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苯乙烯基

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Surface modification of up-conversion luminescence by overcoating with carboxyl groups and its characterization;2. The effects of concentration and adding methods of acrylic acid on the content of carboxyl groups on the magnetic microspheres surface were studied.

利用双层表面活性剂改性的Fe3O4磁流体为种子,通过乳液聚合法考察了苯乙烯或苯乙烯-丙烯酸对Fe3O4磁流体的包覆情况,并考察了丙烯酸浓度及加入时间对磁性微球表面羧基含量的影响。

The mechanism of dioxygen oxidation of 4-nitrotoluene-2-sulfonic acid to 4,4'-dinitrostilbene-2,2'-disulfonic acid in alkali solution under mild condition was investigated.

探讨了在温和条件下在碱的水溶液中氧气液相氧化 4-硝基甲苯- 2 -磺酸制取 4,4'-二硝基二苯乙烯- 2 ,2 '-二磺酸的反应机理,发现 4-硝基甲苯- 2 -磺酸在碱作用下发生离子化生成 4-硝基- 2 -磺酸基苄基阴离子,然后被活化的分子氧氧化成 4-硝基- 2 -磺酸基苄基自由基是反应的关键步骤。

A CR/polystyrene IPN blend was prepared by stepwise synthesis based on CR and styrene monomer and using divinyl benzene as crosslinking agent of PS.

以CR和苯乙烯单体为原料,二乙烯基苯为苯乙烯的交联剂,采用分步合成法制备CR/聚苯乙烯互穿网络共混物。

Firstly, partial sulfonated polystyrene were prepared by solution polymerization with the raw materials of styrene, sodium styrene sulfonate and divinyl benzene; Secondly, the SPS/OMMT nanocomposites were prepared by intercalation polymerization with the monmers and organically modified montmorillonite.

首先,利用NMP为溶剂,BPO引发苯乙烯、苯乙烯磺酸钠、二乙烯基苯溶液共聚;同时,采用高分子的单体与有机蒙脱土插层聚合制备了磺化聚苯乙烯阳离子树脂/蒙脱土复合材料。

The organic montmorillonite VC18-MMT was prepared by the exchanging inorganic cations with vinylbenzyldimethyloctadecylammionun chloride which could be co-polymerized with styrene.The predispersion of VC18-MMT was realized via sonicating the suspension of the montmorillonite particles in emulsifier solution,and then the styrene was added into the system and the in situ emulsion polymerization was carried out to prepare PS/VC18-MMT nanocomposites.

以可与苯乙烯发生共聚的阳离子表面活性剂乙烯苄基二甲基十八烷基氯化铵为插层处理剂改性蒙脱土(VC18-MMT),有机蒙脱土在超声波强剪切作用以及乳化剂作用下预分散在乳化剂溶液中,然后引入苯乙烯单体进行原位乳液聚合制备聚苯乙烯/蒙脱土纳米复合材料。

The diblock copolymer of styrene and chloromethyl-4-vinyl-benzene was obtained by means of reverse addition fragmentation chain transfer reaction living free radical polymerization. The chloromethyl groups in PS-bPCVB were transformed into azidomethyl groups, and then into 1,2,3-triazol groups via click chemistry. The diblobk copolymer containing 1,2,3-triazol groups was thus obtained. The results from NMR spectra suggested a complete transformation from chloromethyl groups to triazol groups.

通过RAFT活自由基聚合方法制备聚(苯乙烯-b-对氯亚甲基苯乙烯)二嵌段共聚物,其中的氯亚甲基侧基经叠氮化反应后与丙炔醇进行点击反应,最终获得了含有1,2,3-三氮唑官能团的聚苯乙烯二嵌段共聚物,核磁共振谱表征结果证明,PS-b-PCVB中的氯亚甲基完全转变成了1,2,3-三氮唑基团。

The diblock copolymer of styrene and chloromethyl-4-vinyl-benzene was obtained by means of reverse addition fragmentation chain transfer reaction living free radical polymerization. The chloromethyl groups in PS-b-PCVB were transformed into azidomethyl groups, and then into 1,2,3-triazol groups via click chemistry. The diblobk copolymer containing 1,2,3-triazol groups was thus obtained. The results from NMR spectra suggested a complete transformation from chloromethyl groups to triazol groups.

