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The research of ethylbenzene dehydrogenation kinetics has been carried out in an experimental adiabatic reactor.

在实验室绝热反应器中进行了乙苯脱氢制苯乙烯的反应动力学研究。

The catalytic performance for the Heck reactions of various substituted aryl halides with acrylic acid or styrene was studied.

研究了该催化剂对各种取代卤代苯与丙烯酸、苯乙烯的Heck芳基化反应催化性能。

In this work, self-emulsified emulsion copolymerization of styrene and unsaturated polyester was studied.

本论文还进行了不饱和聚酯/苯乙烯的自乳化乳液聚合研究。

Objective To establish solvent desorption gas chromatographic method for determination of o-chlorostyrene in workplace air.

目的建立工作场所空气中邻氯苯乙烯的溶剂解吸气相色谱测定方法。

The results of dimerization of α-methylstyrene indicate that no products were detected at room temperature and it is benefieial to the reaction to raise temperature .

同时,α-甲基苯乙烯的二聚反应表明,室温下不发生反应,提高温度有利于反应进行。

Expected part of the next two years will have production capacity of styrene production.

预计未来两年,将有生产苯乙烯的生产能力。

The latices were stable ,thixotropic and monodisperse .The particle sizes range from 192 to 94 nm depending on the acrylamide fractions. The Hofmann reactions of these latices were carried out to introduce primary amines on the particle surface.

由于一直以来,丙烯酰胺-苯乙烯的共聚物胶乳只能用于制备两性胶乳,为了得到较高的胺化度,我们对不同单体配比的丙烯酰胺-苯乙烯共聚物胶乳进行Hofmann反应,探讨了丙烯酰胺在单体中所占的比例对Hofmann反应的影响。

Chiral ligands mentioned above and their complexes with acetate copper were used as enantio-selective catalysts in asymmetric cyclopropanation reactions of diazoacetate and 1,1-diphenyl ethylene. Investigations indicate that all of them reveal certain optical-selective capability, but chiral C2-symmetric 2,6-bispyridine ligands show better catalytic capability than chiral asymmetric schifF-base ligands.

选择了2个手性2,6-吡啶双噁唑啉配体和6个手性不对称席夫碱配体与醋酸铜形成的配合物作为催化剂,对重氮乙酸乙酯与1,1-二苯乙烯不对称环加成进行催化反应,发现这8个催化剂对1,1-二苯乙烯的不对称环丙烷化反应都表现出了一定的光学活性诱导能力,手性2,6-吡啶双噁唑啉-铜类具有比手性Schiff碱-铜类更好的催化性能。

In the mixed solvent of dimethyl phthalate / TBP or phenyl ether / TBP, the selectivity for styrene oxide is good but the conversion of styrene is low due to the coordination to the catalyst of the solvent.

邻苯二甲酸二甲酯或二苯醚等与磷酸三丁酯的混合溶剂中环氧化的选择性较高,但由于溶剂对催化剂的配位作用抑制了催化剂的活性,苯乙烯转化率很低;当部分的邻苯二甲酸二甲酯或二苯醚被甲苯取代后,苯乙烯的转化率提高,生成环氧苯乙烷的选择性不变。

In this thesis, this system is used for epoxidation of propylene and styrenewith good results. The solvent effect is investigated for epoxidation of styrene. In the mixedsolvent of dimethyl phthalate / TBP or phenyl ether / TBP, the selectivity for styreneoxide is good but the conversion of styrene is low due to the coordination to thecatalyst of the solvent. When part of dimethyl phthalate or phenyl ether is replacedby toluene, the conversion increases and the selectivity keeps constant.

邻苯二甲酸二甲酯或二苯醚等与磷酸三丁酯的混合溶剂中环氧化的选择性较高,但由于溶剂对催化剂的配位作用抑制了催化剂的活性,苯乙烯转化率很低;当部分的邻苯二甲酸二甲酯或二苯醚被甲苯取代后,苯乙烯的转化率提高,生成环氧苯乙烷的选择性不变。

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