苯基的

Based on the addition of vinyl magnesium bromide to the chiral non-racemic synthon 2 derived from-1, an enantioselective total synthesis of-3, the antipode of marine alkaloid halitulin 10 steps, overall yield: 5.3% from (R-1 was achieved using aza-Claisen...

取得的主要结果如下：一、从-苯基甘氨醇1出发，通过已知的哌啶手性合成砌块2的加成反应，建立了经aza-Claisen重排反应进行海洋生物碱halitulin手性分子片断的对映体--isohaliclorensin 3不对称合成的路线。

The ternary complexes of Ln with 8-hydroxyquinathroline and cinchophen (2-phenyl-quinoline-4-carboxylic, HL) had been synthesized and their composition, solubility, molar conductance, UV, IR, 1HNMR and XPS studied.

合成了3种辛可芬(2-苯基喹啉-4-甲酸，HL)与8-羟基喹啉的稀土三元配合物，通过元素分析，摩尔电导，UV，IR，1HNMR等的研究，确定配合物的化学组成为Ln3·H2OLn=Ce(Ⅲ，Nd，Sm，观察了它们的抗炎作用、半数致死量(LD50)和在霜剂中的配伍稳定性

The varying tendencies of partition coefficients of some compounds in aqueous or nonaqueous solvent systems by calculating the phase equilibria with universal quasichemical functional group activity coefficient model are predicted. These compounds included saturated and unsaturated fatty acids ethyl esters,N2,4dinitrophenylamino alcohols, pnitrophenyl glucosides and so on, with simple structures and much differences in polarity.

以饱和及不饱和脂肪酸乙酯、2，4二硝基苯胺基脂肪醇和对硝基苯基葡萄糖甙等结构较为简单、极性差别较大的溶质系列为研究对象，应用修正的通用基团活度系数模型，通过相平衡计算，预测了它们在含水或不含水的溶剂体系中分配系数的变化趋势，并与前人的工作进行了对比。

First, the precursor polymer with azobenzene groups on main-chain was obtained by condensation polymerization between 4,4'-dihydroxyazobenzene and N,N-(2-bromoethyl)aniline through Williamson reaction. Then the azo polymer containing azobenzene groups both on main-chain and side-chain was prepared through an azo-coupling reaction between the precursor polymer and the diazonium salt of 4-nitroaniline.

设计并合成了一种新型的主侧链均含偶氮生色团的聚合物，首先通过4，4'-二羟基偶氮苯与N，N-二溴乙基苯胺之间的Williamson反应缩聚得到主链含偶氮苯基团的先驱聚合物，再通过重氮偶合反应得到目标产物，并利用核磁共振、红外光谱、紫外可见光谱、热分析等手段确认了所制备聚合物的结构。

Whenpyridine was used as reductive decomposing agent, the expecting cholest-4-en-3,6-dione-22-al was obtained. However, when Zn/HOAc was used to decomposethe ozonide, C-4,5 double bond was further reduced to give cholest-3,6-dione-22-al as main product. 2 For the side-chain construction of compound (1), the solid-liquid phase-transfer Wittig reaction was used. When (3-methyl-2-oxobutyl)-triphenylarsonium bromide was used as reagent, the reaction can be carried out inmild reaction condition and the yield is higher than that when phosphorane wasused.

但使用Zn／HOAc作为分解剂时，却得到其氢化产物胆甾-3， 6-二酮-22-醛；2在甾体支链引入过程中，采用固-液相转移Wittig反应的方法，用(3-甲基)-2-氧丁基三苯基溴化胂作为试剂，反应在非常温和的条件下便可完成，而且产率比传统采用膦烷的方法更高；3在对某些甾酮化合物的选择性还原反应研究时，发现在〓还原体系中，当加入某些金属离子后，反应有更好的区域选择性和立体选择性。

Approved the substitution effect of 2, 2-diphenylnaphthalinspyran on the phenyl ring, and clarified the property of the compound is not determined only by the pyran planarity and C-O bond, it not only changed the theoretic basis, but also provide a way to find materials with new properties.

