苯环

Experimental process: jing and 3- methyl -2- methyl ethyl ketonesynthesizes by the benzene zong; Again the glacial acetic acidcatalysis produces 2, 3, 3 - trimethyl - 3H - yinduo; Again has thealkylate response production yinduo iodide after the methyl iodide;The iodide takes off molecular HI under NaOH to become freejier thealkali; Adds 5 - nitryls salicylic aldehydes in the ethyl alcohol forthe solvent under if to respond finally produces 6 '- the nitryl yinduolin spiral benzene and pinan; Through the infrared spectrum andthe ultimate analysis irrevocably proved its structure, and studiedthe annulus with to open the annulus the light to send changes colorthe performance, explained in different solvent medium ultravioletabsorption spectrometry solvent effect, and the comparisondiscoloration the response speed number difference, finally mixed itadds to the methyl methacrylate, the peroxidation benzoin formyl in the plexiglass, tested 6 '- the nitryl yinduolin spiralbenzene and pinan in the glass fatigue resistance, thethermostability.

实验过程：由苯肼和3-甲基-2-丁酮合成腙；再冰醋酸催化生成2 ，3 ，3—三甲基—3H—吲哚；再经过碘甲烷发生烷基化反应生成吲哚碘化物；碘化物在NaOH下脱去一分子HI成为费歇尔碱；在乙醇为溶剂下加5－硝基水杨醛与其反应最后生成6'—硝基吲哚啉螺苯并吡喃；通过红外光谱和元素分析确证其结构，并研究了环体与开环体的光致变色性能，解释了在不同溶剂介质中紫外吸收光谱的溶剂效应，并比较褪色反应速率数的差异，最后将其掺加到甲基丙烯酸甲酯，过氧化二苯甲酰有机玻璃中，测试6'—硝基吲哚啉螺苯并吡喃在玻璃中的抗疲劳性、热稳定性。

The initial SAR studies indicated:(1) the presence of a linker of methene at the N-1 may be beneficial to anti-HIV activity, while longer chain could enhance toxicity;(2) substituted phenyl at the C-2 could reduce toxicity;(3) 6-substituted benzimidazoles generally showed higher anti-HIV activity than 5-substuted ones;(4) the presence of a halogenated benzyl ring at the N-l would enhance anti-HIV potency and decrease cytotoxicity.

初步构效分析提示：(1)苯并咪唑环1位侧链间隔基为亚甲基时活性最好，侧链延长，毒性增大；(2)苯并咪唑2位侧链无间隔基毒性相对较低；(3)苯并咪唑6位取代活性高于5位取代；(4)苯并咪唑1位芳环用卤素取代，毒性明显降低。

The initial SAR studies indica ted:(1)the presence of alinker of methene at the N-1may be beneficial to anti-HIV activity,while longer chain could enhance toxicity;(2)substituted phenyl at the C-2could reduce toxicity;(3)6-substituted benzimidazoles generally showed higher anti-HIV activity than 5-substuted ones;(4)the presence of ahalogenated benzyl ring at the N-l would enhance anti-HIV potency and decrease cytotoxicity.

初步构效分析提示：(1)苯并咪唑环1位侧链间隔基为亚甲基时活性最好，侧链延长，毒性增大；(2)苯并咪唑2位侧链无间隔基毒性相对较低；(3)苯并咪唑6位取代活性高于5位取代；(4)苯并咪唑1位芳环用卤素取代，毒性明显降低。

During the manufacturing of the critical intermediate cephalosporin nucleus --7-amino-3-chloro-cephalosporanic acid diphenylmethyl ester hydrochloride salt, first the feasibility of the one-pot synthetic route of open loop, closed loop and ozonization when chlorine is passed over is qualified by experiments. Then the critical factors that will influence this reaction are studied as follows: the mol ratio of triphenyl phosphite and Diphenylmethyl 3-hydroxy-7-phenylacetaminoceph-3-em-4-carboxylate-l-oxide is four to one; the quantity of the stablizer should be at least more than two to one. The temperature of the system must be 25℃ when chlorine is passed over so that the hydrochloride can be precipitated to obtain cephalosporin nucleus of cefaclor--7-amino-3-chloro-cephalosporanic acid diphenylmethyl ester hydrochloride salt.

在制备关键中间体头孢母核7-氨基-3-氯头孢烷酸二苯甲酯盐酸盐时，先通过实验验证把开环、闭环、臭氧化三步在通入氯气时并为一锅煮的合成路线的可行性之外，又研究了影响该反应的几个重要因素：亚磷酸三苯酯与3-羟基-7-头孢烷-5-亚砜-2-甲酸二苯甲酯的摩尔比为4：1；稳定剂2-甲基-2-丁烯的用量至少大于2：1，通入氯化氢气体时体系温度在25℃时盐酸盐则能够顺利析出，获得头孢克洛的头孢母核—7-氨基-3-氯头孢烷酸二苯甲酯盐酸盐。

The response to single compound: To both females and males, the compounds that elicit larger responses of adults are benzaldehyde, benzene acetaldehyde, hexanol,β-phenyl ethyl alcohol, benzyl alcohol, cyclohexanol and eugenol. Phytol, 2-methyl-cyclohexanone and β-caryophyllene reveal to have weaker activity.

