in one of these compounds have bactericidal, antiviral, immunosuppressive agents, anti-cancer efficacy, it aroused great interest of scientists to carry out the in-depth research, so far has made costly results.

苯并呋喃骨架是自然界中存在的重要杂环之一,这些化合物具有杀菌、抗病毒、免疫抑制剂、抗癌等药效,因此激起科学家的浓厚兴趣而深入进行该方面的研究,迄今为止已取得了不菲的成绩。

Excited triplet state of [60]fullerene containing piperidinoxanthate dyad is at 690nm, which has lifetime of 23.7xs in Ar-saturated benzonitrile, whereas that ofparent C60 is at 750nm, with lifetime of 50s, indicating that excited triplet state of

富勒烯C_(60)哌啶黄原酸酯稠合体激发三线态的最大吸收峰在690nm,相对于纯C_(60)发生蓝移用532nm激光激发后,富勒烯C_(60)哌啶黄原酸酯稠合体激发三线态的最大吸收峰在690nm,相对于C_(60)的750nm发生蓝移,在氩气饱和的苯腈中寿命23.7μs,比C_(60)的55μs短,表明环加成反应连接的哌啶黄原酸酯部分具有吸电子性质。

The optimal separating condition of chromatography analysis was: Shimadzu VP-ODS 150mm4.6mm as chromatographic column; acetonitrile/water (12/88,V/V, Contained 1.25mmol/l phosphoric acid) as mobile phase with flow rate of 1.0ml/min. Macroporous ion exchange resins and activated carbon were applied to enrich the trace level impurities and the main impurities was determined by LC-MS and GC-MS.They were : Benzonitrile , 2-Methyl-8-hydroxyquinoline, 2,6-Pyridinediamine , O-ethyloxime Cyclo-hexanone and compound with 220 molecular weight .

采用离子树脂和活性炭吸附富集这些微量的杂质,并通过液质联用和气质联用对杂质进行了定性分析,鉴定了影响290nm吸收的主要杂质为苯甲腈,2甲基-8羟基喹啉,2,6二氨基吡啶,O-乙基环己酮肟和分子量220的物质。

Methods 4-Hydroxy- benzonitrile was treated with sodium hydrogen sulfide and anhydrous magnesium chloride in dimethyl formamide to give thioamide, which was then directly cyclized with ethyl 2-chloroacetoacetate without separation to give ethyl 2-(4-hydroxyphenyl)-4-methylthiazole-5-carboxylate(2) in one-pot; then 2 was formylated with Duff reaction adopting hexamethylenetetramine in trifluoroacetic acid to give ethyl 2-(3-formyl-4-hydroxyphenyl)-4-methylthiazole-5-carboxylate(3); finally, the target compound was obtained by the treatment of 3 with hydroxylamine hydrochloride and sodium formate in formic acid.

采用"一勺烩"方法,以4-羟基苯甲腈为起始原料,首先与硫氢化钠和无水氯化镁在N,N-二甲基甲酰胺中反应,所得中间体不经分离,直接加入2-氯乙酰乙酸乙酯进行环合反应,得到2-(4-羟基)苯基-4-甲基-5-噻唑甲酸乙酯(2);然后通过六亚甲基四胺/三氟乙酸进行Duff反应,得到2-(3-甲酰基-4-羟基)苯基-4-甲基-5-噻唑甲酸乙酯(3);再经盐酸羟胺/甲酸/甲酸钠体系脱水得到目标化合物。

The starting material substituted cyclohexyl benzoic acid was prepared from substituted phenyl ethanones by bromoform reactions...

起始原料取代的环己基苯甲酸由取代的苯乙酮经溴仿反应得到。

The experimental results indicated that the two N-heterocyclic carbene palladium complexes with coordination of pyridine could catalyze the coupling of bromobenze and gave yield of 80%.

结果表明,这两个含吡啶配位的N-杂环卡宾钯络合物,对溴苯与丙二腈的交叉偶联,产率可达80%。

Vitamin K epoxide reductase generates vitamin K hydroquinone to sustain γ-carboxylation of many blood coagulation factors.

哺乳动物维他命K环氧化物还原酶催化对维他命K苯二酚的生成,这是维他命K循环中的决定性一步,是血液凝固所必需的。

909 And 5,654,304 disclose a series of 10,11-methanobenzosuberane derivatives useful in enhancing the efficacy of existing cancer chemotherapeutics and for treating multidrug resistance.

美国专利第5,643,909号和第5,654,304号公开了一系列10,11-亚甲基苯并环庚烷衍生物,其可用于增强现有癌症化疗法的效能并用于治疗多药耐药性。

And the optimum pH was 4-6 for the dechlorination reaction of 2,4-D, and pH between 2 and 8 were all suited for the reaction in Pd/Fe systems. Intermediate and final products of 2,4-D, HCH and chlordane with Pd/Fe were determined by GC/MS, and the possible dechlorination pathways were concluded: 2,4-D can be converted to phenoxyacetic acid through gradual hydrogenolysis, and HCH can be transformed to cyclohexatriene through dichloroelimination or dehydrochlorination.

通过GC/MS定性定量分析了三种目标污染物在Pd/Fe体系中发生还原脱氯反应过程中的反应物及最终产物,并根据反应产物推测分析了这三种有机污染物在催化还原反应体系中可能的反应途径:2,4-D主要通过逐级氢解最终生成彻底脱氯产物苯氧乙酸;而六六六则可能通过逐步双氯消除反应或脱氯化氢反应,最后生成环己三烯。

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推荐网络例句

We have no common name for a mime of Sophron or Xenarchus and a Socratic Conversation; and we should still be without one even if the imitation in the two instances were in trimeters or elegiacs or some other kind of verse--though it is the way with people to tack on 'poet' to the name of a metre, and talk of elegiac-poets and epic-poets, thinking that they call them poets not by reason of the imitative nature of their work, but indiscriminately by reason of the metre they write in.

索夫农 、森那库斯和苏格拉底式的对话采用的模仿没有一个公共的名称;三音步诗、挽歌体或其他类型的诗的模仿也没有——人们把&诗人&这一名词和格律名称结合到一起,称之为挽歌体诗人或者史诗诗人,他们被称为诗人,似乎只是因为遵守格律写作,而非他们作品的模仿本质。

The relationship between communicative competence and grammar teaching should be that of the ends and the means.

交际能力和语法的关系应该是目标与途径的关系。

This is not paper type of business,it's people business,with such huge money involved.

这不是纸上谈兵式的交易,这是人与人的业务,而且涉及金额巨大。