苯乙烯的

The effects of the composition of catalyst (the structure and amount of bident ligand and strong acid, the cocatalytic activity of Cu〓, the roles of methanol and phenol etc.) and the copolymerization condition (the reaction time, temperature, amount of ST and CO, the structure and amount of solvent etc.) on catalytic activity were studied. The principle of the copolymerization was investigated.

研究了催化体系组成（含氮双齿配体的结构与用量、强酸的结构与用量、铜盐的助催化作用、甲醇和酚类化合物作用等）和共聚反应条件（共聚反应的温度与时间、溶剂种类与用量、苯乙烯与一氧化碳量等）对溶液共聚反应的催化活性的影响，探索溶液聚合反应规律。

The polymerization systems can be divided into four categories: styrol, acrylate, hydrophilic and non-ethylene according to the difference of the structure and characteristic of the monomer.

总结了目前各种不同组成的分散聚合体系，按单体的结构、性质的差异，分别介绍了苯乙烯类、丙烯酸酯类、亲水性单体类、非乙烯单体类的分散均聚合研究情况，列出了各种分散聚合体系中的介质、稳定剂和引发剂等组成。

This paper contains three parts: 1 Synthesis of novel titanium complexes; 2 Polymerization behaviors of alkoxyl substituted Cp Titanocenes as catalysts for styrene syndiotactic polymerization; 3 Polymerization behaviors of alkenyl substituted Cp Lanthanocenes as Methyl Methacrylate polymerization catalysts.

中文题名新型茂钛、噁唑啉钛络合物的合成、表征以及茂钛、茂稀土络合物催化性能的研究副题名外文题名 Synthesis，characterization of novel Cp，oxazoline titanium complexes and polymerization behaviors of titanocenes and lanthanocenes 论文作者张浩导师钱延龙黄吉玲学科专业应用化学研究领域\研究方向金属有机与均相催化学位级别博士学位授予单位华东理工大学学位授予日期2003 论文页码总数148页关键词金属有机化学稀土络合物噁唑啉类钛络合物茂钛络合物馆藏号BSLW /2003 /O627 /27 本论文包括三部分内容：1）有机金属钛络合物的合成；2）烷氧基取代茂钛络合物催化苯乙烯间规聚合的研究；3）烯基取代茂稀土络合物催化甲基丙烯酸甲酯聚合的研究。

Two kinds of high alcohol acrylates were prepared by octadecyl alcohol and hexadecyl branched alcohol,respectively.The polymers of depressants were prepared by maleic anhydride-styrene-higher alcohol acrylates.By using these depressants,the pour points of the Liaohe crude oils were lowered form 30℃ to 20℃.

分别采用碳十八直链醇、碳十六支链醇与丙烯酸合成烷基酯，将烷基酯再与顺丁烯二酸酐、苯乙烯聚合制备的三元共聚物，对辽河油田的高凝原油的降凝效果进行了评价，实验发现这两种聚合物对凝固点为30℃原油都具有较好的效果，降幅可达10℃左右，但对凝固点为41℃的原油较差分别为3℃和6℃。

Due to great amount of double bond on rubber chain,a lot of intramolecular reaction occurred in the system,which made the uncontrolled cross-linked system into a controlled cross-linked copolymerization,resulting in chain growth can't go illimitably in cross-linking process.

苯乙烯和二乙烯苯共聚体系是典型的不可控制的交联聚合体系，加入天然橡胶后，通过阳离子聚合方法，生成三元共聚物线团，由于橡胶分子链上含有大量的双键，聚合体系中能进行分子内反应，使不可控的交联聚合体系成为可控的交联聚合体系，其链增长不能无限制进行，从而可以合成可溶解的交联的聚苯乙烯-二乙烯苯-天然橡胶聚合物。

Comparative study of the properties of both ground and excited states of metal-free indoline dyes for dyesensitized solar cells revealed: as the number of rhodanine rings increases, the energy difference between HOMO and LUMO decreases and there is a red shift in the absorption spectrum with the binding energy increased, and the transition dipole moment decreased; Based on an analysis of cha...

