苯乙酮

They are 4-(2- hydroxy-3-butynlenoxy) benzoic acid (1, WA), 5-chloro-7, 8-dihydroxy-7-methyl- 6-oxo-3- [ -3, 4-dihydroxy-3, 5-dimethyl-l-heptylene] -1H-8, 8a-dihydrobenzo [2, 3-c] pyran (2, WB),-2-(2-methyl-2-dibutene diamido)-2-butenoic acid (3, B5262), 3, 4-dihydro-9, 10-dihydroxy-7-methoxy-3-methyl-1H-naphtho [2, 3- c] pyran-1-one (4, A73 semi-Vioxanthin), 8, 8'-bis (6, 9-dioxo-3,4-dihydro-10- hydroxy-7-methoxy-3-methyl-1H-naphtho [2, 3-c] pyran-1-one)(5, A122 Xanthomegnin), 2, 5-dioxo-3a-hydroxymethyl-3, 3a, 6, 6a-tetrahydro-furo [2, 3-b] furan (6, 1003-2), 7-acety1-5-chloro-6, 8-dioxo-7-methyl-3- [ -3, 5-dimethyl-1, 3- diheptylene] -4aH-benzo [2, 3-c] pyran (7, M2-2 sclerotiorin), respectively.

它们分别被命名为4-（2-羟基-3-丁炔氧基）苯甲酸（1，WA）、5-氯-7，8-二羟基-7-甲基-6-氧代-3-[-3，4-二羟基-3，5-二甲基-1-庚烯基]-1H-8，8a-二氢苯并[2，3-c]吡喃（2，WB）、-2-（2-甲基-2-丁烯二酰亚胺基）-2-丁烯酸（3，B5262）、3，4-氢-9，10-二羟基-7-甲氧基-3-甲基-1H-萘并［2，3-c］吡喃-1-酮（semi-Vioxanthin，4，A73）、8，8'-双（6，9-二氧代-3，4-二氢-10-羟基-7-甲氧基-3-甲基-1H-萘并［2，3-c］吡喃-1-酮）（Xanthomegnin，5，A122）、2，5-二氧代-3a-羟甲基-3，3a，6，6a-四氢-呋喃并［2，3-b］呋喃（6，1003-2），7-乙酰基-5-氯-6，8-二氧代-7-甲基-3-［-3，5-二甲基-1，3-庚二烯基］-4aH-苯并2，3-c］吡喃（Sclerotiorin，7，M2-2）。

The results showed that there were 8 kinds of aliphatic, 5 kinds of esters, 2 kinds of aldehydes, 2 kinds of nitrogen sulfur heterocyclic rings and one kind of hydrocarbon, alcoholics, ketone, lactones respectively in the analyzed 21 kinds of aroma components, and the content of furfural,β-methyl valeric acid, palmitic acid, nicotine, neohytadiene were higher, next were acetyl ethyl propionate, caleric acid, phenyl ethyl acetate, hydroxylic diethyl succinate.

结果表明，在分析出的21种香气成分中，分别有脂肪酸类8种，酯类5种，醛类2种，氮硫杂环类2种，烃类、醇类、酮类、内酯类各l种，其中相对含量较高的物质成分是糠醛、β-甲基戊酸、十六碳酸、烟碱、新植二烯，其次是乙酰丙酸乙酯、异戊酸、苯乙酸乙酯、羟基丁二酸二乙酯等。

In ethylene glycol solution, 1 was converted into 1-oxo-13c-(2-hydroxyethoxy)-1, 13c-dihydro-dibenzo -xanthene (23) and ketal compound 7a, 13bethylenedioxy-1-hydroxy-7a, 13b-dihydro-dibenzo -xanthene (24), the structure of which was confirmed by X-ray single crystal diffraction.

在乙二醇中反应时，1被氧化为二苯并咕吨型的23和缩酮型的7a，13b-亚乙二氧-1-羟基-7a，13b-二氢-二苯并-咕吨（24）。24的结构得到X-ray单晶衍射的证实。

In the presence of ethanol- HCl solution, arylamine-HCl and w=37% aqueous formaldehyde solution or the condensation product of arylamine and formaldehyde are directly reacted with ethyl 3-oxo-2-phenylmethylenebutyrate to form l-aryl-2-phenyl-3-carbethoxy-4-piperidone.

2－苯亚甲基－3－丁酮酸乙酯与芳香胺和w＝37％甲醛水溶液或芳胺和甲醛的缩合物在氯化氢－无水乙醇存在下可直接发生的Mannich反应，得到1－对位取代芳基－2－苯基－3－羰乙氧基－哌啶－4－酮。

The major contents in this thesis are described as follows:(1) Seven new thiol fluorescence reagents containing 2-phenylbenzoxazole (or 2-phenylbenzothiazole) derivatives or benzanthrone as fluorphore and iodinacetylamine or maleimide as reaction groups have been synthesized.

