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The enthalpy change of the sorption process corroborates earlier findings that van der Waals forces dominate the sorption of S- and O-heterocyclic compounds such as thiophene, benzothiophene, benzofuran, and 2-methylbenzofuran.

吸附过程的热焓变化证实了早期的发现:硫和氧类杂环物质(像噻酚、苯并噻吩、苯并呋喃、3甲基苯并呋喃)的吸附主要以范德华力为主。

Finally, reacting II with PhNCO givethe compound 1-(6-nitrobenzimidazol-l-acetyl)-4-phenylsemicarbazide,III in the presence of〓 give the new cyclic compound 2-phenylamino-5-(6-nitrobenzimidazol- 1-methylene)-l,3,4-oxadiazole.

第三部分:以6-硝基苯并咪唑-1-乙酰肼为原料,分别与取代苯甲醛、苯乙酮及乙酰基二茂铁进行缩合反应,合成了10个新的6-硝基苯并咪唑-1-乙酰腙衍生物。

Results showed that phenanthrene posed a negligible risk when 95% species were not affected at 95% confidential level. Fluoranthene and pyrene posed higher risk where the probability of the quotients exceeded unit would be near 20%.

结果表明,太湖梅梁湾水源地沉积物的多环芳烃中,菲、荧蒽、芘、苯并[a]蒽、屈、苯并[a]芘、二苯并[a,h]蒽7种具有潜在风险;在保护95%的物种水平下,菲的风险最小,而荧蒽和芘风险较高,达20%。

Products: 3 - benzoyl-ethyl acrylate (97% min), acyl phosphorus acid methyl ester (98% min), P acyl three ethyl acetate (98% min), a phosphorus acid acyl The ethyl esters (98% min), 3 - bromine -1,3,4,5 - tetrahydrocannabinol -2 H-1-benzo-Aza Zhuo -2, 1 - naphthalene-tetrahydrocannabinol (98% min), 3,5 - dimethyl benzoyl chloride (99% min), 3,5 - dichloro benzoyl chloride (97% min), the ethyl benzoyl chloride (99% min), a TCA Ester (99.5% min), o-benzoyl methyl benzene (99% min), 4 - phenyl benzophenone (99% min): glacial acetic acid (99% min), methanol (99% min), liquid chlorine (99.5% min), caustic soda (30% min), isopropyl alcohol (99% min), anthranilic acid (99% min), dichloroethane (99% min ), Chunben (99% min), toluene 99% min

3-苯甲酰基丙烯酸乙酯(97%min)、磷酰基乙酸三甲酯(98%min)、磷酰基乙酸三乙酯(98%min)、磷酰基乙酸甲酯二乙酯(98%min)、3-溴-1,3,4,5-四氢-2H-1-苯并氮杂卓-2酮、1-四氢萘酮(98%min)、3,5-二甲基苯甲酰氯(99%min)、3,5-二氯苯甲酰氯(97%min)、对乙基苯甲酰氯(99%min)、氯乙酸甲酯(99.5%min)、邻苯甲酰基苯甲酸甲酯(99%min)、4-苯基二苯甲酮

The application of ultrasonic method in bored concrete pile detection;2. Suo′s method and ultrasonic method for extracting BPBenzo(aPyrene content from coke oven gas were introduced.

阐述了对焦炉煤气中苯并芘含量提取处理方法中的索氏法和超声法的两种方法,分析了两种方法测定相同含浓度苯并芘含量样品测试数据差异及产生原因,用实验数据分析说明了使用超声法作为测定焦炉煤气中苯并芘含量是一种最佳的处理方法。

Two benzothiazole ester compounds containing boron with different alkyl chain, Di-n-hexyl-[2-(2-benzothiazolylthio)] ethyl boric acid ester (BNS-1) and Dicyclohexyl-[2-(2-benzothiazolylthio)] ethyl boric acid ester(BNS-2), were synthesized and their tribological performance as additives in rapeseed oilwas investigated using a four-ball testing machine.

合成了两种含不同烷基链的含硼苯并噻唑酯类化合物,即二正己氧基-2-[(2-苯并噻唑基)硫代]乙氧基甲硼烷(BNS-1)和二环己氧基-2-[(2-苯并噻唑基)硫代]乙氧基甲硼烷(BNS-2)。

The sulfur compounds in VGO of SCO are mainly C3~7-dibenzothiophene,while those in FCC liquid products are short chain dibenzothiophene and a few alkylated benzothiophene and alkylated thiophene,and the percentages of these three sulfur compounds are 82.04%,13.42% and 0.56%,respectively,and they are difficult to be removed by hydrogenation.

结果表明,所含硫化物主要是C3~7-二苯并噻吩,而催化裂化反应后则以短侧链二苯并噻吩为主,还含少量烷基苯并噻吩和烷基噻吩,三者的质量分数分别为82.04%、13.42%和0.56%,均属于难以加氢脱除的含硫化合物。

According to the statistics of the content of methyldibenzothiophenes in 112 oil samples from China, the conter of methyldibenzothiophenes in marine oil is more than that in terrestrial oil if there is no TSR in oil.

根据对中国含油气盆地112个原油样品中似甲基二苯并噻吩含量统计发现,当原油无TSR作用时,海相原油的似甲基二苯并噻吩含量要大于陆相原油;陆相原油中,盐湖相原油的似甲基二苯并噻吩含量又大于淡水湖相。

ResultsThe major occupational hazardous factors in the project were coke dust, carbon monoxide, benzopyrene, benzene soluble matter and noise. The detection results showed that MAC of benzopyrene on coke pushed side, TWA of benzene soluble matter of two posts and noise level of coke griddle were overproof the rest were eligible.

结果 该扩建项目主要职业病危害因素是焦炭尘、一氧化碳、苯并芘、苯溶物、噪声等;检测结果示焦侧苯并芘的最高接触浓度、炉盖工、出炉工苯溶物的时间加权平均浓度及输焦振筛的噪声强度超标,其余检测点检测结果均符合国家职业卫生标准。

Firstly, phenyliodine diacetate was immobilized to the 2% cross-linked polystyrene or the liner polystyrene resin. The more iodine the resin had, the lower conversion to phenyliodine diacetate. We made our endeavor to extend the range of useful application of polystyrene supported phenyliodine diacetate in organic synthesis:(1) the reagent was used as an effective reagent of carbonyl regeneration from oximes and semicarbazones of ketones.(2) the reagent was also applied to the synthesis of 1, 3, 4-oxadiazoles, 1, 3-disubstituted-2-pyrazoline, 2-arylbenzoxazole from aldehyde N-acylhydrazones, aldehyde hydoazones and phenolic Schiff's bases respectively.

首先,我们以2%交联的聚苯乙烯和线性的聚苯乙烯树脂为载体,制备了聚合物负载的二醋酸碘苯,通过研究发现:(1)聚苯乙烯二醋酸碘苯是酮肟、缩氨脲有效的去保护试剂,不仅芳香酮,脂肪酮和α,β不饱和酮的肟、缩氨脲也能顺利转化为相应的酮,实现酮基的再生;(2)我们还利用此试剂,分别与醛的N-酰基苯、N-酰基苯腙及邻羟基芳亚胺反应,在温和的条件下发生成环反应,以良好的产率生成1,3,4-噁二唑、吡唑啉和二取代苯并噁唑等杂环化合物;(3)聚苯乙烯二醋酸碘苯还可有效地将邻羟基芳酮的酰腙经氧化、重排成1,2-二酰基苯。

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