经单晶分析证实了2，2-二苯基萘并吡喃的苯基上取代基的种类及其位置对光致变色性质的重要影响，改变了只有吡喃平面性及其C-O影响性质的观点，不仅改变了理论依据，还指导有望开发出新性质材料的方向。

The pyrimidine lead compound is obtained via herbicidal activity screen. The optimization of lead compound leads to find the good pyrimidine benzylamine candidates with highly effective herbicidal activity. The novel herbicidal mechanism of pyrimidine benzylamine is put forward. N-(2-bromophenyl)-2-(4, 6-dimethoxypyrimidin-2-yloxy)benzylamine (103-1) has potential as a new selective post-emergent herbicide in oilseed rape.

通过系统的研究工作，发现了具有除草活性的嘧啶先导结构，经结构优化，筛选出具有高除草活性的嘧啶苄胺类优选结构，发现并提出了此类化合物的除草作用新机理，最终经田间试验证实了N-(2-溴苯基)-2-(4，6-二甲氧基-2-嘧啶氧基)苄胺(103-1)可作为超高效油菜田除草剂进行工业性的研究与开发。

Mol/L. 3 A study on the ECL of acridinum esters including 10--acridinium-9-carboxyl-phenyl-ester iodinate and 10-methyl-9-(p-formylphenyl)-acrdiniumfluorosulphonate in neutral solution was carried out. It was found both CACPEI and MFPA give strong ECL in KNO〓 solution when an appropriate voltage was applied on Pt electrode.

本文研究了碘化10-乙羧基吖啶-9-羧酸苯酯和对甲酰基苯基-10-甲基吖啶-9-羧酸酯氟磺酸盐的ECL行为，发现在中性KNO〓介质中，这两种吖啶酯都能在一定的电位下产生很强的ECL信号，考察了各种影响因素，确定了发光的最佳条件，探讨了可能的发光机理。

Pymetrazine is chosed as the lead compound, and 21 compounds were firstly designed and synthesized. These compounds were characterized by introducing phenyl derivatives with different functional groups to replace pyridine ring with the isosteric principle and the method of homogeneous synthesis and reasonable biologically designing in order to find new compounds with potential biological activity. These compounds were confirmed by IR, H NMR and MS spectra.

本文选取吡蚜酮为先导化合物，运用电子等排理念，综合类同合成、生物合理设计的方法，引入含有不同官能团的苯基衍生物替代吡蚜酮的结构中心吡啶环，设计合成了21个未见文献报道的化合物，寻找具有潜在生物活性的新三嗪酮类化合物，通过核磁共振氢谱、红外光谱、质谱等手段进行了结构表征，并验证正确。

Tamarense was studied. 5 mg·L~-1 of N-phenyl-2-naphthylamine was showed to have 50% inhibitory rate on A. tamarense after 3 days. 70 μL·L~-1 of linoleic acid appeared 40% inhibition rate on A. tamarense.70 μL·L~-1 of pelargonic acid had 85% inhibition rate at the 3 rd day with some increase in cell density later on.

结果表明，浓度高于5 mg·L-1以上的N-苯基-2-萘胺，3 d后能保持对塔玛亚历山大藻抑制率超过50%；浓度为70μL·L-1的亚油酸对塔玛亚历山大藻的抑制率约为40%；浓度为70 μL·L-1的壬酸第3天可以达到85%的抑藻率，但随后藻密度有反弹。

According to the clear water experiment, aeration performance of the new equipment is good with high total oxygen transfer coefficient and oxygen utilization ratio.

曝气设备的动力效率在叶轮转速为120rpm～150rpm时取得最大值，此时氧利用率和充氧能力也具有较高值。

The environmental stability of that world - including its crushing pressures and icy darkness - means that some of its most famous inhabitants have survived for eons as evolutionary throwbacks, their bodies undergoing little change.

稳定的海底环境─包括能把人压扁的压力和冰冷的黑暗─意谓海底某些最知名的栖居生物已以演化返祖的样态活了万世，形体几无变化。