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苯并噻唑

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Ophenyl phenol,ophenyl phenol sodium salt tetrahydrate,7ADCA,2ethyl phenyl hydrazine hydrochloride,2,3dihydrofuran,7ethyl3(2hydroxy ethyl)indole,methyl ester of etodolac; 1,8diethyl1,3,4,9tetrahydropyrano[3.4b] indole1acetic acid methyl ester,5chloro2methoxy benzoic acid,4(2aminoethyl)benzene sulfonamide,5cyano phthalide,phthalhydrazide,9thioxanthenone,n[(1,4benzodioxane2yl)carboxyl]piperazine HCL,2chloro4amino6,7dimethoxyquinazoline,2chloro benzimidazole,1(4fluorobenzyl)2chlorobenzimidazole,2methylthio4pyrimidone,5amino4imidazole carboxamide HCL,6chloro2hexanone,11oxo6.11hydrodibenzothiepin,6,11dihydrodibenzooxepin11one,10,11dihydrodibenzocyclohepten5one;dibenzosuberone,dibenzo cyclohepten5one;dibenzosuberenone,3,5dihydroxy benzoic acid,3,5dihydroxy benzyl alcohol,2mercapto benzimidazole,3,4dihydroxy benzaldehyde,3,4dihydroxy benzonitrile,2amino5chloro benzonitrile,2(4chlorophenoxy)ethyl chloride,2(4chloro phenoxy)tert,butane,ditrimethylol propane;DTMP,2,2bis(4hydroxyphenyl)butane; bisphenol B,1,1'bis(4hydroxyphenyl)cyclohexane;bisphenol Z,tetrabromobisphenolS,3,5ditertbutyl salicylic acid,3,4,5trihydroxy benzoic acid stearyl ester,1,2,4trimethoxybenzene.

华业公司产品:邻苯基苯酚,邻苯基苯酚钠盐,7氨基3去乙酰氧基头孢烷酸,邻乙基苯肼盐酸盐,2,3二氢呋喃,7乙基色氨醇,依托度酸甲酯,5氯2甲氧基苯甲酸,4(2氨乙基)苯磺酰胺,5氰基苯酞,双酮酞嗪,9噻吨酮,N〔(1,4苯并二恶烷2基)羰基〕哌嗪盐酸盐,2氯4氨基6,7一二甲氧基喹唑啉,2氯苯并咪唑,1(4氟苄基)2氯苯并咪唑,2甲硫基4嘧啶酮,5氨基咪唑4 甲酰胺盐酸盐,6氯2已酮,11氧6.11二氢苯并〔b.c〕虑平,11氧代6,11二氢二苯并氧杂卓,10,11二氢二苯并环庚烯5酮,二苯并环庚烯5酮,3,5二羟基苯甲酸,3,5二羟基苯甲醇,2巯基苯并咪唑,3,4二羟基苯甲醛,3,4二羟基苯腈,2氨基5氯苯腈,2(4氯苯氧基)1氯乙烷,2(4氯苯氧基)叔丁烷,双丙烷,2,2二(4羟基苯基)丁烷;双酚B,1,1'双(4羟基苯基)环己烷;双酚Z,2[3,5二溴4(2,3二溴丙氧基)]苯砜,3,5二叔丁基水杨酸,3,4,5三羟基苯甲酸十八烷基脂,1,2,4三甲基氧基苯。

Study on the synthesis and structure -property relationship of cyanine dyes is of important theoretical and practical sinificance.

本文以噻菁、噻碳菁和苯并咪唑—噻碳菁这三种类型的菁染料的合成及性质研究为核心,展开了一系列工作,归纳如以下几个方面

A series of 2-acetylformanilides were prepared,followed by thiolation with Lowesson reagent to afford 2-acetylthioformanilides,which further reacted with Mn3·2H2O in glacial acetic acid under microwave irradiation to afford 2-acetyl benzothiazole s.

合成了一系列的硫代酰胺,研究了它们在微波辐射醋酸锰作用下发生氧化自由基环化反应,成功地合成了一系列2-乙酰基苯并噻唑衍生物,其结构经红外光谱、核磁共振谱和质谱得到了证实

It is manufactured through kneading, cold pressing and post-treatment; and the materials for the synthetic brake shoe include butadiene-acrylonitrile rubber, phenolic resin, graphite, iron powder, barium sulfate, potash feldspar powder, composite fiber, sulfur, hexamethine tertramine, polymethylene aniline, 2-mercaptan benzothiazole, zinc oxide and toluene.

