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Analogous complexes 3a" and 4a"= CpRu(PPh32, Ar = para-C6H4OMe containing methoxy group at the para-position of gem-diphenyl group were similarly obtained from protonation of the corresponding acetylide complexes via formation of vinylidene intermediate. But only complex 3a'= CpRu(PPh32, Ar2 = fluorenyl is stable in solution, and decomposed to unidentified complex when heated to reflux in THF. Deprotonation of complex 4a in the presence of base gives neutral acetylide complex 6a.

在两个相邻位置的苯基对位位置上接有一甲氧基的衍生物3a"和4a"也可利用类似的质子化反应合成,唯有错合物3a'= CpRu(PPh32, Ar2 = fluorenyl 可以稳定於溶液中,不会进行上述反应,如将其溶於四氢呋喃溶液加热至沸腾则会分解产生无法鉴定的化合物。

E. The low enantioselectivity may be due to the background reaction of diphenylzinc with imines.

的光学纯度和90%的化学收率,估计低对映选择性可能是苯基锌具有较强的背景反应。

Benzyl isopropyl ether also forms CCT complex with oxygen on the benzene ring like phenyl isopropyl ether, but it is easy to oxidize since charge transfer and 〓 transfer may occur at the methylene group adjacent to the benzene ring, which result in the oxidation of the methylene group.(4) The 〓-CCT complex and the initial dark oxidation mechanism of poly were studied.

虽然苄基异丙醚也以苯环与O〓形成CCT复合物,但它却容易发生暗氧化,这是由于与苯基相连的是亚甲基,此时电荷转移发生在苯环与亚甲基之间,引起亚甲基的氧化,而不是异丙基的氧化。

Since the effect of ultraviolet radiation on synthetic polymers is similar to its effect on the human skin, it is not surprising that ultraviolet stabilizer s such as phenyl salicylate have been used for many years in suntanning lotions.

因为紫外辐射对合成的聚合物的作用类似于它对人体皮肤的作用,所以紫外线稳定剂如水杨酸苯基酯多年来一直被用作防晒液也就不足为奇了。

Since the effect of ultraviolet radiation on synthetic polymers is similar to its effect on the human skin, it is not surprising that ultraviolet stabilizers such as phenyl salicylate have been used for many years in suntanning lotions.

因为紫外辐射对合成的聚合物的作用类似于它对人体皮肤的作用,所以紫外线稳定剂如水杨酸苯基酯多年来一直被用作防晒液也就不足为奇了。

A series of sulfonated poly(arylene thioether phosphine oxide)s with various degrees of sulfonation was prepared by polycondensation of 4,4'-thiobisbenzenethiol with the mixture of sBFPPO and BFPPO at different ratios. The effect of IEC on the properties of the products was studied.

以BFPPO、sBFPPO和4,4'-二巯基二苯硫醚为单体,通过改变BFPPO/sBFPPO的配比,合成了一系列不同磺化度的磺化聚芳硫醚三苯基氧膦,考察了IEC对产物性能的影响。

In addition to cationic gold complexes bearing bulky biphenyl phosphines, a gold complex with tris(2,6-di-tert-butylphenyl)phosphite is exceptionally reactive as a catalyst for this reaction.

在与有大体积连苯基膦配体的金正配合离子加成反应中,三(2,6-二叔丁基苯)亚磷酸盐的金配合物异常活泼并充当该反应的催化剂

Three composites of the different fibers with epoxy resin matrix are prepared and the corresponding unilateral fiber reinforced winding ring specimens are fabricated. The mechanical poperties of the composites including tensile strength, modulus and three point interlaminar shear strength are tested.

据文献 [2 ]介绍,PBO(聚对亚苯基苯并双口恶唑)是含杂环的苯氮聚合物的一种,它是采用二氨基间苯二酚和对苯二甲酸在多磷酸中聚合、采用空气间隙湿法纺丝法进行纺丝而制得的。

In the third step, when the ratio of racemic ester to benzenesulfonyl chloride to triethylamine to catalyst 4-DMAP is 1:1:1:0.1 in 10℃, the yield is 82.9% and high purity is obtained by crystallisation.

在第三步磺酰化反应中,得到合成消旋2-苯磺酸基-2(2-氯苯基)乙酸甲酯的较佳反应条件为邻氯扁桃酸甲酯:苯磺酰氯:三乙胺=1:1:1,催化剂4-DMAP用量为摩尔反应物的10%,反应温度为10℃,收率为82.9%,同时用结晶方法获得高纯度的产物。

Have carried on testing service for nearly 200 hazardous substances, including Asbestos, PAHs, Phthalates, NP/NPEO, AZO, CFC/HCFC/Halons, PVC, PCB, PCT, PCN, CP, Mirex, TPT/TBT/TBTO, Formaldehyde, Heavy metals, can help your products in fully compliance with 'green purchase' request of international buyers.

开展除RoHS以外的近200种有害物质检测业务,包括石棉、多环芳烃、邻苯二甲酸盐、壬基苯酚/壬基苯酚乙氧基化合物、偶氮染料、氟氯烷烃/氢氯氟烷烃/海龙、聚氯乙烯、多氯联苯、多氯三联苯、多氯化萘、短链氯化石蜡、灭蚊灵、三苯基锡类/三丁基锡类/二的氧化物、甲醛、重金属等,涉及范围完全满足各国际买家的&绿色采购&要求。

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According to the clear water experiment, aeration performance of the new equipment is good with high total oxygen transfer coefficient and oxygen utilization ratio.

曝气设备的动力效率在叶轮转速为120rpm~150rpm时取得最大值,此时氧利用率和充氧能力也具有较高值。

The environmental stability of that world - including its crushing pressures and icy darkness - means that some of its most famous inhabitants have survived for eons as evolutionary throwbacks, their bodies undergoing little change.

稳定的海底环境─包括能把人压扁的压力和冰冷的黑暗─意谓海底某些最知名的栖居生物已以演化返祖的样态活了万世,形体几无变化。

When I was in school, the rabbi explained everythingin the Bible two different ways.

当我上学的时候,老师解释《圣经》用两种不同的方法。