苯乙烯的

It is demonstrated that the chiral quaternary ammonium salts catalysts exhibit promising catalytic properties for the substrate. Part III: The synthesis and the characterizing of the macroporous aminomethyl resin-supported cinchona alkaloid complexes and the study on its catalytic properties The part consists of two subsections. the macroporous aminomethyl resin -supported cinchona alkaloid complexes were synthesized by the stuff (cinchonine, quinine and macroporous aminomethyl resin). Their structures were characterized by means of elemental analysis, XPS, TG/DTA; the chiral polymer-supported complexes were first used as catalysts for the reduction of ketones. Their catalytic properties for the reduction processes were investigated. The comparison of the products e.e., the conversion of the substrate among different reduction processes was employed with determined by HPLC. The effects of the time, the temperature, the ratio of catalyst to substrate, reaction solvent as well as the recycle times were also discussed.

第三章聚-4-氨甲基苯乙烯负载金鸡纳碱金属络合物的合成与表征及其不对称催化性能研究本章分为两节，以辛可宁和奎宁及聚-4-氨甲基苯乙烯为原料，合成了4种聚-4-氨甲基苯乙烯负载金鸡纳碱络合物催化剂，并对它们的结构用元素分析、X-射线光电子能谱、TG/DTA等几种测试手段进行了表征；首次将所合成的手性高分子负载的金属络合物用于催化芳香酮不对称还原反应，详细研究了所得的手性高分子负载的金属络合物对不同底物的催化性能，用HPLC等分析手段定量检测了还原过程的底物转化率及其产物对映异构体选择性，并考察了反应时间、反应温度、催化剂和底物投料比、反应溶剂和循环次数对催化性能的影响。

Green Star 1862 Ready Mixed Wallcovering Adhesive is a PVA based product, which has been specially, formulated for use with luxury vinyl, textiles, Hessians, polystyrene tiles, polystyrene coving and polystyrene veneers.

Green Star 1862已拌墙纸胶粘剂是基于PVA而开发的产品，，它是特别为与昂贵的乙烯基，纺织品、粗麻布，多苯乙烯瓦片，多苯乙烯和多苯乙烯表面饰板的粘贴而研制的。

Being combining with products distribution in styrene oxidation, we propose the styrene epoxidation carry out with Ti metallacyclo intermediates, And at the same time Ti-ZSM-5 have properties both catalytic epoxidation and acid-catalysis, namely the skeletal Ti can catalyze styrene epoxidation to styrene oxide and the skeletal Ti and Al can provide Lewis acid site to cause the rearrangement of styrene oxide to phenylacetaldehyde rapidly, the solvolysis to glycols and the cleavage of C=C double bond. Ti-ZSM-5 can also provide Bronsted acid site simultaneously, which is also catalytic center for the solvolysis to glycols.

同时结合Ti-ZSM-5催化选择性氧化苯乙烯反应的产物分布结果，提出苯乙烯环氧化反应可能是通过金属有机环机理进行；Ti-ZSM-5同时具有催化环氧化和酸催化两种功能，其骨架钛可催化苯乙烯环氧化生成环氧苯乙烷，而骨架钛和骨架铝等可提供Lewis酸位使环氧苯乙烷迅速发生重排生成苯乙醛从而使其成为反应的主要产物，同时还可发生加成以及碳碳键的裂解等副反应：Ti-ZSM-5也提供Bronsted酸位，它也是生成加成产物的活性中心。

Cloud point curves from light scattering experiment verify the calculation results;The agreement between the cloud point curve s and the binodal is quite well.

用浊点测定、傅里叶变换红外光谱和微差扫描热分析等方法研究了苯乙烯-顺丁烯二酸酐共聚物与苯乙烯-丙烯腈共聚物共混物的相容性。

When pumped with 800 nm laser irradiation, 2 {4 [2 (4 dimethylamino phenyl vinyl] phenyl} ethylamino ethanol and 2 {4 [2 (4 diethylamino phenyl vinyl] phenyl} ethylamino ethanol show strong two photon induced blue fluorescence at 436 and 440 nm respectively, while DMANHAS and 4 nitro benzoic acid 2 {4 [2 (4 diethylamino phenyl vinyl] phenyl} ethylamino ethyl ester exhibit no fluorescence.

