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Then sodium ethoxide was used as base,the nucleophilic substitution of 2-pyrrolidone with the intermediate provided nefiracetam.

以碳酸钠为缚酸剂,摩尔比为1︰1的2,6-二甲基苯胺与氯乙酰氯反应合成了中间体2-氯-N-(2,6-二甲基苯基)乙酰胺;在强碱乙醇钠作用下,2-吡咯烷酮再与2-氯-N-(2,6-二甲基苯基)乙酰胺经亲核取代合成了目标化合物奈非西坦。

2A series of alternating polyamide-imideswith fluorenyl cardo structure was synthesized by "one-pot" polycondensation of cardo diamines,trimellitic anhydride and various aromatic diamines including p-phenylene diamine,m-phenylene diamine, 4,4\'-oxydianiline,3,4\'-oxydianiline,2,2-bis[4-(4-aminophenoxy)phenyl]propane, 2,2-bis[4-(3-aminophenoxy)phenyl]propane respectively using triphenyl phosphite as condensing agents.

采用&一锅法&(One—pot Synthesis),由Cardo二胺、偏苯三酸酐和不同二胺包括对苯二胺、间苯二胺、4,4\'—二氨基二苯醚、3,4\'—二氨基二苯醚、2,2—双[4—(4—氨基苯氧基苯基]丙烷和2,2—双[4—(3—氨基苯氧基)苯基]丙烷合成了一系列含有芴基Cardo结构的交替聚酰胺酰亚胺。

2A series of alternating polyamide-imideswith fluorenyl cardo structure was synthesized by "one-pot" polycondensation of cardo diamines,trimellitic anhydride and various aromatic diamines including p-phenylene diamine,m-phenylene diamine, 4,4\'-oxydianiline,3,4\'-oxydianiline,2,2-bis[4-(4-aminophenoxy)phenyl]propane, 2,2-bis[4-(3-aminophenoxy)phenyl]propane respectively using triphenyl phosphite as condensing agents.

采用&一锅法&O(来源:88AB57C论文网www.abclunwen.comne—pot Synthesis,由Cardo二胺、偏苯三酸酐和不同二胺包括对苯二胺、间苯二胺、4,4\'—二氨基二苯醚、3,4\'—二氨基二苯醚、2,2—双[4—(4—氨基苯氧基苯基]丙烷和2,2—双[4—(3—氨基苯氧基)苯基]丙烷合成了一系列含有芴基Cardo结构的交替聚酰胺酰亚胺。

The fluorescence spectra of 4- 5 '-p-biphenylyloxadiazolyl-2' benzyl ω-p-biphenylyl polymethylene car-boxylate have been determined. The results of experi-ment show that they can form not only intramolecularexciplex but also intermolecular excimer and triplex.

测定了ω-对联苯基多亚甲基羧酸4-[5'-对联苯基〓二唑-2']苄酯的荧光发射光谱,从实验结果得到,它们不但可以形成分子内激基复合物,而且可以形成分子间激基缔合物和三分子激基复合物。

In this paper,pyromellitic dianhydride,1,2,3,4-cyclobutanetetracarboxylic dianhydride,4[(4-aminophenyl)-bis(4-methoxyphenyl)methyl]benzeneamine,4-hexyloxy-biphenyl-3′,5′-diaminobenzoate,and additive ADD-34 were used to synthesize four PIs.

文章用均苯四甲酸二酐,4[(4-氨基苯基)-二(4-甲氧基苯基)甲基]苯胺,1,2,3,4-环丁烷四羧酸二酐,4-己烷氧基联苯酚-3′,5′-二胺基苯甲酸酯和不同含量的添加剂制备了聚酰亚胺液晶取向剂。

Organosilicon resin microparticles with phenyl and aminopropyl groups were prepared via the hydrolytic co-condensation of phenyltriethoxysilane,γ-aminopropyltriethoxysilane and diphenyldimethoxysilane under the catalysis of tetramethylammonium hydroxide.

在四甲基氢氧化铵水溶液的催化作用下,将苯基三乙氧基硅烷、γ-氨丙基三乙氧基硅烷和二苯基二甲氧基硅烷进行水解共缩聚制备氨丙基苯基有机硅树脂微粉。

The reaction of isomerized butadieneiron complex (I; R = Ph, p-tolyl) with triphenylphosphine and tri-Ph phosphite gave products II (same R; R1 = Ph, OPh), at -60 to -30? When I was reacted with triphenylphosphine in hexane at 60 to 70?

丁二烯二羰基铁配合物的异构化产物,C4H62FeC(OC2H5)Ar(1,Ar=苯基, 2, Ar=对甲苯基),在己烷溶液中于-60到-40℃与三苯膦或亚磷酸三苯酯反应生产产物3-6。

New compounds of the type of unsymmetrically substituted ureas are synthesized by a series of reactions of preparing organic isocyanates by Curtius rearrangement with aromatic amine.

以3 苯基 2 丙烯酸为原料,用Curtius重排的方法合成异氰酸酯,直接与芳香胺作用,合成了5 种N 取代苯基 N′苯丙烯基脲类化合物。

The axial interaction of vanadyl meso-tetraphenylporphyrin and nickel meso-tetraphenylporphyrin with different Lewis basic solvents was investigated by using an ultraviolet-visible spectrophotometric method.

应用紫外可见分光光度法研究了氧钒对四苯基卟啉和镍对四苯基卟啉与Lewis碱性溶剂的轴向配位作用。

First, by using p-methoxybenzaldehyde , p-hydroxybenzaldehyde and pyrrole as raw materials, 5-(p-hydroxyphenyl)-10,15,20-tri(p-methoxyphyenyl)porpyrin was prepares under acidity condition and the let reacted with benzoyl chloride, o-nitrobenzoyl chloride, m- nitrobenzoyl chloride and p- nitrobenzoyl chloride respectively under alkalinity condition with DMF as solvent.

以对-甲氧基苯甲醛、对-羟基苯甲醛和吡咯为原料,在酸性条件下合成了5-对羟苯基10,15,20-三对甲氧苯基卟啉,再以该化合物为原料分别与苯甲酰氯、邻-硝基苯甲酰氯、间-硝基苯甲酰氯和对-硝基苯甲酰氯反应,在碱性条件下以DMF为溶剂合成了四种目前尚未见文献报道的对-甲氧基卟啉硝基苯甲酸酯类化合物。

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According to the clear water experiment, aeration performance of the new equipment is good with high total oxygen transfer coefficient and oxygen utilization ratio.

曝气设备的动力效率在叶轮转速为120rpm~150rpm时取得最大值,此时氧利用率和充氧能力也具有较高值。

The environmental stability of that world - including its crushing pressures and icy darkness - means that some of its most famous inhabitants have survived for eons as evolutionary throwbacks, their bodies undergoing little change.

稳定的海底环境─包括能把人压扁的压力和冰冷的黑暗─意谓海底某些最知名的栖居生物已以演化返祖的样态活了万世,形体几无变化。

When I was in school, the rabbi explained everythingin the Bible two different ways.

当我上学的时候,老师解释《圣经》用两种不同的方法。