苯亚甲基

But in the + moiety, the three benzimidazole rings shared the whole space equally, the dihedral angel among them is about 120°, just like three fan blades of an airscrew, the molecular structure appear gear-like shape.

X-射线单晶衍射测试、红外、紫外等方法确定了三(2-苯并咪唑亚甲基)胺的Fe和Co配合物的结构，由晶体结构发现金属配位情况不同、配合物在结构上存在着差异，Fe为八面体构型，而Co为三角双锥构型；其次，两配合物中的苯并咪唑环间夹角不同，配合物中包含N2和N4的两个苯并咪唑环间夹角仅为9.41(0.11)，几乎构成一个平面，呈蝴蝶形；后者Co三个苯并咪唑环几乎平分了整个空间，它们之间的夹角约为120，呈三扇叶螺旋桨式构型，为齿轮形。

New contributions of this work are as follows:(1). Preparation of Spherical MgCl_2-Supported Late-Transition Metal Catalysts for Ethylene PolymerizationFacile and effective immobilization of late-transition metal catalysts. 2,3-bis-(2,6-diisopropylphenyl) butane diimine nickel dibromide (1) and 2,6-bis-[1-(2,4,6-trimethylphenylimino)ethyl]pyridine iron dichloride (2), for ethylene polymerization has been achieved, using spherical MgCl_2 supports obtained by thermal dealcoholization of MgCl_2·2.56C_2H_5OH, and the effects of dealcoholization temperature on supported late-transition metal catalysts and the properties of resultant polymers were studied, the results indicated that:1.Supports with appropriate mechanical strength, high surface area and high porosity could be prepared by thermal dealcoholization of spherical MgCl_2·2.56C_2H_5OH supports; 2.BET, XRD, IR, SEM, GPC and DSC analyses indicate that the activities of the supported late-transition metal catalysts and the properties of resultant polymers are strongly dependent on the dealcoholization temperature.

本工作的新贡献如下：(1)、球形氯化镁负载后过渡金属催化荆催化乙烯聚合本文将配合物2，3-双(2，6-二异丙基苯亚胺)丁烷二溴化镍(1)和配合物2，6-二[1-(2，4，6-三甲基苯亚胺)乙基]吡啶二氯化铁(2)分别直接负载于经不同热脱醇温度处理的球形氯化镁载体上，研究了氯化镁载体的脱醇温度对负载化后过渡金属催化剂及其聚合物的影响，研究表明：1、通过对球形MgCl_2·2.56C_2H_5OH载体进行热脱醇处理，可以获得合适机械强度、较高比表面积和较高孔隙度的球形氯化镁载体；2、BET，XRD，IR，SEM，GPC和DSC研究表明，脱醇温度极大地影响负载后过渡金属催化剂的活性和聚合物的性能。

New contributions of this work are as follows:(1). Preparation of Spherical MgCl_2-Supported Late-Transition Metal Catalysts for Ethylene Polymerization Facile and effective immobilization of late-transition metal catalysts. 2,3-bis-(2,6-diisopropylphenyl) butane diimine nickel dibromide (1) and 2,6-bis-[1-(2,4,6-trimethylphenylimino)ethyl]pyridine iron dichloride (2), for ethylene polymerization has been achieved, using spherical MgCl_2 supports obtained by thermal dealcoholization of MgCl_2·2.56C_2H_5OH, and the effects of dealcoholization temperature on supported late-transition metal catalysts and the properties of resultant polymers were studied, the results indicated that: 1.Supports with appropriate mechanical strength, high surface area and high porosity could be prepared by thermal dealcoholization of spherical MgCl_2·2.56C_2H_5OH supports; 2.BET, XRD, IR, SEM, GPC and DSC analyses indicate that the activities of the supported late-transition metal catalysts and the properties of resultant polymers are strongly dependent on the dealcoholization temperature.

本工作的新贡献如下：(1)、球形氯化镁负载后过渡金属催化荆催化乙烯聚合本文将配合物2，3-双(2，6-二异丙基苯亚胺)丁烷二溴化镍(1)和配合物2，6-二[1-(2，4，6-三甲基苯亚胺)乙基]吡啶二氯化铁(2)分别直接负载于经不同热脱醇温度处理的球形氯化镁载体上，研究了氯化镁载体的脱醇温度对负载化后过渡金属催化剂及其聚合物的影响，研究表明： 1、通过对球形MgCl_2·2.56C_2H_5OH载体进行热脱醇处理，可以获得合适机械强度、较高比表面积和较高孔隙度的球形氯化镁载体； 2、BET，XRD，IR，SEM，GPC和DSC研究表明，脱醇温度极大地影响负载后过渡金属催化剂的活性和聚合物的性能。

The initial SAR studies indicated:(1) the presence of a linker of methene at the N-1 may be beneficial to anti-HIV activity, while longer chain could enhance toxicity;(2) substituted phenyl at the C-2 could reduce toxicity;(3) 6-substituted benzimidazoles generally showed higher anti-HIV activity than 5-substuted ones;(4) the presence of a halogenated benzyl ring at the N-l would enhance anti-HIV potency and decrease cytotoxicity.

