苯基的

The photoproducts of CCU in organic solvents have also been identified with HPLC- and GC-MS. The photoproducts identified in methanol are isocyanato bezene, 4-chlorophenyl isocyanate, 2-chloro benzamide, chlorobenzene, 4-chlorophenyl urea, N-phenyl methylcarbamate, N-(4chlorophenyl) methylcarbamate, and 2-chloro-N-(4-chlorophenyl) benzamide.

对灭幼脲在各种有机溶剂中的光解产物作HPLC/UV和GC-MS鉴定，发现其在甲醇中的光解产物含有：异氰酸苯酯、对氯苯基异氰酸酯、邻氯苯甲酰胺、氯苯、对氯苯基脲、N-苯基氨基甲酸甲酯、N-氨基甲酸甲酯、以及N-邻氯苯甲酰胺等。

This work, concentrated on the asymmetric allylation of aldehydes controlled by different chiral auxiliaries prepared from rotational pure tartaric acid, can be divided into three parts.The first part aims to review the developments of chiral drugs and asymmetric synthesis, from which derived the present research topic backgrounds and works.Synthesis and applications of allylation from aldehydes are the second part of the thesis. By optimizing the reaction conditions, such as solvents, temperature, time and chiral auxiliaries like N,N\'-dibenzyl tartamide, N,N\'-p-dimethylphenyl tartamide, N,N\'-o-dimethylphenyl tartamide, N,N\'-o-dichlorophenyl tartamide, N,N\'-a-dinaphyl tartamide, N,N\'-dicyclohexyl tartamide and N,N\'-diphenyl tartamide, ideal experimenttal conditions are obtained according to HPLC monitoring, as well as the auxiliaries\' recoveries experiments. Starting from benzaldehyde and 3-bromopropaldehyde, N,N\'-dibenzyl tartamide is considered the best auxiliary in this reaction.

本文介绍了醛的不对称烯丙基化反应，以光学纯酒石酸为原料，研究了不同构型手性配体在醛的烯丙基化反应中的立体选择性，全文共分三部分十个章节：第一部分对当前手性药物和手性技术进行了概述，并由此展开了本文的研究背景和任务；第二部分为有机合成部分，对醛的不对称烯丙基化反应进行了深入探讨，以苯甲醛为原料对反应条件进行优化，在优化的反应条件下对制备的七种可回收手性酰胺配体(N-苄基酒石酸二酰胺、N-对甲苯基酒石酸二酰胺、N-邻甲苯基酒石酸二酰胺、N-邻氯苯基酒石酸二酰胺、N-a-萘基酒石酸二酰胺、N-环己基酒石酸二酰胺和N-苯基酒石酸二酰胺)进行筛选，优化配体回收实验条件，最终确定出N-苄基酒石酸二酰胺在苯甲醛的不对称烯丙基化反应中具有较大优越性，结晶回收的手性配体光学纯度保持不变。

Three novel hemicyanine derivatives,-N-(4-sulfopropyl)-4-[2-(4- N, N-diethylaminophenyl)-ethenyl]pyridinium,-N-(4-suMbbutyl)- 4-[2-(4-N, N-diethylaminophenyl)ethenyl]pyridinium (EPS4), and-N-(4- su)fobutyl-4-[2-(4-N, N-diethylaminophenyl)ethenyl]quinolinium (EQS4) with different length of alkyl chains between the adsorbing group (RSO3-) and the chromophore group, were synthesized and their photophysical and photoelectrochemical properties were studied.

设计合成了具有不同空间位阻的吡啶盐类和喹啉盐类半菁染料-N-(4—磺酸根丙基)-4-[2-4（4-N，N-二乙基氨基苯基）乙烯基]吡啶鎓盐，-N-4-磺酸根丁基）-4-[2-(4-N，N-二乙氨基苯基）乙烯基]吡啶鎓盐（EPS4）和-N-（4-磺酸根丁基）-4-2-（4-N，N-二乙基氨基苯基）喹啉鎓盐（EQS4），研究了它们的光物理性质，并将它们用作TiO2纳米晶电极的光敏化剂引入光电化学电池中。

Atorvastatin calcium, the substance known by the chemical name (R--2 -(4-fluorophenyl)-b, ddihydorxy-5 -(1-methylethyl)-3-phenyl-4 -(phenylamino carbonyl-1H -pyrrole-1 -heptanoic acid hemi calcium salt is known as HMG-CoA reductase inhibitor and is used as an antihypercholesterolemic agent.

阿托伐他汀钙，已知化学名为(R--2-(4-氟苯基)-b，d-二羟基-5-(1-甲基乙基)-3-苯基-4-(苯基氨基羰基-1H-吡咯-1-庚酸半钙盐的物质，已知其为HMG-CoA还原酶抑制剂，并用作抗高胆固醇药。

In the third chapter, the synthesis of5-[(1"S)-1",2"-diacetyl-oxyethyl]-1-phenylpyrazol-3-carboxaldehyde oxime(2) from5-[(1"S)-1",2"-diacetyl-oxyethyl]-1-phenylpyrazol-3-carboxaldehyde(1) and phenyl-hydrazine were introduced firstly. The synthesis of nine dioxapyrrolino[3,4-c]pyrazoles containing chiral pyrazolyl moiety(6a-i) from 2 with N-substituted-phenylmaleimide by nonmetal oxidant IBD-initiated intermolecular 1,3-dipolarcycloaddition was described in detail.

