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Aimed at time and manpower consuming and contact to poisonous substances which are harmful to analyzers,the original method for analysis of trace chlorine in triphenyl phosphine was replaced by microcoulometry,based on times of testing comparisons.

针对齐鲁分公司第二化肥厂原有的三苯基膦氯含量的分析方法耗时、耗力且分析过程中接触的有毒物质较多、对分析人员伤害较大等问题,经过多次试验对照,用微库仑法代替原有的分析方法来测量三苯基膦中的微量氯。

Meanwhile, Azoxybenzene was also detected by GC-Mass from the extracts of culture fluids with dichloromethane, which conformed the probability of the existence of two metabolites: nitrosobenzene and N-phenylhydroxylamine. Because Azoxybenzene might be yield from the reaction of these two compounds under the catalytic influence of alkali.

另外通过GC-MS测定硝基苯降解液的二氯甲烷提取物,测到氧化偶氮苯的存在,它能在碱的催化作用下由亚硝基苯和N-苯基羟胺反应生成,所以它的存在从反面证实了降解中间产物亚硝基苯和N-苯基羟胺的存在。

The illicit synthesis of this compound has been achieved most commonly by the reductive amination of phenyl-2-propanone 2, by the Leuckart formamidation of 2 followed by hydrolysis or by the reduction of ephedrine or pseudoephedrine 3 with hydriodic acid and red phosphorus.

此化合物非法合成的方法有,通过1-苯基-2丙酮的还原胺化作用;通过1-苯基-2丙酮的洛卡特氐反应后进行水解生成;在红磷、氢碘酸的参与下,通过还原麻黄素或伪麻黄素合成。

In the presence of palladium catalyst and triphenylphosphine, alkynyl Grignards or alkynyllithiums could successfully couple with alkyl bromides and iodides. Aryl-substituted propargylic dithioacetals could also be obtained by this strategy.

在钯触媒和三苯基磷的存在下,我们可利用炔基格林那试剂或炔基锂和简单的卤烷进行偶合,而这样的反应条件也能应用在苯基取代炔丙基硫缩酮衍生物的合成上。

Four chalcones were synthesized by aldol condensation reaction of acetophenone or para-substituted acetophenones with 2-phenyl-1,2,3-triazol-4-carboxaldehyde, which reacted with three hydrazines in glacial acetic acid under refluxing to give a series of pyrazoline derivatives.

以2-苯基-1,2,3-三唑基-4-甲醛为原料,与苯乙酮[或取代苯乙酮(1a~1d)]发生羟醛缩合,生成相应的查尔酮(2a~2d),再与不同的肼反应,合成了12种新的5位含2-苯基-1,2,3-三唑基的吡唑啉衍生物3a~3d,4a~4d,5a~5d。

The Limit Oxygen Index also can be raised from 16.5 to 22 and 23 respectively.The Octaphenyl POSS is synthesized via the hydrolysis and condensation of phenyltrichlorosilane (PhSiCl_3) and the subsequent rearrangement reaction catalyzed by tetramethylammonium hydroxide. Poly are easily synthesized from Ph-POSS via bromination with Br_2/Fe system.

以苯基三氯硅烷为起始原料,通过水解缩合、催化重排的办法制备了八聚苯基笼型倍半硅氧烷,在Fe粉催化条件下将溴元素引入Ph-POSS的苯环得到Br-POSS;使用该种Br-POSS和Sb_2O_3的混合物(3∶1,质量比)作为聚苯乙烯树脂的添加剂,采用熔融共混法制备(Br-POSS+Sb_2O_3)/PS复合材料。

It was found that the titled amine in which although dimethyl aniline and triethyl amine both were contained, possesses less efficiency of photoinitiation while it was composed with ketone as an initiated system.

苯基派嗦类化合物是一类特殊的胺类化物,如苯基乙基呱嗦就可看作为一种三级芳胺和另一种三级脂胺组合而成的化合物,然而对这类化合物和酮组合构成的光引发体系的研究,过去报道较少。

The LB films formation and the orientation of TSPP LB films of 5, 10, 15-tn (p-chlorphenyl)-20-m- oxy (a-steanic acid) phenylporphyrin were studied.

研究了具有双亲性的5,10,15-三对氯苯基-20-邻苯基卟啉在气-液界面上的成膜性能,制备了不同层数的TSPP LB膜。

It was confirmed that the 〓-CCT of phenyl isopropyl ether is formed on the benzene ring rather thanon the etheroxy bond. The 〓-CCT complex is not strong enough to induce charge transfer and converts to CTC because the isopropyl group is separated from the benzene ring by oxygen atom. As a result,〓 can not transfer from isopropyl to form radical in cage. Therefore phenyl isopropyl ether is difficult to undergo dark oxidation.

这是由于苯基异丙醚和异丙醚形成O〓-CCT的部位不同,苯基异丙醚的O〓-CCT形成在苯环上,与异丙基相隔一个氧原子,不足以诱发异丙基电荷转移而转化为CTC,也就不能有氢质子转移和笼式自由基的形成,因此难于发生暗氧化反应。

The cross-coupling reaction of DOPO with halogenated phenols were achieved for the first time, novel phenolic hydroxyl-containing reactive-type DOPO-based flame retardants used in epoxy resins were synthesized; the cross-coupling reactions of 2\'-hydroxybiphenyl-2-ylphosphinic acid or diphenyl phosphine oxide with halogenated phenols were studied according to the above result, new reactive-type flame retardants used in epoxy resins were synthesized.

采用Pd催化的方法首次实现了DOPO与卤代酚的交叉偶联,合成了新型含酚羟基的反应型DOPO基环氧树脂阻燃剂;在此基础上实现了2-(2-羟基苯基)苯基次磷酸和二苯基氧化膦与卤代酚的偶联,合成了新型反应型有机磷环氧树脂阻燃剂。

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