初步构效分析提示：(1)苯并咪唑环1位侧链间隔基为亚甲基时活性最好，侧链延长，毒性增大；(2)苯并咪唑2位侧链无间隔基毒性相对较低；(3)苯并咪唑6位取代活性高于5位取代；(4)苯并咪唑1位芳环用卤素取代，毒性明显降低。

The initial SAR studies indica ted:(1)the presence of alinker of methene at the N-1may be beneficial to anti-HIV activity,while longer chain could enhance toxicity;(2)substituted phenyl at the C-2could reduce toxicity;(3)6-substituted benzimidazoles generally showed higher anti-HIV activity than 5-substuted ones;(4)the presence of ahalogenated benzyl ring at the N-l would enhance anti-HIV potency and decrease cytotoxicity.

初步构效分析提示：(1)苯并咪唑环1位侧链间隔基为亚甲基时活性最好，侧链延长，毒性增大；(2)苯并咪唑2位侧链无间隔基毒性相对较低；(3)苯并咪唑6位取代活性高于5位取代；(4)苯并咪唑1位芳环用卤素取代，毒性明显降低。

The synergistic extraction of uranyl nitrate with binary system of 1-phenyl-3-methyl-4-benzoyl-pyrazolone-5 and tributyl phosphate or diphenyl sulfoxide, and ternary system of PMBP-DPSO-TBP were studied.

本文研究了1-苯基3-甲基4-苯甲酰吡唑酮-5与磷酸三丁酯或二苯亚砜的苯溶液从硝酸介质中对U的萃取，实验发现有显著的二元协萃效应，并测定了二元协萃络合物的组成为 UO_2A_2·TBP或 UO_2A_2·DPSO，求得二元协萃平衡常数为1gβ_(12)=3.58，1gβ_(13)=3.61。

It is manufactured through kneading, cold pressing and post-treatment; and the materials for the synthetic brake shoe include butadiene-acrylonitrile rubber, phenolic resin, graphite, iron powder, barium sulfate, potash feldspar powder, composite fiber, sulfur, hexamethine tertramine, polymethylene aniline, 2-mercaptan benzothiazole, zinc oxide and toluene.

同时本发明的提供了采用捏合、冷压、后处理工艺来制造新型高摩擦系数合成闸瓦。组成新型高摩擦系数合成闸瓦的各组分重量百分比如下：丁腈橡胶为6.20％，酚醛树脂为10.00％，石墨为15.00％，铁粉为11.03％，硫酸钡为30.00％，钾长石粉为5.00％，复合纤维为20.20％，硫磺为1.00％，六次甲基四胺为1.00％，聚亚甲基聚苯胺0.12％，2-硫醇基苯并噻唑0.15％，氧化锌0.30％，甲苯8.0％。

Chapter 1: The reactions of methylenecyclopropanes with phenylsulfenyl chloride or phenylselenyl chloride give cyclobutene derivatives along with ring-opened products in good total yields at 0 °C in various solvents. The reactions of methylenecyclopropanes with diphenyl diselenide give the di-phenylselenyl substituted ring-opening products which can be transformed to 2,5-dihydrofuran derivatives under the oxidation with hydrogen peroxide at room temperature.

在第一章中，我们发现亚甲基环丙烷类化合物在0℃时即可很快与苯硫氯或苯硒氯发生反应生成取代环丁烯类化合物和正常的开环产物；而与二苯基二硒的反应则需加热到150℃以上才能进行反应，生成的二苯硒基开环产物在双氧水氧化下可以转化为取代二氢呋喃类化合物。

A method using α methylstyrene as raw material to prepare β methylene phenethyl alcohol,a new rose flavor ,by chlorination,esterification and saponification was studied.

对α 甲基苯乙烯经氯代、酯化、皂化合成新型玫瑰香料β亚甲基苯乙醇的方法进行了研究，选择PTC1作为相转移催化剂，当m∶m (NaAc·3H2 O)∶m (PTC1 )=1 。0 0 0∶0 30 0∶0 0 2 4时，80℃下反应 6h ，产率为 67 3%。

The synthetic route starts from penicillin G, peroxyacetic acid(8.5%) as Oxidizing Agent to get penicillin G sulfoxide; esterifided with p-nitrobenzyl bromine to synthesize penicillin G sulfoxide ester; we synthesize 3-exomethylenecepham sulfoxide ester with phthalimide potassium and 4A molecular sieve as acid scavenger to open the ring, SnCl_4 as catalyzation to close the ring. The yield is over 60%.

本研究采用的合成路线为：以青霉素G钾盐为原料，选用工业过氧化氢制备的过氧乙酸(22.3%)稀释至8.5%为氧化剂，氧化得青霉素亚砜；采用对硝基溴苄为酯化试剂，制备青霉素亚砜酯；以NCP(N-氯代邻苯二甲酰亚胺)为开环试剂，酞酰亚胺钾和4A型分子筛为酸清除剂，顺利开环；再经无水SnCl_4催化闭环得3-环外亚甲基头孢亚砜酯，最终产率在60%以上。

Now, however, all children continue in "comprehensive" schools, and the eleven-plus determines which courses of study the child will follow.

然而现在，所有的孩子都要在综合学校继续学习，所以这次考试只是决定他们将要学习哪些课程。

Cultivatable land , and led to a general recognition that development must not be carried at the cost of agriculture .

城区的迅速扩大在很多情况下侵占了宝贵的可耕地，使人们普遍认识到发展不能以牺牲农业为代价。