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PBO spinning solution was prepared from 4,6-diaminoresorcinol diphosphate in polyphosphoric acid by solution poly-condensation.

将稳定化后的单体和对苯二甲酸在PPA的介质中进行缩聚反应可以得到具有高聚合度(特性粘数=17dL/g)的聚亚苯基苯并二嗯唑。

Promoted by metal dysprosium, aldehydes and ketones could react smoothly with propargyl bromide to afford the corresponding homopropargylic alcohols in good to excellent yields, and no allenic alcohol s were found.

当用苯基炔丙基溴代替炔丙基溴与醛、酮反应时,主要得到了相应的连二烯醇,而没有发现高快丙醇的存在,由此提出了六元环过渡态的反应机理

There was not few report about 5-amino-3-cyan-N-(2,6-dichloro-4-trifluoromethylphenyl)pyrazole in the domestic , so that the whole synthetic course of 5-amino-3-cyan-N-(2,6-dichloro-4-trifluoromethylphenyl)pyrazole was studied and the intermediate with feasible eco...

因此,研究5-氨基-3-氰基-N-(2,6-氯-4-三氟甲基苯基)吡唑的合成,探索其中间体经济可行的合成路线,具有很好的社会效益和经济前景。

It was reported that benzylidenemalononitrile did not react with 1-benzyl-1,4-dihydronicotinamide. However, similar reaction easily takes place under the same condition when the phenyl group is replaced by the pyridyl group.

本课题组之前报道了苯亚甲基丙二腈在室温下不能被BNAH所还原,本论文将反应底物中的苯基换成吡啶基之后,在同样的实验条件下,反应可以比较顺利的进行。

In our work, as a preliminary experiment, the N-phenacylisoquinolinium bromide was reacted with methlhydrazine in refluxed acetic acid. Unexpectedly, 2-methyl-1,2,3-triazole was obtained. The further study of this reaction led to a more simple starting material,α-bromoacetophenone to react with methylhydrazine, obtaining the same product.

我们在研究N-苯乙酰异喹啉溴化物与甲肼在冰醋酸中的反应时,意外地得到了2-甲基-4-苯基-1,2,3-三氮唑,经过进一步的研究发现α-溴代苯乙酮与甲肼也能得到同样的产物。

Also, the type of dispersion of four gasliquid-liquid systems: air-decane-aqueous solution of sodium sulfite and surfactant, airmixture of decane and dodecene-aqueous solution of rhodium complex, ligand, and surfactant, air-mixture of decane, dodecene and tridecyl aldehyde-aqueous solution of rhodium complex, ligand and surfactant, and air-mixture of decane and dodeceneaqueous solution of trisodium salt of tri (m-sulfophenyl) phosphine, and surfactant is determined by electric conductivity.

本文采用电导率测量的方法实验研究了空气—正癸烷—亚硫酸钠和十六烷基三甲基溴化铵水溶液、空气—正癸烷和1-十二碳烯混合物—铑膦络合物催化剂和十六烷基三甲基溴化铵水溶液、空气—正癸烷、1-十二碳烯和十三醛混合物—铑膦络合物催化剂和十六烷基三甲基溴化铵水溶液、空气—正癸烷和1-十二碳烯混合物—三间磺化苯基膦三钠盐和十六烷基三甲基溴化铵水溶液四个三相体系的液液分散特性。当有机相与水相体积比分别为7/3、1/1和3/7时,前三个体系均形成水包油型分散,并有稳定的乳状液生成。

In this article, three novel cyclopalladated ferrocenylimine triphenylphosphine complexes 2-4 were easily synthesized and characterized by elemental analysis, IR, 1H NMR, 31P NMR and X-ray single crystal diffraction.

为筛选高效催化Suzuki反应的催化剂,合成了3种新的环钯化二茂铁亚胺-三苯基膦配合物2~4,经元素分析、红外光谱和核磁共振谱对其结构进行了表征,并通过X射线单晶衍射测定了化合物3的晶体结构。

All of the tripodal schiff base ligands and their complexes were characterized.

以三乙醇胺、巯基苯胺、巯基乙胺为初始原料,设计合成了六个三脚架结构的化合物,其合成路线如下:三乙醇胺与氯化亚砜反应得到三(2-氯乙基)胺(1),然后与巯基苯胺或巯基乙胺在碱性条件下反应生成三脚架结构的三{[2-(2-氨基苯基)硫代]乙基}胺(2)或三{[2-(2-氨基乙基)硫代]乙基}胺(3),然后再与水杨醛、2-甲酰基-8-羟基喹啉(8)、2-甲酰基-8-苄氧基喹啉(7)反应得到六种新型的含硫西佛碱化合

In this study, the critical point data of ternary systems which is composed of supercritical carbon dioxide, trisodium salt of tri-(m-sulfonphenyl)phosphine and cosolvent were measured the first time. With the increase of mol% of the cosolvent, critical temperature of ternary system increased, and the experimental data show a linear dependence of critical temperature with mol% of the ternary system over the concentration ranges studied too.

北京化工大学硕士研究生论文本文还首次测试了在超临界CO:中加入三磺化三苯基麟以及共溶剂组成的三元体系的临界点数据,发现三元体系中临界温度也随共溶剂的浓度增加逐渐增加,呈一种线性关系。

For instance, they may be ethylated by means of an ethyl halide, diethyl sulphate or ethyl p-toluenesulphonate to form dialkyl phenylethylmalonates which are valuable intermediates for the manufacture of certain therapeutically active barbiturates.

通过加入卤代乙烷,二烷基硫酸酯或者乙基p-甲苯磺酸酯,行程二烷基苯基乙基丙二酸酯,它是一种颇有价值的用于制造某些具有治疗活性的巴比妥盐的中间体。

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