苯核

The effects of substituents on the nucleophilic reaction of benzyl halide and sodium azide were studied.

合成了叠氮苄、对氰基叠氮苄，对氟叠氮苄，对甲基叠氮苄和联苯二叠氮苄，研究了苯环上不同取代基对苄基卤代物与叠氮化钠经亲核取代反应生成苄基叠氮化物的反应的影响。

A novel monomer the 1-methyl-4,5-bis(4-chlorobenzoy) cyclometer containing cyclohexene were prepared,so a group of novel polys containing the cyclohexene and phthalazinone moieties was prepared by the nucleophilic displacement reaction of 1-methyl-4,5-bis(4-chlorobenzoyl) cyclohexene and 4,4′-dichlorodiphenyl sulfone and 4-(3,5-dimethyl-4-hydroxyphenyl)-2,3-phthalazin-1-one.

用新型聚合单体1-甲基-4，5-二(4-氯代苯甲酰基)环己烯与4-(4-羟基苯基)-2，3-二氮杂萘-1-酮、4，4′-二氯二苯砜单体经亲核共缩聚反应，成功地合成了含环己烯结构的杂环联苯型聚醚系列聚合物。

A novel monomer the 1-methyl-4,5-bis (4-chlorobenzoy) cyclometer containing cyclohexene were prepared,so a group of novel polys containing the cyclohexene and phthalazinone moieties was prepared by the nucleophilic displacement reaction of 1-methy l-4,5-bis(4-chlorobenzoyl) cyclohexene and 4,4'-dichlorodiphenyl sulfone and 4-(3,5-dimethyl-4-hydroxyphenyl)-2,3-phthalazin-1-one.

用新型聚合单体 1-甲基-4，5-二(4-氯代苯甲酰基)环己烯与 4-(4-羟基苯基)-2 ，3-二氮杂萘-1-酮、4，4′-二氯二苯砜单体经亲核共缩聚反应，成功地合成了含环己烯结构的杂环联苯型聚醚系列聚合物。

In our research on study chemical reaction of active methylene compounds and brom-acetophenone. Because of brom-acetophenone is compound that contain carbonyl and halogen ,which will take place electrophilic substitution and nucleophilic addition. When active methylene compounds are ethyl acetoacetate and β-diketone, controlling reaction condition, we have found that mono-substitution's production and di-substitution's. production is isolated; active methylene compounds are acetoacetanilide and acetoacetanilide derivate, pyrrolidin-2-one derivants were obtained by substitution and close-ring reaction .but there is no report about it.

本文是让活泼亚甲基类化合物与溴代苯乙酮发生化学反应，由于溴代苯乙酮是含有羰基的卤代烃结构，它可以发生亲电取代和亲核加成反应，当活泼亚甲基类化合物为乙酰乙酸乙酯和β-二酮时，控制反应条件可以发生单取代和双取代两种产物；当活泼亚甲基类化合物为乙酰乙酰芳胺类化合物来反应时，溴代苯乙酮中的羰基与氨基会发生分子内的关环反应生成吡咯烷-2-酮衍生物，这在以前的研究中是没有发现的。

Synthesis of target compounds namely: to vanillic acid as the starting material with methanol under reflux conditions for 4 - hydroxy -3 - p-methyl, then ether, and nitration, reduction, cyclization reaction 6 - methoxy -7 - benzyloxy-quinazoline -4 - one, and then by the chloride in place of aniline, benzyloxy-off, such as etherification reaction of the target compounds; target compounds with the second and third occurrence of substitution reactions of amines by the TM1, that is, 4 - amino-benzene -6 - methoxy -7 - [2 - hydroxy -3 -(N, N-diethyl amino) oxy c] quinazoline; with ether occurred Ornidazole reaction of TM2, namely, 4 - amino-benzene -6 - methoxy -7 - [2 - hydroxy -3 -(2 - methyl -5 - nitroimidazole) C oxy] quinazoline.