同时本发明的提供了采用捏合、冷压、后处理工艺来制造新型高摩擦系数合成闸瓦。组成新型高摩擦系数合成闸瓦的各组分重量百分比如下:丁腈橡胶为6.20%,酚醛树脂为10.00%,石墨为15.00%,铁粉为11.03%,硫酸钡为30.00%,钾长石粉为5.00%,复合纤维为20.20%,硫磺为1.00%,六次甲基四胺为1.00%,聚亚甲基聚苯胺0.12%,2-硫醇基苯并噻唑0.15%,氧化锌0.30%,甲苯8.0%。

In this study, new benzo[l,2,3]thiadiazole derivatives were designed according to relationship of structure and efficacy. The 9 novel compounds were synsthesized with following reactions. The chlorine atom in 2-chloro-3,5-dinitro-benzoic acid as beginning raw material was substituted by 2-methylpropane-2-thiol, esterified then with bromoethane, reduced by iron powder and cyclized to obtain ethyl benzo[l,2,3]thiadiazole-7 after diazonation reation.

本论文根据苯并噻二唑诱导剂的构效关系设计了新的苯并噻二唑的结构,并合成了9个未见文献报道的化合物,合成步骤如下:采用2-氯-3,5-二硝基苯甲酸为起始原料,苯环上的氯原子被叔丁基硫醇置换,羧酸由溴乙烷酯化,硝基由铁粉还原,随后经重氮化关环生成苯并[1,2,3]噻二唑-7-羧酸乙酯。

The best of them were 4c and 8d which exhibited 87% and 89% inhibition of Penicilium digitatum . And benzothieno[3,2-d]imidazol[1,2-a]pyrimidin-2,5(1H, 3H)-diones or benzothieno[3,2-d][1,2,4]triazol[1,5-a]pyrimidin-10(3H)-one only exhibited moderate inhibition.

而苯并噻吩并[3,2-d]嘧啶-4(3H)-酮和苯并噻吩并[3,2-d]咪唑并[1,2-a]嘧啶-2,5(1H,3H)-二酮以及苯并噻吩并[3,2-d][1,2,4]三唑[1,5-a]嘧啶-10(3H)-酮衍生物以及三唑醇衍生物均只表现出中等的抑制率。

And benzothieno[3,2-d]imidazol[1,2-a]pyrimidin-2,5(1H, 3H)-diones or benzothieno[3,2-d][1,2,4]triazol[1,5-a]pyrimidin-10(3H)-one only exhibited moderate inhibition.

而苯并噻吩并[3,2-d]嘧啶-4(3H)-酮和苯并噻吩并[3,2-d]咪唑并[1,2-a]嘧啶-2,5(1H,3H)-二酮以及苯并噻吩并[3,2-d][1,2,4]三唑[1,5-a]嘧啶-10(3H)-酮衍生物以及三唑醇衍生物均只表现出中等的抑制率。

Aminobenzothiazoleswere diazotized and then coupled with active methylenecompounds to form a kinds of new hydrazones.

苯基硫脲在浓硫酸中,先在溴作用下氧化合环,再直接硝化,得到产率95%,纯度98%的2-氨基-6-硝基苯并噻唑

Examples of metal chelating groups include hydroxides especially aryl or heteroaryl hydroxides such as phenolic hydroxides; amines which may be aliphatic aryl or heteroaryl; mercaptans which may be aliphatic aryl or heteroaryl; carboxylic acids which may be aliphatic aryl or heteroaryl; oximes and ketoximines; acetarylamides; hydroxy silanes and silicones; N-containing heterocycles such as imidazoles benzimidazoles triazoles benzotriazoles thiazoles isothiazoles acid anhydrides and more preferably acid groups (especially carboxylic acid groups phosphoric acid groups polyphosphoric acid groups phosphonic acid groups sulphuric acid groups and sulphonic acid groups).

金属螯合组的例子包括氢氧化物,特别是芳基或如酚醛氢氧化物杂氢氧化物;胺可能是脂肪族,芳基或杂;硫醇可能是脂肪族,芳基或杂,这可能是脂肪族,芳基或羧酸杂;肟和ketoximines; acetarylamides;羟基硅烷和有机硅,含N,如咪唑,苯并咪唑类,三唑类,苯并三氮唑,噻唑类,isothiazoles,酸酐杂环,多最好酸组(特别是羧酸团体,磷酸,团体,多聚酸组,膦酸组,硫酸团体和磺酸组)。

Cyclohexylamine is mainly to be made sodium cyclamate, CBS accelerating agent, cyclohexanol, cyclohexanone, caprolactam, acetate fiber and nylon.

环己胺主要用于合成食品甜味剂环己基氨基磺酸钠和橡胶促进剂N-环己基-2-苯并噻唑次磺酰胺。

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