第三章首先以5-[(1′S)-1′，2′-二乙酰氧基乙基]-1-苯基吡唑-3-醛(1)和苯肼为原料，合成了化合物5-(1′S)-1′，2′-二乙酰氧基乙基1-1-苯基吡唑-3-醛-苯腙(2)；再用化合物(2)与N-取代苯基马来酰亚胺反应，利用无金属氧化剂—IBD引发1，3-偶极反应，发生分子间的环加成，合成了9种新型手性吡唑连二氧代吡咯啉并

Four phenanthroline derivatives of 2-phenyl-imazole [5,6-f]-(1,10) phenanthroline, 2-(4-hydroxy-phenyl)-imazole [5,6-f]-(1,10) phenanthroline, 2-(4-methoxyl-phenyl)-imazole [5,6-f]-(1,10) phenanthroline and 2-(4-formacyl-phenyl)-imazole [5,6-f]-(1,10) phenanthroline were synthesized, and twelve new complexes of europium were then synthesized with these phenanthroline derivatives as the first ligand and butyric acid, n-heptanoic acid and tetradecanoic acid as the second ligand.

合成2-苯基咪唑并[5，6-f]邻菲咯啉，2-（4-苯酚）咪唑并[5，6-f]邻菲咯啉，2-（4-甲氧基苯基）咪唑并[5，6-f]邻菲咯啉和2-（4-甲酰基苯基）咪唑并[5，6-f]邻菲咯啉等4种邻菲咯啉衍生物，并分别以其为第一配体，选择丁酸，正庚酸和十四酸为第二配体合成12种新的铕－邻菲咯啉衍生物－脂肪酸荧光配合物。

Four phenanthroline derivatives of 2-phenyl-imazole [5, 6-f]-(1, 10) phenanthroline, 2-(4-hydroxy-phenyl)- imazole [5, 6-f]-(1, 10) phenanthroline, 2-(4-methoxyl-phenyl)-imazole [5, 6-f]-(1, 10) phenanthroline and 2-(4-formacyl -phenyl)-imazole [5, 6-f]-(1, 10) phenanthroline were synthesized, and twelve new complexes of europium were then synthesized with these phenanthroline derivatives as the first ligand and butyric acid, n-heptanoic acid and tetradecanoic acid as the second ligand.

摘 要：合成2-苯基咪唑并[5， 6-f]邻菲咯啉，2-(4-苯酚)咪唑并[5， 6-f]邻菲咯啉，2-(4-甲氧基苯基)咪唑并[5， 6-f]邻菲咯啉和2-(4-甲酰基苯基)咪唑并[5， 6-f]邻菲咯啉等4种邻菲咯啉衍生物，并分别以其为第一配体，选择丁酸，正庚酸和十四酸为第二配体合成12种新的铕-邻菲咯啉衍生物-脂肪酸荧光配合物。

A series of lanthanide complexes (Ln = Er, Nd, Yb) with infrared emission properties were designed and synthesized by using different anionic ligands [1 -phenyl-3-methyl-4-(4-tertbutylbenzoyl)-5-pyrazolone and l-phenyl-3-methyl-4--5-pyrazolone and 2-naphtoyl trifluoroacetone] and netural ligands (2,2-dipyridine, phenanthroline, triphenylphosphine oxide and water). Three crystal structures of these complexes were obtained and structure studied, and the properties of photoluminescence and fluorescent lifetime were studied in detail.

我们通过选用不同的第一配体[1-苯基-3-甲基-4-(4-异丁酰基)-5-吡唑酮，1-苯基-3-甲基-4-(4-叔丁基苯甲酰基)-5-吡唑酮和2-萘基三氟乙酰丙酮]和第二配体(2，2-联吡啶，邻菲啰啉，三苯基氧膦)合成了16个稀土红外配合物(Ln=Er，Nd，Yb)，获得了其中三个配合物的单晶结构，研究了这些稀土红外配合物的光致发光和荧光寿命等性质。

By synthesizing the hapten LBc starting from the metabolite of bifenthrin (2-methyl-3-phenylbenzyl alcohol), LBs (2-methyl[1,1-biphenyl]-3-ylmethyl 3-carboxyl-2,2-dimethylcyclopropane carboxylate and Lby (2-methyl[1,1-biphenyl]-3-ylcarboxylic acid , Three haptens were praparaed which were used in next step.

利用联苯菊酯的代谢物联苯醇合成了联苯菊酯的半抗原LBc(2-甲基-3-苯基苄基氧基羰基丙酸)、LBs(2-甲基-3-苯基苄基-3-羧基一2，2-二甲基环丙烷羧酸)和LBy(2-甲基-3-苯基苯甲酸)。

The main work of the article was to synthesize a suitable monomer, bis(4-carboxyphenyl)phenyl phosphine oxide, as the retardant for poly fibre. The procedures were divided into three steps: dichloride phenyl phosphine oxide was synthesized and bis(4-methyl phenyl)phosphate oxide was prepared from DCPP by Friedel-Crafts reaction.

双苯基氧化膦是一种适用于PET纤维阻燃改性的新型有机磷阻燃剂，本文主要研究了其合成工艺，整个合成路线分为三步，通过Friedel-Crafts烷基化反应制备了苯基二氯化膦，进而通过Friedel-Crafts酰基化反应合成了双苯基氧化瞵，经氧气、高锰酸钾氧化得到了产品BCPPO。

What would he tell Judith and the children?

他将怎样告诉朱迪丝和孩子们呢？

I this is at that time, the opinion with peacockish true girl is full of in a heart.

这就是当时的我，一个心中布满虚荣的女孩子真实的想法。