本论文以嘌呤类似物喹唑啉为母核，分别在其4位和7位引入结构多样的取代苯氨基和柔性侧链，设计了一系列4-取代苯胺基-6-甲氧基-7-(2-羟基取代丙氧基)喹唑啉类化合物。目标化合物的合成即：以香草酸为起始原料，与甲醇回流条件下得到4-羟基-3-甲氧基苯甲酸甲酯，然后经过醚化、硝化、还原、环合反应得到6-甲氧基-7-苄氧基喹唑啉-4-酮，然后再经氯化、取代苯胺、脱苄氧基、醚化等反应得到目标化合物；目标化合物与二乙胺发生胺取代反应得到了TM1，即4-苯氨基-6-甲氧基-7-[2-羟基-3-丙氧基]喹唑啉；通过与奥硝唑发生醚化反应得到TM2，即4-苯氨基-6-甲氧基-7-[2-羟基-3-(2-甲基-5-硝基咪唑)丙氧基]喹唑啉。

The acetated and hydrogenated urushiol dimer has been separated,and studied by hetero-J resolved 2D-NMR,homo- and heteronuclearchemical shift correlation 2D-NMR and long-range coupled chemicalshift correlation 2D-NMR.The results show that the urushiol dimerare most diphenyl and alkyl phenyl ether structures.Furthermore,IR and MS data also has conformed this structures.

本文将酶催化预聚后的生漆，催化加氢后，乙酰酯化，再进行离心旋转薄层层析，分离得到二聚体主要组分，用异核J分辨谱，同核化学位移相关，异核化学位移相关，远程偶合异核化学位移相关等2D—NMR技术，全面研究了其结构，得到了联苯型和烷基芳醚型聚合结构的结论。

A series of sulfonated poly copolymers with different degree of sulfonation were synthesized by aromatic nucleophilic polycondensation of 3,3′-disulfonate 4,4′-dichlorodiphenylsulfone,4,4′-dichlorodiphenylsulfone and 4,4′-biphenol.

将磺化二氯二苯砜、二氯二苯砜与4，4′-联苯酚通过亲核缩聚反应得到一系列具有不同磺化度的磺化聚芳醚砜共聚物。

Novel phosphazene cyclomatrix network polymers were synthesized via nucleophilic displacement of activated nitro groups of tri (4-nitrophenoxy)tri cyclotriphosphazene and hexa cyclotriphosphazene with the hydroxyls of bisphenol A.

以三对硝基苯氧基三苯氧基环三膦腈和六对硝基苯氧基环三膦腈为主要单体，采用活性硝基亲核取代的方法，合成了一类新的环簇膦腈聚合物。

Novel phosphazene cyclomatrix network polymers were synthesized via nucleophilic displacement of activated nitro groups of tri (4-nitrophenoxy) tri cyclotriphosphazene and hexa (p-nitrophenoxy) cyclotriphosphazene with the hydroxyls of bisphenol A.

以三对硝基苯氧基三苯氧基环三膦腈和六对硝基苯氧基环三膦腈为主要单体，采用活性硝基亲核取代的方法，合成了一类新的环簇膦腈聚合物。

But the electrochemical results show that complexes exhibitcompletely irreversible redox behaviour which is different from thatfound in diiron proteins. 1.3 To obtain the diiron species which are stable to elec-trochemical reduction, a series of new tetranuclear cage ironspecies containing two 〓 cores, with using hexadentatepolybenzimidazole ligands, were synthesized and characterized by vari-ous spectroscopic methods. Their physical properties have been investi-gated. The crystal structures of 〓〓tetrakis (benzimidazol-2-ylmethyl)-1, 4-diaminobutane and 〓,〓-tetrakis ( N-ethylbenzimidazol-2-ylmethyl )-1, 4-diaminobutane were determined. They contain two 〓 cores which arelinked to each other by -〓-chain in the ligands.

1.3为了获得电化学还原稳定双核氧桥联Fe化合物，使用六齿配体合成了一系列含有两个〓单元四核笼状化合物，并用各种谱学手段表征了它们，还研究了它们的物理化学性质确定了〓L=N，N，N'，N'-四(苯骈咪唑基-1，4-丁二胺和〓，〓四-1，4-丁二胺化合物的晶体结构，它们含有两个〓单元，其中两个〓单元是通过配体的〓链桥联成四核笼状结构。

We have no common name for a mime of Sophron or Xenarchus and a Socratic Conversation; and we should still be without one even if the imitation in the two instances were in trimeters or elegiacs or some other kind of verse--though it is the way with people to tack on 'poet' to the name of a metre, and talk of elegiac-poets and epic-poets, thinking that they call them poets not by reason of the imitative nature of their work, but indiscriminately by reason of the metre they write in.

索夫农 、森那库斯和苏格拉底式的对话采用的模仿没有一个公共的名称；三音步诗、挽歌体或其他类型的诗的模仿也没有——人们把&诗人&这一名词和格律名称结合到一起，称之为挽歌体诗人或者史诗诗人，他们被称为诗人，似乎只是因为遵守格律写作，而非他们作品的模仿本质。

The relationship between communicative competence and grammar teaching should be that of the ends and the means.

交际能力和语法的关系应该是目标与途径的关系。