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In this thesis, we synthesized a series of ferrocene-based triphenyl amine compounds via different approaches. By using electrochemical method and spectral electrochemistry we could observe their properties and then make into devices.

在本论文中,我们藉由不同的策略合成出一系列以二茂铁为核心之双三苯基胺化合物,利用电化学的方法及光谱电化学来观察其特质,并制作成元件。

In the meanwhile, we also found that compounds being connected by OXD rings, electronic coupling between the ferrocene and triphenyl amine could be prevented by using OXD ring as connecting unit.

同时,我们也发现,化合物若以OXD环为连接基团,不但可以阻隔二茂铁单元和三苯基胺单元的偶合作用,使得分子可以利用电化学的方法形成电聚膜。

In DMSO, the polymerization of methyl methacrylate could be carried out efficiently. However the photopolymerization was inhibited in acetonitrile. It was ascribed to the complex formed between coumarin 1 and HTIB photolyzed to unreactive species after irradiation in acetonitrile.

在一般极性溶剂中如DMSO中能有效地引发甲基丙烯酸甲酯光聚合,而在电子受体性质的极性溶剂如乙腈中,光聚合反应受阻,这归结于香豆素1与羟基苯基碘鎓盐形成络合物,使得光反应后生成不具活性的产物。

Synthesis and UV- visible spectrum of tetraphenylporphyrin and its derivatives.

四苯基卟啉及其衍生物的合成和可见光谱的研究。

In the field of visible photosensitive resin, the absorption spectrum, excited state, solvent polarity effect, fluorescence spectrum, fluorescence quenching, concentration effect, photo fading, reaction mechanism as well as photopolymerization kinetics of xanthene iodonium salts and cyanine dye-borate were discussed. It is found that under the radiation of visible light, intra-ion-pair electron transfer reactions occur in bis salt of fluorescein and unsymmetrical trimethine cyanines containing quinoline end group triphenyl-butylboron, and the fading rate is very high.

在可见光敏树脂部分,通过对呫吨染料碘鎓盐和菁染料-硼盐体系的吸收光谱性质、激发态性质、溶剂极性效应、荧光光谱、荧光猝灭、浓度效应、光褪色反应、光聚合动力学等的研究,结果发现:荧光黄双二苯基碘鎓盐体系和含喹啉环端基不对称三甲川菁染料-三苯基丁基硼盐体系在可见光作用下均发生离子对内电子转移反应,且光褪色反应速率很高。

The NOT, OR and XOR gate of combinational logic were replaced by the polyphenylene based molecular device whileTour-type molecular wire constitute the framework in the molecular circuit accounting for the geometry and steric constraints imposed by the bonding and shapes of the organic molecules.

为了在分子电路水平实现减法运算,按照固态电子学组合逻辑原理,提出了一种基于聚亚苯基分子器件的二进制减法器逻辑电路的设计。

After the diazotization ,2-aminophenol-4-(2-'carboxy)sulfanil phenylamine was coupled with acetoacetanilide,2-naphthol,1-phenyl-3-methyl-5-pyrazolone,1-naphthol-4-sulfonic acid,separately to get the different diazotized compounds,then complexed with potassium chromium sulfate or cobaltous chloride to obtain the yellow,orange,red,purple,blue and other colour dyestuffs.

2-氨基苯酚-4-(2'-羧基)磺酰苯胺重氮化,分别与乙酰乙酰苯胺、2—萘酚、1-苯基-3-甲基-5-吡唑啉酮、尼文酸、1-乙酰氨基-7-萘酚等偶合,得到不同的偶氮化合物,然后分别与硫酸铬或氯化钴进行络合反应,得到黄、橙、红、紫、蓝多种颜色染料,并进行了毛织品的染色实验。

The analogs of piracetum with the core of demethylclausenamide(III-4 and III-5) were prepared by condensation of demethylclausenamide with ethyl bromoacetate and hydrolysis or aminolysis there after.

3在兰培工作的基础上,选用O-乙酰-R--扁桃酸为拆分剂,成功的拆分了表黄皮酰胺前体5--4-苯基-1-甲基吡咯烷酮(Ⅱ-1),和Ⅱ-1分别引入3位羟基得到和表黄皮酰胺。

In the presence of ethanol- HCl solution, arylamine-HCl and w=37% aqueous formaldehyde solution or the condensation product of arylamine and formaldehyde are directly reacted with ethyl 3-oxo-2-phenylmethylenebutyrate to form l-aryl-2-phenyl-3-carbethoxy-4-piperidone.

2-苯亚甲基-3-丁酮酸乙酯与芳香胺和w=37%甲醛水溶液或芳胺和甲醛的缩合物在氯化氢-无水乙醇存在下可直接发生的Mannich反应,得到1-对位取代芳基-2-苯基-3-羰乙氧基-哌啶-4-酮。

The optical nonlinearities, including the nonlinear absorption, the nonlinear refraction and the third-order nonlinear polarizability of 2-(2′-hydroxyphenyl)benzothiazole in cyclohexane, have been investigated using a single-beam Z-scan technique.

以532 nm皮秒脉冲作泵浦光,采用单光束Z-扫描技术对具有激发态分子内质子转移效应的有机分子2-(2′-羟基苯基)苯并噻唑在其双光子吸收区的非线性光学特性进行了详细地研究。

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Shop assistant: Please check at the door.

店员:请您到门口柜台交费。

In the end, transportation of PAHs in the environmental matrix was preliminarily investigated and discussed according to PAHs data of soils and sediments from a certain region in Shanghai. The result indicated that there are two or more pathways on PAHs transportation in the environmental matrix.

最后,对上海特定地区内PAHs在环境介质中的迁移径途进行了分析讨论,结果表明上海市土壤和沉积物等环境介质中PAHs的迁移存在多种途径。

Quick stop! AIDS doctors while the side and say hello and colleagues mention a blood sample box, the Red Cross had sent blankets and so on, with patients有说有笑to go home.

快停车!防艾医生们一边招呼一边和和同事们提着血液采样箱,抱着红十字会送来的被子等,有说有笑地同患者往家走。