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In this paper, chiral molybdenum or tungsten 2'-pyridinyl alcoholate complex catalyzed asymmetric epoxidation of cis-1-propenylphosphonic acid in H2O was reported.

目前磷霉素的生产是通过以Na2WO4为催化剂、在乙醇中以30%的H2O2将顺丙烯膦酸环氧化得到消旋产物,再利用α-苯乙胺进行拆分而得到[2,3]。

We first examined the ability of the catalyst to promote the direct aldol reaction between acetone and 4-nitrobenzaldehyde under various conditions.

通过偶联反应将催化剂1固载到硅胶上,并将其用于催化环己酮和硝基苯甲醛的aldol反应,dr值最高达到90:10,ee最高76%。

Benzene undergoes metabolic oxidation by cytochrome P450 enzymes to form an electrophilic epoxide which can alkylate protein and DNA.

苯在细胞色素P450酶氧化代谢下,形成一种能烷化蛋白质和DNA的电环氧化物。

In this novel cyclization, nucleophiles very regioselectively attack the internal C1′alkyne carbon of enediynes to give benzene derivatives as a single regioisomer.

在这新的环化,亲核攻击非常regioselectively内部C1'alkyne碳的enediynes给予苯衍生物作为一个单一的regioisomer 。

Three chiral phosphorus ligands were prepared using anisole as the startingat material.Their applications in the asymmetric hydroformylation and asymmetric conjug ed addition of diethylzinc to enones were investigated.

以苯甲醚为原料,合成了三种新的手性含磷配体,考察了三种配体在不对称氢甲酰化反应和ZnEt2对环己烯酮的不对称共轭加成反应中的应用。

Methods Starting from anisole, liarozole was synthesized by Friedel-Crafts acylation, nitration, nucleophilic substitution, reduction and cyclization.

以苯甲醚为起始原料,经傅克酰基化、硝化、取代、还原、环合等7步反应得到目标化合物利阿唑。

Photoinduced reactions of 1 with 15, 16 and 19 gave the corresponding annulation products 21 (58%), 30 (71%) and 35 (87%) directly in one pot sequential reactions.

二氯香豆素(1)可分别与2-和3-苯基苯并呋喃以及2-甲基-4-苯基噻唑在光照条件下经一锅内的连续反应直接合成增环产物21(58%),30(71%)和35(87%)。

THE FIRST TOTAL SYNTHESIS OF TAXAMAIRIN B Taxamairin B, representive of rare naturally-occuring rearrang-ed 9(10→20)-abeo-8, 11, 13-triene diterpenoids, has been firstsynthesized by a eleven-step route in an overall yield of 8.19%,starting from commercially available catechol and 1,3-cyclohexan-dione. The improved Friedel-Crafts annulation, thermodynamicallycontrolled-geminal pairing methylation, the selective oxidation ofallyl group and the selective reduction of the less-hindrancecarbon-carbon double bond are the key steps.

二。美丽红豆杉素B的全合成研究 1,美丽红豆杉素B的首次全合成以价廉,易得的邻苯二酚和1,3-环己二酮为原料,经过改良的Friedel-Crafts烷基化反应,热力学控制的α,β-不饱和酮结构的α一位双烷基化,烯丙位的选择性氧化,以及选择性还原位阻较小的碳碳双键等十一步反应,以8.19%的总收率首次完成了美丽红豆杉素B的全合成。

Benzaldehyde, cyclohexanone, and octanal were the major products from their respective alcohols.

苯甲醛、环己酮和辛醛等是相应醇的主要氧化产物。

In this paper,the detailed preparation process of gas chromatographic column for separating benzene series was introduced,the optimum column temperature and flow rate of carried gas were selected for separation the mixture of cyclohexane,benzene and toluene,and the column performance has been studied in respects to column efficiency and separating size.

本文主要介绍了气相色谱柱的详细制备过程,并以环已烷、苯和甲苯的混合物的分离为例,选择了最佳的操作条件。同时从柱效率和分离度两方面考察了该色谱柱的柱性能。

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推荐网络例句

We have no common name for a mime of Sophron or Xenarchus and a Socratic Conversation; and we should still be without one even if the imitation in the two instances were in trimeters or elegiacs or some other kind of verse--though it is the way with people to tack on 'poet' to the name of a metre, and talk of elegiac-poets and epic-poets, thinking that they call them poets not by reason of the imitative nature of their work, but indiscriminately by reason of the metre they write in.

索夫农 、森那库斯和苏格拉底式的对话采用的模仿没有一个公共的名称;三音步诗、挽歌体或其他类型的诗的模仿也没有——人们把&诗人&这一名词和格律名称结合到一起,称之为挽歌体诗人或者史诗诗人,他们被称为诗人,似乎只是因为遵守格律写作,而非他们作品的模仿本质。

The relationship between communicative competence and grammar teaching should be that of the ends and the means.

交际能力和语法的关系应该是目标与途径的关系。

This is not paper type of business,it's people business,with such huge money involved.

这不是纸上谈兵式的交易,这是人与人的业务,而且涉及金额巨大。