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苯乙烯

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The mechanism of dioxygen oxidation of NTS to DNS in alkali solution under mild condition was inquired into. The result showed that the key step in the preparation of DNS from NTS was the formation of 4-nitro-2-sulfobenzyl anion as a result ionization of NTS in strong alkali and then oxidization to 4-nitro-2sulfobenzyl radical by activated dioxygen.

探讨了在温和条件下于碱的水溶液中氧气液相氧化4-硝基甲苯-2-磺酸制取4,4'-二硝基二苯乙烯-2,2'-二磺酸的反应机理,发现4-硝基甲苯-2-磺酸在碱作用下发生离子化生成4-硝基-2-磺酸基苄基阴离子,然后被活化的分子氧氧化成4-硝基-2-磺酸基苄基自由基是反应的关键步骤。

Chemically, propolis is exceedingly complex and contains a rich variety of potent terpenes and benzoic, caffeic, cinnamic, and phenolic acids.

从化学成分分析,蜂胶是极度复杂的并且富含了有效的萜烃,安息香酸,咖啡酸,苯乙烯酸和酚酸。

The ee's of30-93% and yields of 64-96% were achieved in NaClO / 4-PPNO and m-CPBA /NMO oxidant systems by using substituted styrenes and substituted2,2-dimethylchromenes as substrates.

在优化反应条件下,在NaClO/4-PPNO、m-CPBA/NMO两个氧化体系中,对取代苯乙烯系列底物获得了30~70%ee和64~96%的收率;对取代苯并吡喃类化合物,获得了84~93%ee和82~96%的收率。

The effects ofreaction temperature, reaction time, BPO and St concentrations,Oxygen on grafting ratio were studied.

研究了反应温度、反应时间、BPO浓度、苯乙烯浓度以及氧气对接枝率的影响。

Two new chiral imidazoles with big conjugate system were synthesized, that is,-1-(-methylbenzyl)-2-benzene-4,5-dibenzene-imidazole and-1-(-methyl benzyI)-2-styrene-4,5-dibenzene-imidazole, whose salifying conditions were also briefly investigated.

设计并合成了两个新的含有手性单元和较大共轭体系的多取代咪唑:-1--2-苯基-4,5-二苯基咪唑和-1--2-苯乙烯基-4,5-二苯基咪唑,并对其成盐反应和条件进行了一些初步研究。

The electric mechanism of α-cypermethrin based microemulsion formed by polyoxyethylene styrenyl phenyl ether and dodecyl benzenesulfonic salt combined with different kinds of antiparticles, and the phase behavior were investigated.

研究了结合不同反离子的十二烷基苯磺酸盐与苯乙烯苯酚聚氧乙烯醚(NR600)形成的高效氯氰菊酯微乳液的导电机理,以及反离子对体系相行为的影响。

In the one hand, for catalytic double carbonylation of phenyl iodide or catalytic hydroesterification of styrene, the effect of pressure on products ratio reflected the difference in the volume of activation of different reaction routes.

对于碘苯双羰基化反应或苯乙烯氢酯基化反应,由于不同产物反应的活化体积不同,压力对于不同反应速率常数的影响亦不相同,因此压力增大会有利于其中某个反应。

Styrene epoxidation was carried out using styrene as the row material, molecular oxygen as the oxidant, and modified vanadium phosphorus oxide as the catalyst.

苯乙烯为原料,分子氧为氧化剂,改性的钒磷氧化物为催化剂合成环氧苯乙烷。

Based on the objective lens and voice coil motor of the current DVD pickup head,according to photobleaching three-dimensional (3D) optical information storage's theory of two-photon absorption,the Ti∶sapphire femtosecond pulse laser was used as written optical beam and reading optical beam of two-photon three-dimensional optical storage voice coil motor was carried through multiplayer choice, and the storage and readout experimental study of binary format code with two-photon photobleaching in the new photobleaching material consisting of stilbene derivant was conducted.

基于现有的DVD光头物镜与音圈电机,根据光致漂白的双光子吸收三维光信息存储原理,以钛蓝宝石飞秒脉冲激光进行双光子光信息写入和读出,利用音圈电机进行选层,在新型光致漂白材料二苯乙烯衍生物中进行光致漂白二进制编码信息的存储和读出实验研究;实现了三层光信息存储,信息点间距和信息层间距分别为4 μm和15 μm;用Matlab软件读出信息的信号强度并对其进行了识别,识别结果与写入的二进制编码信息完全一致。

The inhibition effect of 2,2,6,6-tetramethyl-4-hydroxylpiperidine-oxyl and some phenols and quinones on the AIBN initiated radical polymerization of styrene was studied by using dilatomitry method.

用膨胀计法,研究了2,2,6,6-四甲基-4-羟基哌啶氧自由基及一些醌、酚类化合物对偶氮二异丁腈引发的苯乙烯自由基聚合的阻聚效应。结果表明,当 St在80℃聚合时,加入TMHPO·或TMHPO·-BQ,阻聚效果较为显著。

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