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This dissertation deals with the synthetic method of benzotellurazoles containing various substituents in benzene nuclei: introducing tellurium atom to the acetanilide derivatives in ortho-position by direct or indirect ways, then reduced and cyclized to give substituted benzotellurazoles directly or indirectly.

本文系统研究了含各类取代基的苯并碲唑杂环的合成方法,即向原料中用四氯化碲以直接或间接定位的方法引入碲,再经过直接或间接还原关环法制备苯并碲唑。

Part 2. Annulation reaction of 3, 4-dichlorocoumarin (1) and 3, 4-dichloromaleimide (8) by a new general annulation strategy developed in this group with 2-phenylbenzofuran (15), 3-phenylbenzofuran (16), 2, 5-diphenyloxazole (17), 2, 5-diphenylthiazole (18), 2-methyl-4-phenylthiazole (19) and 2, 3-dimethoxy-1, 3-butadiene (40) were investigated.

二。在本课题组前一阶段提出的从二氯代环烯酮与1,1-二芳基乙烯的光化反应以及光化反应中得到的环丁烷产物的连续电环化反应对3,4-二氯马来酰亚胺以及3,4-二氯香豆素进行增环反应的工作基础上,研究了3,4-二氯香豆素(1)和3,4-二氯马来酰亚胺(8)与5个α-苯基取代的环烯烃2-苯基苯并呋喃(15),3-苯基苯并呋喃(16),2,5-二苯基噁唑(17),2,5-二苯基噻唑(18),2-甲基-4-苯基噻唑(19),以及一个丁二烯——2,3-二甲氧基丁二烯(40)进行的芳香族增环反应。

Because they have one nitrogen atom with lone pair electrons, benzimidazole compounds are endowed with capability of complex and molecular recognition and they can analogue biological molecule.

苯并咪唑具有一个含孤对电子的氮原子,从而使苯并咪唑类化合物具有很强的配位能力及分子识别能力,可以用于生物分子的模拟。

We developed a simple and efficient method for the synthesis of benzimidazole derivatives in water. Imidazolium salt grafted iodobenzene diacetate containing double features of ionic liquid and iodobenzene diacetate was synthesized.

报道了一种简便高效的苯并咪唑类衍生物的水相合成新方法,合成了兼具离子液体和二醋酸碘苯双重特点的咪唑盐二醋酸碘苯。

Benzoxazine compounds are one kind of highly active protoporhyrinogen oxidase inhibitors. These compounds can effectively control both monocotyledon weeds and dicotyledon weeds at lower dosage. The action mechanism is similar to p-nitro-o-substituted diphenylethers. They can result weeds albinism and decolorization, which are very important albinism herbicide.

苯并噁嗪类化合物是一类高活性的原卟啉原氧化酶抑制剂,低剂量可有效地防除禾本科与阔叶杂草,其作用机理和对硝基邻位取代的二苯醚类似,它们造成白化或脱色,是白化除草剂中较重要的种类,其活性远超过二苯醚除草剂,是目前化学农药研究领域的热点。

The highly sensitive chromogenic reaction of a ternary complex of 4-(2-benzothiazolylazo) pyrocatechol with Mo-, W-diphenyl guanidine and the application of partial least squares method in simultaneous spectrophotometric determination of trace Mo and W have been studied.

本文研究了新显色剂4-(2-苯并噻唑偶氮)邻苯二酚-Mo、W-二苯胍三元配合物的高灵敏显色反应以及偏最小二乘法在同时分光光度测定痕量钼和钨中的应用。

Results61 peaks were separated and 16 constituents were identified, which were composed of about 96.46% of the total essential oil.ConclusionThe main constituents are allyl phenoxyacetate(80.17%), eudesma-4(14),11-diene(6.83%), 2,3-dihydro-3-methyl-3-benzofuran-methanol(2.94%), limonene(1.63%). The essential oil in Oenanthe javanica DC from Dali, Yunnan can be used in the food service industry and the cosmetic industry as spices.

水芹挥发油中的主要成分为苯氧乙酸烯丙酯(80.17%)、桉叶-4(14),11-二烯(6.83%)、2,3-二氢-3-甲基-3-苯并呋喃甲醇(2.94%)、柠檬烯(1.63%),云南大理产水芹挥发油中萜类化合物及其衍生物含量在13%以上,苯氧乙酸烯丙酯含量高,可用作食品工业和化妆品工业的香料。

ConclusionThe main constituents are allyl phenoxyacetate(80.17%), eudesma-4(14),11-diene(6.83%), 2,3-dihydro-3-methyl-3-benzofuran-methanol(2.94%), limonene(1.63%). The essential oil in Oenanthe javanica DC from Dali, Yunnan can be used in the food service industry and the cosmetic industry as spices.

水芹挥发油中的主要成分为苯氧乙酸烯丙酯(80.17%)、桉叶-4(14),11-二烯(6.83%)、2,3-二氢-3-甲基-3-苯并呋喃甲醇(2.94%)、柠檬烯(1.63%),云南大理产水芹挥发油中萜类化合物及其衍生物含量在13%以上,苯氧乙酸烯丙酯含量高,可用作食品工业和化妆品工业的香料。

In order to find highly active pesticide, three series of 5--12-substituent-benzo phenanthridine derivatives were synthesized through the reaction of 2-methylbenzonitrile with dif-ferent aldehyde, and further dehydration with DDQ or N-methylation with NaH and CH3I, respectively.

为了寻找新的高活性农药,利用2-甲基苯甲腈与不同的醛反应,再通过2,3-二氯-5,6-二氰基-1,4-苯醌脱氢或NaH和CH3I氮甲基化,合成了3个系列共18个5-取代氨基-12-取代苯并菲啶衍生物,其中15个是未见文献报道的化合物。

Deoxybenzoin(3) was prepareded by using the resorcinol and substituted phenylacetic as starting meterials in microwave-mediated.Then the compound(3) was reacted with acetic anhydride to produce(4).The compound(4) was hydrolyzed to convert compound(5) in the acid-mediated. The compound(5) was reacted with the 1,2-dibromo-ethane and 1,3-dibromo-propane in refluxed condition with acetone as solvent to give(6) or(7),respectively.Lastly,the title compounds were synthesized by refluxing(6) or(7) with 2-methyl-benzimidazole and potassium carbonate in acetone solution.

以取代苯乙酸和间苯二酚为起始原料,用微波辐射法合成脱氧安息香(3),(3)与乙酸酐缩合生成2-甲基-7-乙酰氧基异黄酮(4),(4)在酸性条件下水解生成相应的异黄酮(5),化合物(5)分别与1,2-二溴乙烷和1,3-二溴丙烷反应生成(6)和(7),化合物(6)和(7)再分别与2-甲基苯并咪唑偶合生成目标化合物。

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