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Associating with the increasing FPT, the content fluorene and alkaned fluorene is decreasing, while benzyl-fluorene is increasing.

试验物料热解焦油的芳烃中二环芳烃中萘和其甲基衍生物的含量是微量的,但萘的苯基衍生物比较高。

Analogous complexes 3a" and 4a"= CpRu(PPh32, Ar = para-C6H4OMe containing methoxy group at the para-position of gem-diphenyl group were similarly obtained from protonation of the corresponding acetylide complexes via formation of vinylidene intermediate. But only complex 3a'= CpRu(PPh32, Ar2 = fluorenyl is stable in solution, and decomposed to unidentified complex when heated to reflux in THF. Deprotonation of complex 4a in the presence of base gives neutral acetylide complex 6a.

在两个相邻位置的苯基对位位置上接有一甲氧基的衍生物3a&和4a&也可利用类似的质子化反应合成,唯有错合物3a'= CpRu(PPh32, Ar2 = fluorenyl 可以稳定於溶液中,不会进行上述反应,如将其溶於四氢呋喃溶液加热至沸腾则会分解产生无法鉴定的化合物。

A new functional electroluminescent copolymer is reported in which chromophores and hexa segments alternate along the polymer backbone.

采用Wittig反应合成了一种分子主链由烷氧基取代的1,4二苯乙烯基苯聚对亚苯基亚乙烯基(PPV的三个单元的齐聚物与柔性隔离链段五缩六乙二醇组成的交替型蓝绿色发光共聚物。

The results showed that under 200 W power, in the present of various alkalis, e.g. Na2CO3, NaF, KF, NaHCO3, and DMF-H2O (V∶V=5∶3) used as solvent, PVC-TETA-Pd could catalyze sodium tetraphenylborate to react quantificationally with iodobenzene in 20 min without inert gas protection, and all the phenyl g...

实验发现:在微波功率为200W时,在Na2CO3,NaF,KF,NaHCO3等多种碱的存在下,以DMF的水溶液(V∶V=5∶3)为溶剂,在无惰性气体保护下,PVC-TETA-Pd催化四苯硼钠与碘代苯在20min内即可定量反应,与常规加热方式相比,节省了大量时间;同时也证明了四苯硼钠的四个苯基均可参与Suzuki偶联反应;该催化剂回收再利用3次后,仍具有较高的催化活性。

Synthesis and chracterization of high ordered Ladderlike Polysilsesquioxane Since Brown first reported the synthesis of ladderlike polyphenylsilsesquioxane via "thermal equilibration polymerization"in 1960, it is still a question whether ordered ladderlike polysilsesquioxane can be prepared or not all over the world till now.

第一部分高规整性梯型聚硅氧烷的合成1960 年Brown 首次报道了用&热平衡缩聚法&合成含梯形结构的聚苯基倍半硅氧烷,但该报道受到许多研究者的质疑。至今40 多年来对能否合成真正规整梯形结构的聚倍半硅氧烷一直存在着争议。

With the growth cycle short thinnerthan chermcal as a disposable chopsticks are generally considered to be the best choice, the mandatory moldproof dampproof health indicators is the focus of the bamboo chopsticks standard as qualified water content is less than 10%, at the same time on the o-phenylphenol and other antimold are mandatory limits is less than 10 mg/kg, and so on.

以生长周期短的竹子作为一次性筷子的原料被普遍认为是最佳选择,强制性的防霉防潮卫生指标是竹筷标准的重点,如强制限定含水率小于10%,同时对邻苯基苯酚等防霉剂均强制限量每千克小于10毫克等。

Since OPP and its sodium salt are nontoxic, odorless, of high phytocidal activity, good disinfecting and mould-inhibiting properties, they can be used as antiseptic, used for fruits and vegetables especially mandarins to inhibit mould, and used to treat lemons, pineapples, melons, apples, pears, peaches, tomatoes, etc, to protect them from putrefying to the greatest extent.

由于邻苯基苯酚及其钠盐除莠活性很高,并且有广谱的杀菌除霉能力,而且无毒无味,是较好的防腐剂,可用于水果蔬菜的防霉保鲜,特别是用于柑桔类的防霉,也可以用于处理柠檬、菠萝、瓜、果、梨、桃、西红柿等,可使腐烂降到最低限度。2。

The structure model of 5, 10, 15, 20-meso-tetraphenylporphyrin has been optimized by the first-principle calculation. The result shows that the angle between the benzenes and the porphine plane is 55°, and the rotation of the benzenes lead to a slight bending of the porphine plane.

利用第一性原理确定了四苯基卟啉分子的结构模型,结果表明分子中的苯环与卟吩骨架的夹角为55°,且笨环的自由旋转导致卟吩骨架略微偏离平面形状。

A C-C bond type radical initiator i.e. 1,1,2,2-tetraphenyl-1,2-ethanediol and a S-S bond type thermal iniferter, i.e., tetraethyl thiuram disulfide were used to consist of new reverse ATRP initiation systems TPED/FeCl3/PPh3 and TD/FeCl3/PPh3, respectively."Living"/controlled polymerizations of a polar monomer MMA and a non-polar monomer St were investigated with the initiation systems as well as other new initiation systems; behavior of vinyl polymerization with a new asymmetrical C-C bond type thermal monomeric iniferter was studied also.

前者选用C-C键型的自由基聚合引发剂1,1,2,2-四苯基-1,2-乙二醇、S-S键型的热iniferter二硫化四乙基秋兰姆组成新引发体系TPED/FeCl3/PPh3、TD/FeCl3/PPh3,研究这些引发体系引发MMA、 St聚合的&活性&/控制聚合行为,同时研究一些其他新引发体系;后者合成了一种新的非对称C-C键型热引发转移终止剂,并研究其自由基聚合规律。

In this paper, the improvement of synthetic method of 2-acetylaminotropone is introduced. 3-Acetyltropolone reacted with low concen-tration methylamine solution and solvent was directly evaporated in reduce pres-sure to give 2-acetyl-7 -methylaminotropone in good yield. The compound reacted with phenyltrimethylammonium tribromide to give two new compounds.

本文介绍2-乙酰基-7-甲胺基酮合成方法的改进——用挥发性小的低浓度甲胺溶液与3-乙酰基酚酮反应;和采用直接减压蒸除溶剂法分离产品,得到较好产率的2-乙酰基-7-甲胺基酮;用化合物与三溴化苯基三甲铵反应,得到两种至今未见文献报道的新化合物。

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