对比研究吲哚染料的基态和激发态性质，揭示了随着绕丹宁环数目的增加，HOMO和LUMO的能量差减少，吸收光谱红移，但是束缚能增加，跃迁偶极矩减少；依据电荷差分密度，电荷和能量从苯乙烯转移到吲哚环和绕丹宁；电子空穴相干性主要表现在吲哚环和绕丹宁环，对于吲哚染料系统，存在一个绕丹宁环的体系的激子数目为30个原子，带有两个绕丹宁环的体系激子数目有40个原子。

The present invention provides a multinuclear half metallocene compound in which two or more of transition metals of groups 3 to 10 on periodic table are connected through bridge ligand simultaneously containing Pi-ligand cycloalkandienyl group and Alpha-ligand functional group and its preparation, and a process for preparing styrene polymer using the compound as a catalyst.

本发明提供了一种其中的两个或更多元素周期表第3-10族过渡金属通过同时包含π-配体环烷基二烯基团和α-配体功能基团的桥配体连接的多核半金属茂络合化合物及其制备方法，及使用本化合物为催化剂的苯乙烯聚合体的制备工艺。

In solid phase process, the polyiodides, which include triiodide, pentaiodide, heptaiodide, nonaiodide and undecaiodide tetra-n-butyl ammonium iodide, tetrabutyl ammonium bromide and tetramethyl ammonium iodide poly-compounds, were synthesized by the low-heat solid phase reaction between iodine and tetra-n-butyl ammonium iodide, tetrabutyl ammonium bromide or tetramethyl ammonium iodide; In complexation process, solution polyiodides were synthesized by complexing action of different agents; In resinifying process, triiodide, pentaiodide, heptaiodide resinic polyiodides were synthesized by ion-exchange when the strong basicity styrene anion exchange resin, potassium iodide and iodine were used as raw materials.

固相法是用正四丁基碘化铵、四丁基溴化铵或四甲基碘化铵分别与碘作用，通过低热固相反应，合成出碘三、碘五、碘七、碘九和碘十一形式的正四丁基碘化铵、四丁基溴化铵或四甲基碘化铵的系列高聚碘化合物；在络合法合成溶液高聚碘的实验中，选用几种络合剂通过络合作用首次合成了溶液高聚碘；树脂法合成高聚碘的实验是采用强碱性苯乙烯系阴离子交换树脂、碘化钾和碘为原料，通过离子交换，合成了碘三、碘五和碘七形式的树脂高聚碘。

Wedgeplug O-Seal plug valves with their positive, no-leak features are not only recommended as the best general purpose valves for handling hydrocarbons, vegetable oils, solvents, etc., but are ideal for such tough service as butane, propane, butadiene, acetone, ethyl alcohol, ammonia, anhydrous ammonia, benzene, vinyl chloride, dry chlorine, Dowtherm, ethane, ethylene, hydrogen chloride, napthalene, oxygen, hydrogen, phthalic anhydride, dry phosgene, phosphoric acid, potassium carbonate, styrene, molten sulphur, sulphur dichloride and related services within a temperature range from -300oF to + 450oF within pressure limits of the valves.

楔塞O形密封旋塞阀具有积极的、无泄漏特性，不但是最好的通用的阀门，用于处理碳化氢，植物油，溶剂等，还特别适用于严酷的应用环境，如丁烷，丙烷，丁二烯，丙酮，乙醇，氨，无水氨，苯，氯乙烯，干氯，道氏热载体，乙烷，乙烯，氯化氢，萘，氧，氢，邻苯二甲酸酐，干碳酰氯，磷酸，碳酸钾，苯乙烯，融化硫，二氯化硫，以及温度在-184oC至232oC之间，压力在阀门额定压力等级范围内的有关应用。

One monolayer of CSB deposited on Au/Ge(111)-√3 at 220 K followed by cooling to 100 K leads to the formation of a well ordered (2×1) structure as observed by LEED. The TPD spectra for CSB thermal desorption from Au/Ge(111)-√3 exhibit showed two well-resolved peaks at Tp = 243 and 274 K corresponding to multilayer and monolayer desorption, respectively.

我们也尝试利用LEED观察二苯乙烯吸附在(√3×√3)R30°表面的规则排列，并且成功看到(2×1)的LEED绕射图谱，另外我们也架设一组氦氖雷射来测定表面上吸附物的光学反射率变化，在金属覆盖的锗(111)单晶表面上，确定Au覆盖量不同会造成反射的变化。

The split between the two groups can hardly be papered over.

这两个团体间的分歧难以掩饰。

This approach not only encourages a greater number of responses, but minimizes the likelihood of stale groupthink.

这种做法不仅鼓励了更多的反应，而且减少跟风的可能性。