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A novel Pd/C catalyst with high activity,high selectivity and good stability developed by our group was used for the hydrogenation of N-(3-nitro-4-methoxyphenyl)acetamide into N-(3-amino-4-methoxyphenyl)acetamide in methanol and water,respectively.

笔者开发了一种高效的Pd/C催化剂,分别选用甲醇和水作为反应溶剂,实现了高活性、高选择性和高稳定性地催化加氢制备N-(3-氨基-4-甲氧基苯基)乙酰胺。

Two compounds were isolated from ethyl acetate extract of the fermentation of fungus 07-11,which obtained from the soil of Yunnan Province. They were identified as N-(4-hydroxy-2-methoxyphenyl)acetamide (1) and ergosta-7,22-diene-3,6-dione (2) respectively on the basis of spectral analyses and physical and chemical identifications.

从云南土壤真菌07-11号菌株的发酵液乙酸乙酯萃取物中分离得到2个化合物,通过理化鉴别和光谱测定,鉴定两化合物分别为N-(4-羟基-2-甲氧苯基)乙酰胺(1)和麦角甾7,22-二烯-3,6-二酮(2)。

The effect of content of water on the yield of 2-phenylbenzamide by using sodium amide to cleave fluorenone was studied.

研究了水分含量对氨基化钠裂解芴酮制备2-苯基苯甲酰胺收率的影响。

Methods This title compound was prepared using the O-phenylene diamine and the anisaldehyde as the raw material,methanol as the solvent,and the phosphoric acid makes the oxidant.

方法本课题以邻苯二胺和对甲氧基苯甲醛为原料,在甲醇为溶剂,磷酸为催化剂的酸性条件下,一步反应制得2-(4-甲氧基苯基)苯并咪唑。

Methoxycarbonyl-4-(4-methoxyphenyl )-6-methyl-3, 4-dihydropyrimidine-2(1H)-one was synthesized from anisaldehyde, methyl acetoactate and urea in presence of HF-1O1 strong acidic ion-exchange membrane.

在HF-101强酸性离子交换膜的存在下,由对羟基苯甲醛、乙酰乙酸甲酯与脲一步合成了5-甲氧羰基-4-(4-甲氧苯基)-6-甲基-3,4-二氢嘧啶-2(1H)-酮。

Aim To synthesize methyl 2-(4-methoxyphenyl)-2-oxoacetate from the ascidian Polycarpa aurata.

目的合成从太平洋海鞘 Polycarpa aurata中提取的天然产物2-(4-甲氧基苯基)-2-氧代乙酸甲酯。

Hydroxy-2-methyl-1-phenyl propan-1-one (1173) was a more effective photoinitiator to these monomers than that of benzophenone.

与二苯甲酮相比,2-羟基-2-甲基-1-苯基丙酮(1173)对两种单体具有较好的引发效果。

Using benzyl phosphorus and pyridine phosphorus ligands, a series of complexes were synthesized and their structures were also discussed.

使用苯基膦酸以及吡啶膦酸配体合成了一系列链状和层状配合物,并对它们的结构进行了研究。

In previous literatures,2- or 4-position of 1,5-benzothiazepines is substitutented by simple aliphatic or benzyl groups .

目前国内外对此类化合物的研究主要局限于2,4位是简单烷基或取代苯基。

Accordingly a further feature of the invention is a combined process wherein a dialkyl phenylethylmalonate is made from an alkyl phenylacetate and a dialkyl carbonate by a process comprising adding to a quantity of sodium which is covered with a hydrocarbon solvent boiling above 100°C, at least a chemically equivalent proportion of a lower aliphatic alcohol, subsequently adding an approximately equivalent proportion of a dialkyl carbonate and of an alkyl phenylacetate, heating the mixture to induce reaction and continuously distilling out the alcohol formed from the reaction zone and finally causing the sodio diethyl phenylmalonate so obtained to interact with an ethylating agent, such as ethyl halide, diethyl sulphate of ethyl p-toluene-sulphonate.

因此,本发明的另一个应用是一个组合工艺过程:二烷基苯基乙基丙二酸酯由烷基乙酸苯酯和二烷基碳酸酯得到,具体工艺过程是:向覆盖有沸点超过一百摄氏度的团庆化合物溶剂的金属钠中添加至少化学平衡的低级脂肪族醇,然后加入大约相同当量的二烷基碳酸酯和烷基乙酸苯酯,加热混合物引导反应进行,持续蒸馏把形成的醇类从反应区域移出,最后使获得的二乙基苯基丙二酸酯和乙基化试剂如卤代乙烷,二乙基硫酸酯形成乙基p-甲苯磺酸酯。

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