在800 nm的飞秒脉冲激光激发下，反式-4-(N-羟乙基-N'-乙基氨基)-4'-二苯乙烯和反式-4-(N-羟乙基-N'-乙基氨基)-4'-二苯乙烯均发出较强的蓝紫色上转换荧光，荧光峰分别位于436和440 nm，而DMANHAS和反式-4-[N-(乙氧基羰基-4-硝基苯基)-N'-乙基氨基]-4'-二苯乙烯没有荧光。

Firstly, partial sulfonated polystyrene were prepared by solution polymerization with the raw materials of styrene, sodium styrene sulfonate and divinyl benzene; Secondly, the SPS/OMMT nanocomposites were prepared by intercalation polymerization with the monmers and organically modified montmorillonite.

首先，利用NMP为溶剂，BPO引发苯乙烯、苯乙烯磺酸钠、二乙烯基苯溶液共聚；同时，采用高分子的单体与有机蒙脱土插层聚合制备了磺化聚苯乙烯阳离子树脂／蒙脱土复合材料。

The organic montmorillonite VC18-MMT was prepared by the exchanging inorganic cations with vinylbenzyldimethyloctadecylammionun chloride which could be co-polymerized with styrene.The predispersion of VC18-MMT was realized via sonicating the suspension of the montmorillonite particles in emulsifier solution,and then the styrene was added into the system and the in situ emulsion polymerization was carried out to prepare PS/VC18-MMT nanocomposites.

以可与苯乙烯发生共聚的阳离子表面活性剂乙烯苄基二甲基十八烷基氯化铵为插层处理剂改性蒙脱土（VC18-MMT），有机蒙脱土在超声波强剪切作用以及乳化剂作用下预分散在乳化剂溶液中，然后引入苯乙烯单体进行原位乳液聚合制备聚苯乙烯/蒙脱土纳米复合材料。

A series of sulphonated SBS were achieved by reacting SBS blockcopolymer with sulphuric acid, meanwhile, the blends of PVC andsulphonated SBS were studied. By means of strength capabilityexamination and DSC analysis, it was found the miscibility wasincreased after SBS was sulphonated.2 The chemical grafting of styrene and PVC membrane2.1 The reaction condition of graftingBy means of the swelling and seepage of Styrene to PVC film,St was grafted onto PVC film by the initiation of BPO .

采用硫酸对热塑性弹性体SBS进行磺化，得到不同磺化度的产物，并对其与PVC的物理共混进行了研究；通过力学性能及DSC测试，发现SBS磺化后增加了与PVC的相容性(来源：Af2a2a2BC论文网www.abclunwen.com)。2 苯乙烯与聚氯乙烯膜的化学接枝2.1 苯乙烯与聚氯乙烯膜接枝条件利用苯乙烯对PVC的溶胀渗透，在过氧化苯甲酚的引发下发生接枝共聚反应。

Styrene degassing tower is one of chief equipments of styrene monomer recover system of StyreneButadiene Rubber device.

苯乙烯脱气塔是丁苯橡胶装置中苯乙烯单体回收系统的主要设备。

Underoptimal conditions, in toluene / dimethyl phthalate / TBP, after EAHQ was oxidizedwith 〓, then the catalyst and styrene were added, the conversion of styrene basedon EAHQ is 68%, the selectivity for styrene oxide based on styrene is 92% and theTON of the catalyst is 500; in toluene / phenyl ether / TBP, epoxidation of styrenewas performed with 〓 generated in situ, the conversion is 46%, the selectivity is94% and the product can be separated by distillation under reduced pressure.

优化条件下，甲苯／邻苯二甲酸二甲酯／TBP(2／2／1，体积比)中，EAHQ先用〓氧化完全后，再加入催化剂A和苯乙烯进行环氧化反应苯乙烯相对于EAHQ的转化率为68％，生成环氧苯乙烷的选择性为92％，催化剂A的TON达到500；甲苯／二苯醚／TBP(1／3／1，体积比)中，原位生成〓条件下苯乙烯相对于EAHQ的转化率为46％，生成环氧苯乙烷的选择性为94％，产物可通过减压蒸馏分离。

The split between the two groups can hardly be papered over.

这两个团体间的分歧难以掩饰。

This approach not only encourages a greater number of responses, but minimizes the likelihood of stale groupthink.

这种做法不仅鼓励了更多的反应，而且减少跟风的可能性。