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Firstly, polyacrylamide with 26 million molecular weight was compounded in lab through establishing optimum compounding initiator proportionality of 1:1. 3 and mass concentration of 170 mgL^(-1), temperature of 10 ℃, acrylamide mass percentage of 25%, electrical conductivity of 3.6 μSm^(-1) and pH value of 6.57. The salt-resistance, thermal endurance and shear-resistance of polyacrylamide could be enhanced b introducing sulfonic acid group or styrene sulfonate group or drawing the two groups above at the same time. Secondly, chelator HEDP, bactericide isoquinoline ketone and oxygen scavenger thiourea were optimized to improve the compatibility of polyacrylamide and formation water.

在由室内试验确定了复合引发剂最佳比值1:1.3和质量浓度170 mgL^(-1)、合成最佳温度10℃、丙烯酰胺单体质量分数25%、电导率3.6μSm^(-1)和pH值6.57后,合成出相对分子质量高于2.6×10^7的聚丙烯酰胺,同时通过丙烯酰胺单体复配引入磺酸基团、苯乙烯磺酸基团或同时引入此两种基团,提高了聚合物的抗盐、抗温、抗剪切性能;后针对聚丙烯酰胺与地层水配伍性差的问题,优选出HEDP螯合剂、异噻唑烷酮杀菌剂和除氧剂硫脲,对聚合物稳定效果明显。

The styrene-acrylic emulsion was synthesized using monomer styrene,butyl acrylate,2-hydroxy propylacrylate and monobutyl itaconate.

采用苯乙烯、丙烯酸丁酯及丙烯酸-2-羟基丙酯作主单体,衣康酸单丁酯作功能单体合成了苯丙乳液,比较了功能单体MB I及丙烯酸对苯丙乳液性能(包括耐水性、表面张力、钙离子稳定性等)的影响,用透射电镜观察了乳胶粒子形态。

Three series of donor-acceptorπ-conjugated molecules 1, 2, and 3 have been designed and synthesized with a N, N-dimethylamino, Julolidine group (2,3,6,7-tetrahydro-1H, 5H-pyrido[3, 2, 1-ij]quinolinyl), or N, N-diphenylamino group as the donor moiety, a phenylvinyl or thienylvinyl unit as the bridge, and a bromide or aldehyde group as the acceptor moiety.

本文设计并合成了1、2、3三个系列的D-π-A型化合物(Donor-Acceptorπ-conjugated compounds),在化合物分子中引入久洛尼啶基团(2,3,6,7-tetrahydro-1H,5H-pyrido-[3,2,1-ij]quinolinyl),N,N-二甲基氨基,或N,N-二苯基氨基为供电子基团,以苯乙烯基或噻吩乙烯基为桥链,以溴原子或醛基为吸电子基团。

A series of acrylamide-styrene copolymer latices with different acrylamide and styrene weight ratio were prepared from the polymerization in emulsifier-free aquesous media .

为了在水介质中获得高固含量的聚丙烯酰胺,通过无皂乳液聚合制备了一系列不同单体比例的丙烯酰胺-苯乙烯的共聚物胶乳,固含量达50%,稳定性好,胶乳粒子大小均一,具有一定的触变性。

Two kinds of cross-linked polyacrylate latices with relatively narrow distribution of particle diameters, which are abbreviated to P and P/P, were synthesized by seeded emulsion co-polymerization, respectively. Butyl acrylate and 2-ethylhexy! acrylate were used as comonomers of ACR core, styrene and methyl methacrylate were employed as comonomers of ACR shell, and 1,4-butanediol diacrylate was used as cross-linking agent.

采用丙烯酸丁酯和丙烯酸2-乙基己酯(2-EHA)为核层单体、苯乙烯和甲基丙烯酸甲酯为壳层单体、1,4-丁二醇二丙烯酸酯为交联剂,通过多步种子乳液聚合方法合成了P、P/P两种具有窄粒径分布的共聚丙烯酸酯胶乳。

Thermoset acrylic coating are based on resins prepared from acrylic and methacrylic esters, acrylic and methacrylic acids, and /or styrene.

热固型丙烯酸涂料是由丙烯酸和甲乙基丙烯酸酯,丙烯酸和甲基丙烯酸,或苯乙烯反应而成。

Synthesized ethylene - laborious Xi copolymer and methylic acrylic acid armour ester - propylene nitrile - the graft copolymer of styrene .

梗概: 合成了乙烯-辛烯共聚物和甲基丙烯酸甲酯-丙烯腈-苯乙烯的接枝共聚物。

They were Pinosylvin, pinosylvin monomethyl ether and pinosylvin dimethyl ether. PSD was only found in part of the samples where was low in concentration.

在抗腐朽的木材心材样品中,总二苯乙烯类物质的平均含量为7.43mg/g(试验林1)和5.10mg/g(试验林2);在易腐朽的心材样品中的含量为6.30mg/g(试验林1)和4.77mg/g(试验林2)。

Then, the multidentate amine immobilized on silica gel was used as ligand for CuCl in ATRA of CCl_4 with MMA and methyl trichloroacetate with St repeatly. The conversion and purity of the product were determined through the gas chromatography and ~1H NMR respectively. Finally, the multidentate amine immobilized on silica gel was used as ligand for CuCl in ATRP of St initiated by TCPP and MMA initiated by MMTCB. The number average molecular weights of the polymers were determined through GPC.

此多齿胺改性硅胶配体被分别多次重复用于四氯化碳与甲基丙烯酸甲酯,三氯乙酸甲酯与苯乙烯的ATRA反应中,通过气相色谱测定了原料的转化率随时间的变化,且通过核磁~1H NMR测定了产物的纯度,我们还进一步将此种多齿胺改性硅胶配体用于TCPP引发St的ATRP和MMTCB引发MMA的ATRP反应中,通过GPC测定所得聚合物的分子量。

The present invention provides a multinuclear half metallocene compound in which two or more of transition metals of groups 3 to 10 on periodic table are connected through bridge ligand simultaneously containing Pi-ligand cycloalkandienyl group and Alpha-ligand functional group and its preparation, and a process for preparing styrene polymer using the compound as a catalyst.

本发明提供了一种其中的两个或更多元素周期表第3-10族过渡金属通过同时包含π-配体环烷基二烯基团和α-配体功能基团的桥配体连接的多核半金属茂络合化合物及其制备方法,及使用本化合物为催化剂的苯乙烯聚合体的制备工艺。

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