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At present, since fluorobenzene liquid crystal and cyclohexyl crystal are very popular liquid crystals. some research have done on the synthesis of the intermediate, fluorophenol and alkylcyclohexylbenzene compounds in this thesis.

本论文的主要内容分为两部分:第一部分,针对目前液晶材料研究的热点:含氟液晶和环己烷类液晶,就其液晶材料中间体氟代苯酚和烷基环己基苯类化合物的合成进行研究。

The preparation of esterified derivant : it is prepared by the esterifying reacting of above (3) product and 4g dodecylbenzene sulphonic acid heated in water bath at 40℃ within 30min.

聚环氧氯丙烷乙二醇哌啶接支酯化衍生物的制备:4g十二烷基苯磺酸于40℃水浴条件下聚环氧氯丙烷乙二醇哌啶接支衍生物进行酯化反应。

Three series of segmented polyurethanes were synthesized, which are based on 4,4'-methylene-di, N-methyl diethanolamine and hydroxy terminated poly-butadiene, poly or poly.

本文讨论了以聚环氧乙烷、聚环氧丙烷以及聚丁二烯为软段,以4,4'-二异氰酸二苯甲烷和N,N-二羟乙基甲胺为硬段的链段型聚氨酯的合成。

The chapter two was focused on the samarium diiodide promoted organic reactions and their applications in organic synthesis, firstly, a new synthesis of highly substituted cyclopentadienes from a,β-alkynone promoted by samarium diiodide was investigated and the highly substituted cyclopentadienes were prepared in moderate to good yields under mild conditions. Secondly, the Michael addition and Michael-aldol tandem reaction of diorganyl diselenides or diorganyl disulfides with α,β-alkynones mediated by samarium diiodide were studied and a series of alkenylsulfides and alkenylselenides were prepared in good yields. Then the highly regioselecfive nucleophilic addition of the allylsamarium bromide to α,β-alkynones were explored. We found that the allylsamarium bromide reacts with α,β-alkynones to afford regiospecificly 1. 2-nucleophilic addition products in good yields under mild condition. At last we studied the coupling reaction of aryl halides promoted by NiCl〓/PPh〓/Sm〓.

第二章 研究了二碘化钐、金属钐促进的有机反应:1、二碘化钐促进下α,β-炔基酮的偶联环化反应,提供了一种制备多取代环戊二烯的新方法;2、二碘化钐促进下的二硫醚、二硒醚与α,β-炔基酮的Michael加成反应,为高产率地制备多取代的烯基硫或烯基硒化合物提供了方便可靠的新方法;3、二碘化钐促进下的二硫醚、二硒醚与α,β-炔基酮和醛、酮的Michael—aldol串联反应,提供了一种一锅法高产率地制备多取代的含硫的烯丙基醇或含硒的烯丙基醇类化合物的方便可靠的原子经济性的新方法;4、烯丙基溴化钐与α,β-炔基酮的高度区域选择性的1,2-亲核加成反应;5、NiCl〓/PPh〓/Sm〓促进的卤代芳烃的偶联反应-一种从各种卤代芳烃制备联苯类化合物的有效方法。

The molecule of taxol is an extremely complex diterpene with a taxane ring structure fused with a four-membered oxetane ring, an ester side-chain at position C-13 and a benzoyl side-chain at the C-2 position Fig.

紫杉醇分子是一个极其复杂的四环二萜类化合物:一个紫杉烷环加一个四个元素组成的氧烷环,在C-2和C-13上还分别有一个苯氧基和酯基侧链。

Fifty-seven kinds of polycyclic aromatic hydrocarbon were detected by qualitative method,and sixteen kinds of those were mensurated by quantitative method.The results suggested that the average concentration of chry was the highest,21.83 ng/m3;the average concentration of fluoranthene was the second highest, 21.14 ng/m3; the mass c...

并对16种多环芳烃定量测定,结果表明:以屈艹为最高,平均值为21.83ng/m3;荧蒽次之,平均值为21.14ng/m3;苯并芘的质量浓度为14.52ng/m3,不满足GB3095-96中的质量浓度限值。2001~2003年检测结果对比表明,部分监测点空气中多环芳烃的浓度有下降的趋势。

In this paper, the research and application progress on quinolines, benzimidazoles, and furazan etc deviatives of rosin were reviewed. The research foreground of rosin-based heterocyclic compounds were also forecasted.

本文对喹啉、苯并咪唑、呋咱等系列松香基杂环化合物的研究进展进行了综述,并对松香基杂环化合物的研究前景进行了展望。

An atom other than carbon in the structure of a heterocyclic compound.

碳环的有一个仅由碳原子组成的环的,如苯

Three series of compounds containing isophthalic acid as a bent core and cycloalkylmethanols as a terminal group were synthesized and characterized. Their chemical structures are shown as following.

本论文使用文献上少见的1, 3-苯二酸作为弯曲核,并以短小且刚硬的环烷基作为末端基,共合成了两个七环系列和一个五环系列的液晶化合物。

Inside benzene or toluene solvent, in the presence of stannous octoate as catalyst and under the conditions of no water, no oxygen, heating and stirring, MPEG and aliphatic cyclic monomer are ring-opening polymerized to obtain binary block MPEG-aliphatic polyester copolymer.

聚乙二醇单甲醚和脂肪族环酯单体,在苯或甲苯溶剂中,在无水无氧,加热和搅拌的条件下,用辛酸亚锡为催化剂,开环聚合得到聚乙二醇单甲醚-脂肪族聚酯二嵌段共聚物。

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We have no common name for a mime of Sophron or Xenarchus and a Socratic Conversation; and we should still be without one even if the imitation in the two instances were in trimeters or elegiacs or some other kind of verse--though it is the way with people to tack on 'poet' to the name of a metre, and talk of elegiac-poets and epic-poets, thinking that they call them poets not by reason of the imitative nature of their work, but indiscriminately by reason of the metre they write in.

索夫农 、森那库斯和苏格拉底式的对话采用的模仿没有一个公共的名称;三音步诗、挽歌体或其他类型的诗的模仿也没有——人们把&诗人&这一名词和格律名称结合到一起,称之为挽歌体诗人或者史诗诗人,他们被称为诗人,似乎只是因为遵守格律写作,而非他们作品的模仿本质。

The relationship between communicative competence and grammar teaching should be that of the ends and the means.

交际能力和语法的关系应该是目标与途径的关系。

This is not paper type of business,it's people business,with such huge money involved.

这不是纸上谈兵式的交易,这是人与人的业务,而且涉及金额巨大。