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Based on reviewing of functionalization of saturated carbon by catalytic oxidation with metalloporphyrins and metal phthalocyanines as a mimic of the enzyme cytochrome P-450, two reaction systems of which one was the preparation of 4, 4'-dinitrostilbene-2, 2'-disulfonic acid from 4-nitrotoluene2-sulfonic acid and the other was the preparation of 4, 4'-bis (dimethylamino -diphenyl) phenylmethanol from 4, 4'-bis (dimethylamino-diphenyl) phenyl methane , were specifically studied as carfunctionalization and oxyfunctionalization of saturated carbon.

本文在全面综述金属卟啉和金属酞菁类模拟细胞色素P-450酶催化剂催化氧化饱和碳原子功能化的基础上,选择由4-硝基甲苯-2-磺酸制取4,4'-二硝基二苯乙烯-2,2'-二磺酸和由4,4'-二苯基甲烷制取4,4'-二苯基甲醇两个反应体系进行饱和碳原子碳功能化和氧功能化的具体研究。

The spectrum evolution of the femtosecond laser pulse in a three-level organic molecular medium 4, 4'-bis(dimethylamino stilbene is studied theoretically by solving the Maxwell-Bloch equations using an iterative predictor-corrector finite-difference time-domain method.

通过采用预估校正的时域有限差分法求解麦克斯韦-布洛赫方程,我们研究了飞秒激光脉冲在三能级有机分子(4, 4'-二甲氨基二苯乙烯分子)介质中传播时脉冲的频谱演化情况。

The spectrum evolution of the femtosecond laser pulse in a three-level organic molecular medium4,4'-bis(dimethylamino stilbene is studied theoretically by solving the Maxwell-Bloch equations using an iterative predictorcorrector finite-difference time-domain method.

通过采用预估校正的时域有限差分法求解麦克斯韦-布洛赫方程,我们研究了飞秒激光脉冲在三能级有机分子(4,4-二甲氨基二苯乙烯分子)介质中传播时脉冲的频谱演化情况。

Three new chromophores and 4 nitro benzoic acid 2 {4 [2 (4 dimethylamino phenyl vinyl] phenyl} ethylamino ethyl ester have been synthesized and the structures have been characterized by 1H NMR, IR and elemental analyses.

作者中文名:延云兴;陶绪堂;杨家祥;王东;于晓强;赵显;蒋民华摘要:合成了反式-4-[N-(乙氧基羰基-4-硝基苯基)-N'-乙基氨基]-4'-二苯乙烯和三个新有机化合物。

Radiation-induced grafting of binary vinyl monomers of styrene/ maleic anhydride, St/ dimethylamino ethyl methacrylate and St/ vinyl acetate onto cotton cellulose was carried out byγ- radiation from a60 Co source at room temperature under nitrogen.

在氮气气氛下用γ线辐照的方法在棉纤维上接枝苯乙烯/来酸酐、乙烯/基丙烯酸二甲胺乙酯、乙烯/酸乙烯酯二元单体。

Finally, 4, 4'-diaminostilbene-2, 2'-disulfonic acid with high quality was synthesized from DNS after purification.

研究结果表明,适宜的重结晶温度约为85℃,优化pH值为9~10,以重结晶后所得精制DNS为原料可制备高品质4,4'-二氨基二苯乙烯-2,2'-二磺酸。

The oxidation of p-nitrotoluene-2-sulfonic acid to prepare 4, 4'-dinitrostilbene-2, 2'-disulfonic acid was monitored, and the mechanism for the formation of by-products 4-nitrobenzaldehyde-2-sulfonic acid and 4-nitro-2-sulfobenzonic acid was suggested.

跟踪了对硝基甲苯邻磺酸制备4,4'-二硝基二苯乙烯-2,2'-二磺酸的过程,推测了4-硝基苯甲醛2-磺酸钠与4-硝基苯甲酸2-磺酸钠杂质的生成机理。

The mechanism of dioxygen oxidation of 4-nitrotoluene-2-sulfonic acid to 4,4'-dinitrostilbene-2,2'-disulfonic acid in alkali solution under mild condition was investigated.

探讨了在温和条件下在碱的水溶液中氧气液相氧化 4-硝基甲苯- 2 -磺酸制取 4,4'-二硝基二苯乙烯- 2 ,2 '-二磺酸的反应机理,发现 4-硝基甲苯- 2 -磺酸在碱作用下发生离子化生成 4-硝基- 2 -磺酸基苄基阴离子,然后被活化的分子氧氧化成 4-硝基- 2 -磺酸基苄基自由基是反应的关键步骤。

Based on the study of the adsorption mechnism between the macroporous weak base anion-exchange resins and the aromatic sulfonic acid, a pretreatment method for the wastewater from 4, 4'-diaminostilibene-2, 2'-disulfonic acid manufacturing process, a refractory dye intermediate wastewater, was developed.

在对芳香磺酸化合物吸附机理研究的基础上,开发了大孔弱碱性阴离子交换树脂吸附法处理4,4'-二氨基二苯乙烯-2,2'-二磺酸氧化工序生产废水的新技术,并得到了工业化应用。

A kind of modified casting polyurethane by styrene and divinyl benzene with good adhesion with ethylene-propylene-diene monomerhas been prepared by one-step process, which can be cured at the room temperature.

采用苯乙烯、二乙烯基苯对聚氨酯进行了改性研究,利用一步法工艺,制备了与三元乙丙橡胶具有优良粘接性能的双组分室温固化的改性浇注胶。

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The split between the two groups can hardly be papered over.

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