苯偶酰

Starting from 3-benzoyl-5-formyl-indolizine, 3-benzoyl-5-(2'2'-diacetylethenyl)-indolizines and analogs were obtained by the 〓mediated aldol condensation or Wittig reaction. These compounds,promoted by low-valent titanium, gave highly functionlizedcycl[3,2,2]azine derivatives. The coupling reaction proceeded betweenthe carbonyl group and the carbon-carbon double bond, a rare example inMcMurry reaction.

我们以3-苯甲酰基-5-甲酰基中氮茚为原料，通过三碘化钐促进的aldol反应和Wittig反应制备了3-羰基-5-羰基乙烯基中氮茚，随后经低价钛还原偶联，没有生成正常的分子内羰基-羰基偶联产物，而是得到反常的羰基与α，β-不饱羰基的双键偶联产物，较高收率地得到了含多官能团的CycI[3，2，2]azine衍生物。

Dry oxidation of benzoin with air under microwave irradiation gave benzil in excellent yield.

研究了微波辐射下干法氧化苯偶姻生成苯偶酰的反应。

Catalytic oxidation of benzoin to benzil by molecular oxygen using metal oxide supported on activated charcol, silcon oxide, activated aluminum oxide and obsorbe resin as catalyst at atmosphere pressure was studied.

考察了几种常用载体负载金属氧化物催化分子氧氧化苯偶姻制备苯偶酰的性能，发现氧化铁/三氧化二铝催化活性较高，稳定性较好。

We studied the effect of water on the palladium acetate-catalyzed coupling reaction of aryl boronic acid with aryl bromide or acyl chloride in ionic liquid or PEG, and found that water had a remarkable rate accelerating effect on the Suzuki reaction and Suzuki-Type reaction when other reaction conditions were uniform.

研究了水对离子液体或聚乙二醇中Pd2催化的卤代苯或苯甲酰氯与苯硼酸的Suzuki和Suzuki-Type偶联反应收率的影响。

This dissertation is mainly focused on the reactivity of methylenecyclopropanes and comprises six parts. 1 The reactions of methylenecyclopropanes with phenylsulfenyl chloride, phenylselenyl chloride and diphenyl diselenide; 2 The coupling reactions of the ring-opening products derivated from methylenecyclopropanes; 3 The palladium-catalyzed ring-enlargement of mono-aryl group substituted methylenecyclopropanes to cyclobutenes. 4 The gold-catalyzed domino ring-opening and ring-closing hydroamination of methylenecyclopropanes with sulfonamides; 5 The Lewis acid-catalyzed reactions of mono-aryl group substituted methylenecyclopropanes with diethyl ketomalonate in the presence of water; 6 The iodobenzene diacetate mediated novel 1,3-dipolar cycloaddition of methylenecyclopropanes, vinylidenecyclopropanes, and methylenecyclobutane with phthalhydrazine.

本论文主要研究了亚甲基环丙烷类化合物的一些化学反应性能，共由以下六部分组成：1、亚甲基环丙烷类化合物与苯硫氯、苯硒氯及二苯基二硒的反应；2、亚甲基环丙烷类化合物开环产物的偶联反应；3、单芳基取代的亚甲基环丙烷类化合物在钯催化剂作用下的扩环反应；4、金化合物催化磺酰胺对亚甲基环丙烷类化合物的串联开环关环氨氢化反应；5、路易斯酸催化亚甲基环丙烷类化合物与丙酮二羧酸二乙酯在有水存在下的反应；6、醋酸碘苯促进的亚甲基环丙烷类化合物、亚乙烯基环丙烷类化合物及亚甲基环丁烷类化合物与邻苯二甲酰肼的新型1，3-偶极环加成反应。

The sodium dithiobenzoic acid was oxidized with potassium ferricyanide to obtain di disulfide.The influences of raw materials mole ratio,stirring method and reaction time on the yield were studied with orthogonal test.

