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Experiments showed that inorganic mercury and phenyl mercury could be adsorbed by activated carbon in 0.5% aqua regia with adsorption time of 1.5 hours. The adsorption percentage was 97% for inorganic mercury and 96.5% for phenyl mercury.

结果表明,在活性炭用量为0.2g,φ=0.5%的王水介质中搅拌1.5h,无机汞和苯基汞的吸附率均达96%以上,无机汞和苯基汞的吸附容量分别为82.5μg/g和66.0μg/g。

Alkylations of benzene with dodecene and/or chloromethane in the room temperature ionic liquid 1-methyl-3-butylimdazole chloride-aluminium chloride as catalyst have been investigated with high conversion and selectivity.

首次研究了在氯铝酸室温离子液体系中二甲苯与苯乙烯的烷基化反应制1-苯基1-二甲苯基乙烷及其衍生物。考察了离子液体催化剂量和反应条件的不同对产物组成及副产物数量的影响。

A process for reducing nitryl with unstable guanyl on para-position of benzene ring into azyl features that active metal reacts on organic acid and solvent at ordinary temp. and pressure to reduce N-(2 or 3-M, 5 or 6-M',4-nitrophenyl)-N',N'-dimethyl acetamidine into N-(2 or 3-m, 5 or 6-M', 4-aminophenyl)-N',N'-dimethyl acetamidine, where M=H,-R,-OR,-COOR (R=H, C1-C6); and M'=H,-R,-OR,-COOR (R=H, C1-C6). Its advantages include reduced by-reaction and high reducting rate up to 80%-95%.

本发明是将苯环上对位带有不稳定脒基的硝基还原为氨基的方法,采用活泼金属,如:锌或锡,与有机酸和适当的溶剂,在常温、常压下发生反应,将N-(2或3-M,5或6-M',4-硝基苯基)-N',N'-二甲基乙脒还原为N-(2或3-M,5或6-M',4-氨基苯基)-N',N'-二甲基乙脒,其中M=H,-R,-OR,-COOR(R=H,C1-C6),M'=H,-R,-OR,-COOR(R=H,C1-C6),减少了副反应,使还原收率达到80%以上,最高可达95%以上,更适用于工业化生产。

Direct competitions of intramolecular C - H insertions into benzylic C - H and 4-nitroor 4-methoxy substituted benzylic C - H of methyl 2-diazo-3-oxo-6-(4-substituted phenyl)-4-(2-phenylethyl)hexanoate 44a and 44b catalyzed by Rh-mediated carbenoid were alsoinvestigated, and the relative reactivities obtained by compound 44a or 44b were comparableto those obtained by indirect method.

此外,还研究了Rh催化分解下,对位硝基取代或甲氧基取代的4-(2-苯基乙基)-6-(4-取代苯基)-2-重氮基-3-氧代己酸甲酯44a、44b苯甲位C-H插入反应的相对速率,与化合物47a和47f得到的结果比较,数据平行。

Benzylidene[1,3-bis(2,6-dimethylphenyl)-4,5-dihydroimidazol-2-ylidene]dichloro(2-methylpyridine)ruthenium (62), benzylidene[1,3-bis(2,6-dimethylphenyl)-4,5-dihydroimidazol-2-ylidene] dichloro(2,4-dimethylpyridine)ruthen ium (63) introduce ortho substituted pyridine as dissociating ligand to weaken Ru-N bondand accelerate dissociation of pyridine derivative ligand through steric hindrance.

在钌卡宾配合物[1,3-二-(2,6-二甲苯基)-4,5-二氢咪唑基]-苯亚甲基-(2-甲基吡啶)-二氯合钌(62),1,3-二-(2,6-二甲苯基)-4,5-二氢咪唑基1-苯亚甲基-(2,4-二甲基吡啶)-二氯合钌(63)中,邻位取代的吡啶作为解离配体,通过邻位基团的空间效应削弱钌-氮配位键,使配体更易解离,提高了催化剂的初活性。

The synthesis of l-(4-acetylaminophenyl)-2-bromo-1-propanone was discussed, and the mechanism and possible factors were analyzed. Hence the routine was determined, in which l-(4-acetylaminophenyl)- 1-propanone was reacted with Bromine dissolved in ethanol, so that the a -bromination can be carried on, resulted in the yield of up to 70.4%.

探讨了1-(4-乙酰胺基苯基)-2-溴代-1-丙酮的合成方法,分析了反应机理和影响因素,确定将1-(4-乙酰氨基苯基)-1-丙酮溶解在乙醇中以溴的乙醇溶液进行α-溴化的合成路线,产率可达70.4%。

A small cell-permeable compound, BH3I-2 3-iodo-5-chloro-N-[2-chloro-5-((4-chlorophenyl)sulphonyl phenyl]-2-hydroxybenzamide, has been recently reported to have a function similar to Bak BH3 peptide.

最近报道,可通透细胞的小分子化合物,BH3I-2':3-碘-5-氯-N-{2-氯-5-[(4-氯苯基)磺酰]苯基}-2-水杨酰胺具有与Bak BH3肽相似的作用。

The crystal structure of the deoxygenating reaction product 1,1-dichlorotetraphenylcyclopentadienone of phenyl mercury with tetraphenylcyclopentadienone is reported.

本文报道了二氯卡宾(由一溴二氯苯基甲基汞产生)与四苯基环戊二烯酮脱氧反应产物的晶体与分子结构,并就其结构特征讨论了反应机理和产物的关系。

For the asymmetric reduction ofα-hydroxyacetophenone and ethyl 4-chloro acetoacetate,-1-phenyl-1,2-ethanediol and-ethyl 4-chloro-3-hydroxybutanoate were produced by the purified enzyme, with the 99% and 94.3% e.e. value respectively.

在纯酶水平验证了近平滑假丝酵母(Candida parapsilosis CCTCCM203011)对外消旋苯基乙二醇的拆分机理,整个去消旋过程是由-苯基乙二醇次级醇脱氢酶和羰基还原酶共同催化完成的。

On the contrary, sulfonated poly(arylene thioether phosphine oxide)s, with a IEC of 1.60 meq/g, even denote a swelling of 70.1% at 80oC and thus lose most of the mechanical strength.

而前述IEC为1.60 meq/g的磺化聚芳硫醚三苯基氧膦在80oC下的溶胀率为70.1%,已经出现溶胀突变,显著丧失力学强度,其耐溶胀性能比磺化聚二氮杂萘酮醚三苯基氧膦差得多。

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