对单一化合物的反应：两种昆虫，不论是雌蛾还是雄蛾，能引起较强EAG反应的化合物均为苯甲醛、苯乙醛、正己醇、β-苯乙醇、苯甲醇、环己醇和丁香酚，植醇、2-甲基环己烷和β-石竹烯仅能引起微弱的EAG反应。

For the synthesis reaction of chalcone, cyclohexanone aldolization and biodiesel,γ-Al_2O_3-NaOH-Na solid superacid has a satisfactory catalytic activity. With hypnone and phenylaldehyde as raw material, amount of catalyst 7.5% wt% of material, mole ratio of hypnone and phenylaldehyde 1:1.1, reaction temperature 40℃, after 3 hours, the yield of chalcone can be up to 96.88%. With cyclohexanone as raw material, amount of catalyst 10% wt% of material, reaction temperature 190℃, after 3 hours, dimmer of cyclohexanone can be up to 85.66%.

将该固体超强碱催化剂应用于查尔酮、环己酮自缩合以及生物柴油的合成反应中，该改性固体超强碱催化剂表现出了良好的催化活性：以苯乙酮和苯甲醛为原料，反应温度为40℃，催化剂用量为反应物总质量的7.5％，苯甲醛与苯乙酮摩尔比为1：1.1，反应3h查尔酮产率可达96.88％；以环已酮为原料，催化剂用量为原料总质量的10％，反应温度为190℃，反应3h，二聚物的总收率可达85.66％；以动物油和甲醇为原料，醇油摩尔为9：1，催化剂用量为动物油质量的2％，反应温度为70℃，反应3h后，生物柴油的收率可达91.8％。

A novel method for determination of benzoyl peroxide with spectrophotometry was developed. Inclusion ratio of β cyclodextrin to dibenzoy peroxide and benzoic acid is obtained with spectrophotometry.The mechanism of the inclusion was studied,too. The results showed that β-CD react with dibenzoyl peroxide to form a 1:1 or 2:1 host-guest complex, with the apparent formation constants of 5.0× 10~2and 2.5× 10~4 , respectively.β-CD reacts with benzoic acid to form a 1:1 host-guest complex with the apparent formation constant of 6.9 × 10~2 after the dibenzoyl peroxide was reduced by hydroxyl ammonium chloride.

建立了用β环糊精测定过氧化苯甲酰的分光光度法，并测定了β环糊精与过氧化苯甲酰和苯甲酸的包结比，随着β-CD浓度的增大，可与BPO分别形成1：1或2：1的包容络合物，包结常数分别为5.0×10~2和2.5×10~4，与苯甲酸形成1：1的包容络合物，包结常数为6.9×10~2；由于包结物的吸光度值比过氧化苯甲酰的吸光度值大大增加，建立了一种当β-CD存在下，在水溶液中测定过氧化苯甲酰的方法。

Novel phosphazene cyclomatrix network polymers were synthesized via nucleophilic displacement of activated nitro groups of tri (4-nitrophenoxy)tri cyclotriphosphazene and hexa cyclotriphosphazene with the hydroxyls of bisphenol A.

以三对硝基苯氧基三苯氧基环三膦腈和六对硝基苯氧基环三膦腈为主要单体，采用活性硝基亲核取代的方法，合成了一类新的环簇膦腈聚合物。

Novel phosphazene cyclomatrix network polymers were synthesized via nucleophilic displacement of activated nitro groups of tri (4-nitrophenoxy) tri cyclotriphosphazene and hexa (p-nitrophenoxy) cyclotriphosphazene with the hydroxyls of bisphenol A.

以三对硝基苯氧基三苯氧基环三膦腈和六对硝基苯氧基环三膦腈为主要单体，采用活性硝基亲核取代的方法，合成了一类新的环簇膦腈聚合物。

First, 4-(2, 3-epoxypropoxyl) benzaldehyde was obtained by reaction of 4-hydroxy benzaldehyde and epichlorohydrin. Then, the Wittig reaction was carried out to convert EBD to styryl glycidyl ether.

首先用对羟基苯甲醛和环氧氯丙烷反应制备4-(2， 3-环氧丙氧基)苯甲醛，然后通过Wittig反应将醛基转化为乙烯基得到含环氧基团的功能性单体苯乙烯基环氧丙基醚，最后用ATRP方法聚合单体SGE得到含环氧侧基的聚苯乙烯。

We have no common name for a mime of Sophron or Xenarchus and a Socratic Conversation; and we should still be without one even if the imitation in the two instances were in trimeters or elegiacs or some other kind of verse--though it is the way with people to tack on 'poet' to the name of a metre, and talk of elegiac-poets and epic-poets, thinking that they call them poets not by reason of the imitative nature of their work, but indiscriminately by reason of the metre they write in.

索夫农 、森那库斯和苏格拉底式的对话采用的模仿没有一个公共的名称；三音步诗、挽歌体或其他类型的诗的模仿也没有——人们把&诗人&这一名词和格律名称结合到一起，称之为挽歌体诗人或者史诗诗人，他们被称为诗人，似乎只是因为遵守格律写作，而非他们作品的模仿本质。

The relationship between communicative competence and grammar teaching should be that of the ends and the means.

交际能力和语法的关系应该是目标与途径的关系。