本论文的研究工作主要分为以下几个方面：(1)以碘乙酰胺或马来酰亚胺为反应基团和以2-芳基苯并噁唑类化合物或苯并蒽酮为荧光团，首次合成了七种新的碘乙酰胺类和马来酰亚胺类巯基荧光试剂。

Universal indicator paper,special indicator paper,ammonium fluoride,ammonium hydrogen difluoride,nbenzyldimethylamine,disinfectant paper,nacetylphenylhydrazine,mcresol purple,bromocresol green,fluorescein,eosin Y,ninhydrin,phenedons,potassium phthalate,pamimobenzene sulphonic acid anhydrous.

广泛试纸，精密试纸，氟化铵，氟化氢铵，N苄基二甲胺，消毒试纸，N乙酰苯肼，间甲酚紫，溴甲酚绿，荧光素，曙红Y，水合茚三酮，菲尼酮S，苯甲酸氢钾，无水对氨基苯磺酸。

Results: The 12 kinds of toxicants including methyl acetate, ethyl acetate, benzene, toluene, ethylbenzene, butyl acetate, p-dimethylbenzene, m-dimethylbenzene, o-dimethylbenzene, n-butanol, cinnamene and cyclohexanone were separated well. Good linear relationship sensitivity and reproducibility were obtained and detection limits (S/N=3) of them were 0.2 mg/l respectively. Conclusion: In this paper, a new method for simultaneous determination of 12 kinds of toxicants by using gas chromatography has been described.

结果：对乙酸甲酯、乙酸乙酯、苯、甲苯、乙酸丁酯、乙苯、对二甲苯、间二甲苯、邻二甲苯、正丁醇、苯乙烯、环己酮12种有毒物质的分离效果好，线性和重现性均较好，方法的检测限达到0.2 mg/L。

Synthesis of Antidote of N-Dichloroacetyl-2-methyl-1-oxa-4-aza-spiro-4.4-nonane BI Hong-mei, ZHANG Jin-yan, LIANG Ying, SHEN Yong (College of Arts and Sciences Heilongjiang August First Reclamation University, Daqing 163319, Heilongjiang, China) Abstract: N-Dichloroacetyl-2-methyl-1-oxa-4-aza-spiro-4.4-nonane was synthesized by one pot method with isopropanolamine, cyclopentanone and dichloroacetyl chloride. The optimum reaction conditions obtained are as follows:the proportion in moles of the above materials is 1∶1∶1.2, reaction solvent is toluene, reaction temperature is -15 to -10 ℃,reaction time is 3 h, under the optimum condition, the yield of the compound is 50.0%.

除草剂解毒剂N-二氯乙酰基-2-甲基-1-氧杂-4-氮杂-螺[4.4]壬烷的合成毕洪梅，张金艳，梁英，沈勇(黑龙江八一农垦大学文理学院，黑龙江大庆 163319)摘要：以33%的氢氧化钠水溶液为缚酸剂，异丙醇胺、环戊酮和二氯乙酰氯为原料，采用&一锅法&合成了N-二氯乙酰基-2-甲基-1-氧杂-4-氮杂-螺[4.4]壬烷，采用正交实验法得到最佳反应条件：反应原料摩尔比为1∶1∶1.2，苯作溶剂，反应的温度为-15 ℃~-10 ℃，搅拌时间为3 h，产率达到50.0%。

Bezaldehyde was used as protective agent in first method.S-Epichloeohydrin was aminated and acidulated to give(2S)-1-Amino-3-chloro-propanol Salts.The acetylation of (2S)-1-Amino-3-chloro-propanol by acetic anhydride produced the intermediate-N-[2--3-chloropropyl]acetamide.And then at 20℃,in the presence of lithium tert-butoxide,benzyl 3-fluoro-4-morpholinophenyl carbamate react with-N-[2--3-chloropropyl]acetamide to give linezolid in total yield of 43.6%.

路线一采用苯甲醛作保护剂，使S-环氧氯丙烷氨解、酸化生成S-1-氨基-3-氯-2-丙醇盐酸盐，然后经乙酰化反应后，生成中间体-N-[2-乙酰氧基-3-氯丙基]乙酰胺，再用N-(3-氟-4-吗啉苯基)氨基甲酸苄酯和中间体在催化剂叔丁醇锂存在下25℃反应生成利奈唑酮，总产率达到43.6%。

A plausible process of this reaction is as following: Aldehyde was in equilibrium with the enol form, aldehyde reacted with aniline catalyzed by 2,2,2-trichloroacetic acid to afford imine, the generated imine immediately reacted with enol to form intermediate via intramolecular cyclization.

我们发现一分子芳基叠氮和一分子三苯基磷反应生成一分子磷亚胺，后者与由两分子取代的苯氧乙酰氯原位生成的烯酮反应生成4-亚烷基-β-烷基-内酰胺，其串联过程涉及烯酮亚胺的形成及其与烯酮的[2+2]的环加成反应。

For a big chunk of credit-card losses; the number of filings (and thus charge-off rates) would be rising again, whether

年美国个人破产法的一个改动使得破产登记急速下降，而后引起了信用卡大规模的亏损。

Eph. 4:23 And that you be renewed in the spirit of your mind

弗四23 而在你们心思的灵里得以更新