苯乙酮

Under optimal conditions, oxidation of ethylbenzene into acetophenone under 1 atm O2 and 1 mol% NHPI reach to 64% yield.

在最佳的催化状态下，苯乙烷能在1 atm的氧气、1 mol% NHPI与轴向配位基为吡啶的紫质修饰二氧化钛共催化下，氧化成苯乙酮，并得到64%的产率。

The effects of some factors, such as reaction temperature, reaction time, substrate concentration and yeast concentration, on the acetophenone conversion and- 1-phenylethanol enantioselectivity were investigated by orthogonal experiments.

研究了酵母细胞催化芳香酮的不对称还原反应，采用正交试验综合考察了反应温度、反应时间、底物浓度和酵母浓度等因素对底物苯乙酮转化率和产物1苯基乙醇对映选择性的影响。

In the precence of the base catalyst KF/Al2O3, the one - pot reaction of 2 -hydroxybenzaldehyde or 2 - hydroxynaphthaldehyde with ethyl α- bromoacetate,α-bromoacetophenone , 1,4 - dichloromethylbenzene , 4,4'- dichloromethylbiphenyl and 1,5 -dichloromethylnaphthalene gave the benzofuran compounds in 38-89% yield.

本文报道用 KF/Al_2O_3作为碱催化剂，由水杨醛或2-羟基-1-萘醛分别和α-溴代乙酸酯、α-溴代苯乙酮、苄基氯、4，4'-二氯甲基联苯和1，5-二氯甲基萘等进行一锅化缩合反应，以38～89％的产率合成了14种芳并呋喃化合物。

The reaction of α-hydroxyketone with Michael acceptor nitroalkene.was studied. After many experiments, we then found that in the presence of Zn2 and cinchonine, the α-hydroxyketone could successfully react with nitroalkene. Under our optimized condition, we gained the 95% yield of product with the ratio of syn : anti of 3:1 and 72% ee value for syn-product.

有机碱作用下α－羟基酮对硝基烯烃的加成反应研究研究了α－羟基酮类化合物与Michael受体硝基烯烃类化合物的反应，通过分析和实验发现在Zn2和辛可宁的作用下α－羟基苯乙酮能够与硝基烯烃化合物顺利反应，在优化的条件下以95%产率和3：1的Dr主要得到顺式产物，其中顺式产物的ee值最高为72%。

Further treatment of the Ru nanoparticles with chiral modifier (1S, 2S)-1, 2-diphenyl-1, 2-ethylene-diamirse (1S, 2S-DPEN and KOH in ionic liquid/i-PrOH mixed solvent resulted in a novel immobilized chiral catalyst which can asymmetrically hydrogenate acetophenone and its derivatives.

将此钌纳米粒子与(1S， 2S)-1，2-二苯基乙二胺（简称(1S， 2S)-DPEN）、KOH在离子液体／异丙醇介质中原位生成一种不对称加氢催化剂，用于催化苯乙酮及其衍生物的不对称加氢反应。

Ascorbic acid, a well-known natural antioxidant, was successfully used to remove the sulfonyl group of α-phenylsulfonyl acetophenone derivatives by photochemical method.

抗坏血酸作为众所周知的天然抗氧化剂，在光诱导电子转移反应中被成功地运用到α-苯磺酰基苯乙酮衍生物磺酰基基团的移除反应中。

The eight VOCs were acetophenone, phenol, benzotrichloride, 1, 3-butadiene, chlorobenzene, methanol, methyl chloroform and methylene chloride. They were mixed together with very low concentrations.

所测定的八种VOCs为苯乙酮，苯酚，三氯甲苯，1，3丁二烯，氯苯，甲醇，三氯代乙烷和二氯甲烷。

A sample-pretreated method of ether-extraction-precolumn-derivation was established, and the chromatographic conditions, which was used for determinating the derivant of extracted UDCA, were decided to be Hypersil C_(18) column(250×4.6mm, 10μm), acetonitrile-methol-0.005mol·L~(-1) phosphoric buffer-triethylamine(50:27:42:0.25, adjusted to pH3.0±0.1 by phosphoric acid) as mobile phase with detective UV wavelength at 247nm and column temperature at 35℃.

建立了乙醚提取-柱前衍生化血浆样品预处理方法，采用Hypersil C_(18)柱(250×4.6mm，10μm)，乙腈-甲醇-0.005mol·L~(-1)NaH_2PO_4缓冲液-三乙胺(50：27：42：0.25，磷酸调节pH3.0±0.1)为流动相的HPLC法，以溴苯乙酮为衍生化试剂，在247nm处测定家兔血浆中熊去氧胆酸衍生化产物。

None of them have been reported before. Some efforts were also made to find cupric ion as the right catayzer which could promote the cyclization of phenylhydrazine and a-bromoacetophenone efficiently.

为了扩展这一新的合成方法，我们用苯肼替代甲肼，发现在合适的催化剂存在下，苯肼也能够与α-溴代苯乙酮发生类似的环合反应，得到2，4-二苯基-1，2，3-三氮唑。

While in phenylhydrazine case, the intermediate phenylhydrazone was not active enough for the reaction of intermolecular condensation, unless in the presence of oxidizer, such as cupric chloride.

苯腙可以通过苯肼和α-溴代苯乙酮在没有催化剂存在下反应得到。

For a big chunk of credit-card losses; the number of filings (and thus charge-off rates) would be rising again, whether

年美国个人破产法的一个改动使得破产登记急速下降，而后引起了信用卡大规模的亏损。

Eph. 4:23 And that you be renewed in the spirit of your mind

弗四23 而在你们心思的灵里得以更新