通过可逆加成-断裂链转移聚合活性自由基聚合方法制备了聚(苯乙烯-b-对氯亚甲基苯乙烯)二嵌段共聚物,其中的氯亚甲基侧基经叠氮化反应后与丙炔醇进行点击反应,最终得到了含有1,2,3-三氮唑官能团的聚苯乙烯二嵌段共聚物,核磁共振谱表征结果证明,PS-b-PCVB中的氯亚甲基完全转变成了1,2,3-三氮唑基团。

Oligomeric poly (sodium styrenesulfnate-co-styrene), denotated P, was synthesized by means of radical polymerization, layered.

采用自由基溶液聚合的方法将苯乙烯与对苯乙烯磺酸钠共聚,合成了低聚物P。

The mechanism of dioxygen oxidation of NTS to DNS in alkali solution under mild condition was inquired into. The result showed that the key step in the preparation of DNS from NTS was the formation of 4-nitro-2-sulfobenzyl anion as a result ionization of NTS in strong alkali and then oxidization to 4-nitro-2sulfobenzyl radical by activated dioxygen.

探讨了在温和条件下于碱的水溶液中氧气液相氧化4-硝基甲苯-2-磺酸制取4,4'-二硝基二苯乙烯-2,2'-二磺酸的反应机理,发现4-硝基甲苯-2-磺酸在碱作用下发生离子化生成4-硝基-2-磺酸基苄基阴离子,然后被活化的分子氧氧化成4-硝基-2-磺酸基苄基自由基是反应的关键步骤。

In the dissertation, a new stabilization method, equal-density method was adopted to prepare modified asphalts with storage stability at high temperature. In this method, a compound was prepared by premixing polymer and filler, and the compound was mixed with asphalt to prepare Polymer-Modified Asphalt by changing the ratio of polymer and filler. The asphalts with good storage stability were formed with the addition of filler, by regulating the density difference between polymer and asphalt. With identifying the effect of composition factor and the technique conditions on mechanical properties of polymer/filler compound and the molecular distribution of the polymer, identifying the effect of composition factor and the technique conditions on the properties and structure of polymer/filler modified asphalt, Styrene-Butadiene-Styrene copolymer, Low Density PolyEthylene, Styrene-Ethylene-Butadiene-Styrene block copolymer modified asphalts with good storage stability and performance were prepared. Rheological method, gel content analysis and swelling measurement were adopted to elucidate the interaction between the polymer and filler. Filler reduced the difference between the polymer and asphalt with the premixing technique, which led to the improvement of the storage stability of the modified asphalts. The thermo-oxidative aging process of base asphalt and PMA were studied and the effect of antioxidant additives on the base asphalt and PMA were analyzed.

本论文采用等密度方法,即预先混合聚合物与填料制备复合物,复合物在沥青中会吸收油份而溶胀,改变填料的用量从而调节聚合物与沥青的密度差异的方法,制备出高温贮存稳定的改性沥青,并研究了工艺条件和配方因素对聚合物/填料复合物力学和聚合物分子量分布的影响,系统考察了工艺条件和配方因素对聚合物/填料改性沥青性能与形态结构的影响,研制出性能优良、高温贮存稳定的苯乙烯-丁二烯-苯乙烯三嵌段共聚物、氢化SBS、低密度聚乙烯改性沥青,并通过流变学分析方法及凝胶和溶胀测试探讨了聚合物与填料的相互作用,指出经过预混工艺填料改变了聚合物与沥青的密度差异,以此说明聚合物/填料改性沥青高温贮存稳定的原因;研究了基质沥青和聚合物改性沥青热氧老化过程,并分析了抗氧剂对基质沥青及聚合物改性沥青的影响,探讨了抗氧剂提高沥青耐老化性能的原因。

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