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The reduction of acetophenone was studied by cyclic voltammetry and the mechanism has been proposed on the basis of the results.

并利用循环伏安法研究了苯乙酮的还原和电羧化过程的机理。

The method has been used to determine Phthalic esters in drinking water and seawater sample. 3. Single drop microextraction, followed by gas chromatography with flame ionization detection has been applied to determine Formaldehyde, Acetaldehyde and Acraldehyde in water based on 2,4-Dinitrophenylhydrazine derivatization. Extraction solvent, extraction time and stirrer speed were optimized. Optimal experimental conditions were as follows: 1.6μL toluene microdrop exposed for 30 min in a 3ml aqueous sample placed in 4ml vial and stirred at 600 rpm/min.

以2,4-二硝基苯肼衍生,单滴液相微萃取与气相色谱火焰光度检测器联用测定水样中的甲醛、乙醛、丙烯醛,考察了萃取溶剂、液滴大小、萃取时间、搅拌速度、盐效应等对该方法的影响,并对影响液相微萃取的各种因素进行了系统的阐述,确定了该体系的最佳实验条件,实现了甲醛、乙醛、丙烯醛的提取和富集。

Meanwhile, the properties of activated carbon fiber and benzene adsorption were also studied carefully.

同时,本文也对活性炭纤维的性能做出了分析,并研究了活性炭纤维对苯的吸附。

The coating is effected by impregnation with aluminium isopropoxide in benzene solution and the alcoholate is then hydrolysed in situ, and the whole is heated to 600℃ for activation.

涂溃方法系将耐火砖用异丙醇铝的苯溶液浸渍,再把浸上去的异丙醇铝水解,并在600℃下活化。

We first examined the ability of the catalyst to promote the direct aldol reaction between acetone and 4-nitrobenzaldehyde under various conditions.

通过偶联反应将催化剂1固载到硅胶上,并将其用于催化环己酮和硝基苯甲醛的aldol反应,dr值最高达到90:10,ee最高76%。

The experimental and theoretical work on high pressure phase equilibria of the Benzene-Ethylene Alkylation system are undertaken at first.

本文首先通过实验测定与理论计算,得到了苯与乙烯反应系统的高压流体相平衡,确定了近临界区的大致范围,并结合反应系统,提出了操作上值得注意的因素。

TCB pervades in natural environment and industrial production. It causes a series of problems due to its longevity and amassment.

目的 1,2,4-三氯苯(1,2,4-Trichlorobenzene,1,2,4-TCB)广泛存在于自然环境和工业生产中,并长期存留和富集产生一系列环境问题。

Two: Synthesized a novel rhodamine derivative with a single amidogen, then analyzed and characterized the dye by 1H NMR and EI-MS.

二、以对硝基苯甲醛和八羟基久洛尼定为原料,合成了一种新型的罗丹明荧光染料,并通过核磁共振、质谱等手段对染料结构进行了表征。

Based on the changes in the spectrum characters of guest molecules producedthrough inclusion complex formation with cyclodextrins, we have carried out two aspects of investigation:First, the mechanisms for the host-guest recognition reactions have been studied, such as the interactions between 3-CD and curcumin, the main constituent of the rhizomes of the plant Curcuma longa, the recognition of p-CD towards rubidate, the effective component of the Chinese traditional medicine madder, and the reactions of p-CD towards the antileprotic drug dapsone and the antiinflammatory drug nabumetone: The formation of supramolecular complex between P-CD and guest molecule has been discussed and verified in virtue of multitudinous means such asultraviolet-visible absorption, fluorescence emission, infrared spectrogram and so on. The influence of addition of linear alcohols on the supramolecular system has been studied and the reason why the noncovalent interactions in the three-component system could result in a decrease in the apparent association constant of the inclusion complex has been revealed.

本论文基于环糊精对被包结客体光谱性质的改变,开展了两大方面的研究:β-环糊精对姜黄属植物根茎主要成分—姜黄素、中药茜草有效成分—茜草双酯、抗麻风药物氨苯砜及抗炎药物萘丁美酮的主-客体识别反应机制研究:借助超分子包合物的紫外吸收光谱、荧光光谱或红外吸收光谱等手段,通过多种方法探讨并验证了超分子包合物的形成;研究了直链醇的加入对超分子体系的影响,揭示了三元体系中非共价相互作用导致超分子包合物表观结合常数降低的原因:对超分子包结反应进行了热动力学研究,探讨了各热动力学参数的变化趋势并从熵焓互补的角度考察了超分子包结过程;通过荧光猝灭实验进一步揭示了水相中β-环糊精增敏客体荧光的本质原因,从而为超分子化学提供新的理论和研究方法。

Finally, N ethey[3,3 dimethyl spiralindoline naphthoxazine]was synthesized by the addition of 1 nitroso 2 naphthol also,the photochromic mechanism of the substance and its photochromic phenomenon in ethanol were studied.

报道了以苯肼和 3 甲基 2 丁酮为原料首先合成 2 ,3 ,3 三甲基吲哚,吲哚再与碘乙烷亲核取代,碱化得费舍尔碱,最后与 1 亚硝基 2 萘酚作用合成N 乙基 [3 ,3 二甲基螺吲哚啉萘并恶嗪 ]的全过程,并研究了该物质的变色机理以及在乙醇溶剂中的光致变色现

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