用铁氰化钾溶液氧化二硫代苯甲酸钠，得双二硫代苯甲酰，采用正交实验探讨了4，4'-偶氮双(4-氰基戊酸)与双二硫代苯甲酰反应的投料比、搅拌方式、反应时间对反应收率的影响。

Furoin was synthesized from furol with VB1 as the catalyst,which was then reacted with acetyl chloride, lauroyl chloride ,benzoyl chloride,α-furoyl chloride and 3-α-furyl acryloyl chloride,respectively;corresponding monoester compounds of furoin were synthesized in THF in the presence of sodium hydroxide under reflux.

以糠醛为基础原料，经维生素B1催化合成糠偶姻，再由糠偶姻分别和乙酰氯、月桂酰氯、苯甲酰氯、α-呋喃甲酰氯和3-α-呋喃烯丙酰氯反应，在NaOH/无水THF体系中，于水浴回流条件下合成了相对应的糠偶姻单酯类化合物。

Two new active esters of acrylic acids monomers, N-p-acryloxybenzoyloxy succini-mide and N-p-methacryloxybenzoyloxy succinimide have been synthesized and polymerized.ABOSu and MBOSu were prepared by coupling of p-acryloxybenzoic acid or p-methacryloxybenzoie acid with N-hydroxy succinimide in the presence of dicyclohexylcarbodimide.

新的丙烯酸活性酯，N-(对甲基丙烯酰氧苯甲酰氧基)丁二酰亚胺及N-丁二酰亚胺单体分别由对甲基丙烯酰氧基苯甲酸、对丙烯酰氧基苯甲酸与N-羟基丁二酰亚胺在环已基羰二亚胺存在下经偶联反应合成。

When 3-benzoyl-5-formyl-indolizine or ethyl 5-benzoyl-indolizine-3-carboxylatewere used as substrates, a novel coupling reaction occurred, givinghydroxy-cycl[3,2,2]azines. A mechanism of the reaction was proposed.

其中3-苯甲酰基-5-甲酰基中氮茚和5-苯甲酰基-3-中氮茚甲酸乙酯在低价钛试剂的作用下，发生了新奇的偶联反应，得到了用其它方法难以制备的Hydroxy-cycl[3，2，2]azine，并对此现象作了解释。

Guanine can quench the phthalhydrazidylazoacetylacetone's ECL in acid medium, and the linear concentration range of guanine relative to the ECL intensity is from 2.0×10~(-6) to 1.0×10~(-5) mol/L.The mechanism of phthalhydrazidylazoacetylacetone's ECL on the surface of ITO glass has been discussed according the experimental phenomenon.The phenomenon of ITO self-luminescence has also been studied.It has been found that the machanism of phthalhydrazidylazoacetylacetone on the surface of ITO in different medium is dissimilarity. The phenomenon of ITO self-luminescence may be caused by the interaction of the active oxygen element and ITO's surface.

鸟嘌呤在弱酸性介质中3-(1-乙酰丙酮偶氮)苯二甲酰肼的电化学发光具有显著的淬灭作用，2.0×10~(-6)～1.0×10~(-5) mol/L浓度范围内，电化学发光强度与鸟嘌呤的浓度成良好的线性关系根据相关试验现象对3-(1-乙酰丙酮偶氮)苯二甲酰肼在氧化铟锡玻璃电极上的电化学发光机理进行了初步探讨，并对氧化铟锡玻璃电极自身发光现象进行了研究，研究发现在不同酸度环境中，3-(1-乙酰丙酮偶氮)苯二甲酰肼在氧化铟锡玻璃电极上电化学发光的机理是显著不同的；ITO自身发光可能是由活性氧系分子与ITO镀膜玻璃电极表面相作用引起的。

I didn't watch TV last night, because it .

昨晚我没有看电视，因为电视机坏了。

Since this year, in a lot of villages of Beijing, TV of elevator liquid crystal was removed.

今年以来，在北京的很多小区里，电梯液晶电视被撤了下来。