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苯乙烯

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Carbon bisulfide was the main poison in the hydrogenation reaction of conjugated double bond of styrene and the negative effect increased with the increase of carbon bisulfide content; the negative effect decreased with the increase of reaction temperature.

二硫化碳是苯乙烯中共轭烯烃加氢快速失活的主要硫化物。随着二硫化碳含量的增加,苯乙烯中共轭烯烃加氢活性下降程度增大;随温度升高,其加氢活性下降程度减小。

Surface modification of up-conversion luminescence by overcoating with carboxyl groups and its characterization;2. The effects of concentration and adding methods of acrylic acid on the content of carboxyl groups on the magnetic microspheres surface were studied.

利用双层表面活性剂改性的Fe3O4磁流体为种子,通过乳液聚合法考察了苯乙烯苯乙烯-丙烯酸对Fe3O4磁流体的包覆情况,并考察了丙烯酸浓度及加入时间对磁性微球表面羧基含量的影响。

Comparing the three processes, it has been found that the semicontinuous solution polymerization runs stably and the polymerization temperature can be well controlled.

为了获得稀土催化苯乙烯聚合合成UHMWPS的合适的聚合方式,分别进行了稀土催化苯乙烯间歇本体、溶液聚合及半连续溶液聚合的研究。

Oligostilbenes are a type of compounds with complex structures and multi-faced bioactivities, polymerized from stilbene monomers.

苯乙烯类低聚体是由二苯乙烯单体以不同方式聚合而成的一类结构复杂,具有多种生物活性的化合物。

Radiation-induced grafting of binary vinyl monomers of styrene/maleic anhydride, St/dimethylamino ethyl methacrylate and St/vinyl acetate onto cotton cellulose was carried out by γ-radiation from a 60Co source at room temperature under nitrogen.

在氮气气氛下用γ射线辐照的方法在棉纤维上接枝苯乙烯/马来酸酐、苯乙烯/甲基丙烯酸二甲胺乙酯、苯乙烯/醋酸乙烯酯二元单体。

Radiation-induced grafting of binary vinyl monomers of styrene/maleic anhydride, St/dimethylamino ethyl methacrylate and St/vinyl acetate onto cotton cellulose was carried out by γ-radiation from a 60Co source at room temperature under nitrogen.

闫宇,伊敏,彭金粉,翟茂林*,哈鸿飞摘要:在氮气气氛下用γ射线辐照的方法在棉纤维上接枝苯乙烯/马来酸酐、苯乙烯/甲基丙烯酸二甲胺乙酯、苯乙烯/醋酸乙烯酯二元单体。

A series of sulphonated SBS were achieved by reacting SBS blockcopolymer with sulphuric acid, meanwhile, the blends of PVC andsulphonated SBS were studied. By means of strength capabilityexamination and DSC analysis, it was found the miscibility wasincreased after SBS was sulphonated.2 The chemical grafting of styrene and PVC membrane2.1 The reaction condition of graftingBy means of the swelling and seepage of Styrene to PVC film,St was grafted onto PVC film by the initiation of BPO .

采用硫酸对热塑性弹性体SBS进行磺化,得到不同磺化度的产物,并对其与PVC的物理共混进行了研究;通过力学性能及DSC测试,发现SBS磺化后增加了与PVC的相容性(来源:Af2a2a2BC论文网www.abclunwen.com)。2 苯乙烯与聚氯乙烯膜的化学接枝2.1 苯乙烯与聚氯乙烯膜接枝条件利用苯乙烯对PVC的溶胀渗透,在过氧化苯甲酚的引发下发生接枝共聚反应。

When ATRP of styrene was investigated with 1-phenylethyl bromide/benzyl a,a-dibromide mixture as initiator, the GPC chromatogram shows two elution peaks and the molecular weighs of the peaks are approximately in a 2/1 ratio. It suggests that benzyl dibromide is a difunctional initiator of ATRP of styrene. The analysis of end group using 1H-NMR also proves the result above.

采用1-苯基溴乙烷/α,α-二溴化苄混合引发剂进行苯乙烯的ATRP反应时,所得聚苯乙烯的GPC谱图为双峰,分子量相差一倍,初步证明了α,α-二溴化(来源:ABf399C论文网www.abclunwen.com)苄引发苯乙烯ATRP反应时是双官能引发剂,并用~1H-NMR对聚合物结构进行分析,进一步证明了α,α-二溴化苄引发苯乙烯ATRP时是双端同时增长的。

Based on the pure styrenes polymerization, the inhibited polymerization by inhibitor was studied. The effect of polymerization temperature, the addition of ethylbenzene, the content of inhibitor, and the compound of inhibitors was measured for the bulk thermal polymerization of styrene.

在纯苯乙烯聚合基础上,着重考察了阻聚剂(缓聚剂DNBP和阻聚剂M)阻聚下苯乙烯的聚合行为,并系统研究了聚合温度、乙苯含量、缓聚剂及阻聚剂含量、阻聚剂的复配对苯乙烯本体热聚合动力学的影响规律。

Underoptimal conditions, in toluene / dimethyl phthalate / TBP, after EAHQ was oxidizedwith 〓, then the catalyst and styrene were added, the conversion of styrene basedon EAHQ is 68%, the selectivity for styrene oxide based on styrene is 92% and theTON of the catalyst is 500; in toluene / phenyl ether / TBP, epoxidation of styrenewas performed with 〓 generated in situ, the conversion is 46%, the selectivity is94% and the product can be separated by distillation under reduced pressure.

优化条件下,甲苯/邻苯二甲酸二甲酯/TBP(2/2/1,体积比)中,EAHQ先用〓氧化完全后,再加入催化剂A和苯乙烯进行环氧化反应苯乙烯相对于EAHQ的转化率为68%,生成环氧苯乙烷的选择性为92%,催化剂A的TON达到500;甲苯/二苯醚/TBP(1/3/1,体积比)中,原位生成〓条件下苯乙烯相对于EAHQ的转化率为46%,生成环氧苯乙烷的选择性为94%,产物可通过减压蒸馏分离。

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