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苯乙烯基

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Bromoethyl benzene was synthesized by anti-Markovnikov addition of hydrogen bromide to styrene under ultraviolet light irradiation.

在紫外线的照射下,苯乙烯与溴化氢气体发生反马氏规则自由基加成反应,可合成β-溴乙苯。

Bromoethyl benzene was synthesized by anti-Markovnikov addition of hydrogen bromide to styrene.

通过苯乙烯与溴化氢气体发生反马氏规则自由基加成反应,合成了β-溴乙苯。

The prepared supported palladium catalyst with ultra thin fiber morphology can hydrogenate olefin and nitrobenzene hydrogenation in high efficiency. The loss of noble metal was reduced and the quality of the product was improved for formation of chemical bond between metal and polymer.

本论文以电纺丝技术为基础,利用聚丙烯腈、苯乙烯-丙烯腈共聚物、聚乙烯基吡咯烷酮和壳聚糖衍生物等为载体,制备出了负载钯的超细纤维无纺布形态催化剂,并对其催化加氢性能进行了讨论研究。

UV and HPLC were used for the first time to study the photo-cis-trans isomerism in dilute DNS solution.

首次采用紫外光谱和高压液相色谱初步研究了4,4'-二硝基二苯乙烯-2,2'-二磺酸稀溶液中的光致顺反异构现象。

Besides,through Arbuzov reaction,Vilsmer-Haack Hydroformylation,Wittig-Horner reaction,nitryl hydrogenation deoxidize,and imidization five steps synthesized another compound which included hole-transporting,electron-transporting and luminescence materials.

此外,又通过Arbuzov反应、Vilsmer-Haack甲酰化反应、Wittig-Horner反应生成二苯乙烯、硝基加氢还原、酰亚胺化5步反应合成了一种集空穴传输-电子传输-发射三位一体的新型苝酰亚胺化合物。

Experimentally,among the calculated compounds,4,4′—bis(di-n-butylamino)stilbene and 4,4′—bisstilbene were synthesized at first.

其中对于化合物4,4′—二甲胺基二苯乙烯,从理论计算、分子设计、材料合成到实验研究,是尚未见报道的新工作。

Under these conditions, the yields of anthraquinone and stilbene glycoside are 1.06% and 5.03% respectively, and the clearance rate to DPPH is 58.7%.

在此条件下蒽醌类物质的得率为1.06%,二苯乙烯苷得率5.03%,DPPH自由基清除率为58.7%。

S Vinylidene chloride/acrylonitrile/styrene suspension terpolymer was synthesized with AIBN as initiator.

VDC 丙烯腈苯乙烯三元悬浮共聚树脂便是常见用作制备泡沫材料的基体树脂之一[3~ 5] 。

Second, the polymerization behaviors of alkoxyl substituted Cp titanocene for styrene syndiotactic polymerization were investigated.

其次,本文研究了烷氧基取代的茂钛络合物对苯乙烯间规聚合的催化作用。

To further study the chemical constitutes of lipophilic active parts, we prepared Alc95% and Alc50% according to original literature. 20 compounds were isolated by using macroporous resin, silica gel, polyamide, Sephadex LH-20, Rp-18, preparative TLC and preparative HPLC chromato-graphy. The structures of them were elucidated by means of physical and chemical properties, modern spectroscopic analysis techniques—UV、IR、 EI/MS、ESI/MS、〓H-NMR、〓C-NMR、DEPT、HMQC、HMBC. They are nine anthraquinones: chrysophanol (95-1), physcion (95-2), emodin (95-5), aloemodin (95-7), rhein (50-1), sennoside A or B (50-6),ω-hydroxylemodin (95-10), chrysophanol-8-0-β-D-glucoside (95-12), aloemodin-ω-0-β-D-glucoside (95-13); three phenanthaquinones: tanshinone ⅡA (95-3), cryptotanshinone (95-6), tanshinone Ⅰ(95-4); one isoflavone: 7, 3'-dihydroxyl-5' methoxyisoflavone (95-14) and protocaechuic aldehyde (95-9), protocaechuic acid (95-11), astragaloside Ⅳ(50-4), amygdalin (50-5), 2, 3, 5, 4'-tetrahydroxylstilbene-2-0-β-D-glucoside (50-3),-catechin (50-2), cinnamic acid (95-8). Among them, 3'-dihydroxyl-5' methoxyisoflavone (95-14) is a new compound.

经过溶剂萃取、大孔吸附树脂富集、Sephadex LH-20精制、制备TLC及Semi-pre HPLC等手段从中分离了20个化合物,利用理化性质和波谱技术(UV、IR、EI/MS、ESI/MS、〓H-NMR、〓C-NMR、DEPT、HMQC、HMBC)相结合鉴定了它们的结构,分别为9种蒽醌类化合物:大黄酚,大黄素甲醚,大黄素,芦荟大黄素,大黄酸,番泻苷A或B,ω-羟基大黄素(ω-hydroxylemodin),大黄酚-8-0-β-D-葡萄糖苷(chrysophanol-8-0-β-D-glucoside),芦荟大黄素-ω-0-β-D-葡萄糖苷(aloemodin-ω-0-β-D-glucoside);3种菲醌类化合物:丹参酮ⅡA(tanshinoneⅡA),隐丹参酮,丹参酮Ⅰ(tanshinone Ⅰ);1种异黄酮:7,3'-二羟基-5'-甲氧基异黄酮(7,3'-dihydroxy-5' methoxyisofla-vone)以及原儿茶醛,原儿茶酸,黄芪甲苷(astragaloside Ⅳ),苦杏仁苷,2,3,5,4'-四羟基二苯乙烯-2-0-β-D-葡萄糖苷(2,3,5,4'-tetrahydroxylstilbene-2-O-β-D-g1ucoside),Z—儿茶素,桂皮酸。

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