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苯乙二醇

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Dihydroxy-7, 4′-dimethoxy-dihydrflavonol and -3, 5, 7 -trihydroxy-4′-methoxy- dihydrflavonol were synthesized by selective protection, condensation, epoxidation, cyclization and deprotection from 2, 4, 6-trihydroxyacetophone and anisaldehyde.

以2,4,6-三羟基苯乙酮和茴香醛为起始原料,经选择性保护、缩合、环氧化、关环等步骤首次完成了-3,5-二羟基-7,4′-二甲氧基二氢黄酮醇和-3,5,7-三羟基-4′-甲氧基二氢黄酮醇全合成。

Their structures were characterized as dihydroconiferyl dihydro-p-coumarate, vanillin, apocynin, p-hydroxybenzaldehyde, syringaldehyde, syringic acid, syringylethanone,α-hydroxypropiosyringone, coniferyl aldehyde, dihydroconiferyl alcohol, 2-hydroxyphenylpropanol, and 3-hydroxy-4-methoxy-phenylethanol, respectively.

结果 从该植物中分离得到12个酚性化合物,其结构分别为二氢松柏醇二氢对羟基桂皮酸酯,香草醛,罗布麻宁,对羟基苯甲醛,丁香醛,丁香酸,丁香乙酮,α-羟基丁香丙酮,松柏醛,二氢松柏醇,2-羟基苯丙醇和3-羟基-4-甲氧基苯乙醇。

Ingredients:Water,Hamamelis Virgin-iana Water,Glycerin,Olive Oil Peg-7 Esters,Gm Euglena Gracilis Polysaccharide,Betaine,Aloe Barb-adensis Leaf Juice,Hydrolyzed Wheat Protein,Sodium Pca,Tocopheryl Acetate,Polysorbate 20,Creatine,Hyaluronic Acid,Tetrasodium Edta,Perfume

成分:去离子水,金缕梅蒸馏液,甘油,橄榄油,PEG-7酯类,细小裸藻多糖,甜菜碱,芦荟叶提取物,水解小麦蛋白,吡咯烷酮羧酸钠,生育酚乙酸酯,聚山梨醇酯-20,肌酸,透明质酸,乙二胺四乙酸四钠,香精,苯氧乙醇,辛二醇,山梨酸。

The constituents were extracted by some solvents. 18 constituents were isolated from Chloroform fraction by different chromatography. 15 constituents were identified by IR ,MS and NMR as follows: 3-sitosterol, P-sitosterylpalm itate,succinate acids, 1, 4-benzenediol, 1, 2-benzenediol, p-hydroxybenzaldehyde, syringaresinol, oleanolic acid, usolic acid, ethyl caffeate , Rosmarinic acid ethylster and etc. In such constituents ,nine compounds were isolated for first time from Origanum vulgare L..

牛至药材经水煮醇沉法所得浸膏,利用溶剂法和色谱法从中分离得到18个单体成分,通过IR、MS、NMR等波谱技术鉴定了其中的15个化合物,分别为β-谷甾醇(1)、β-胡萝卜苷(2)、琥珀酸(3)、对-二苯酚(4)、邻-二苯酚(5)、对羟基苯甲醛(6)、1.2-二羟基-4-异丙基-5-甲基苯(7)、新木脂素(8)、丁香脂素(9)、齐墩果酸(10)、乌苏酸(11)、4-二十六烯(12)、正二十六醇(13)、咖啡酸乙酯(14)、迷迭香酸乙酯(15)等,其中化合物3、4、5、6、7、8、9、14、15等9种化合物均为首次从该属植物中分离得到。

This invention carrying through alcoholysis of common gloss polyester chip, getting low-molecular polymer of polytetramethylene terephthalate, using this low-molecular polymer as pregnant liquor, doing esterification reaction and polycondensation reaction of PTA and hybrid diatomic alcohol in normal pressure, getting the modified copolyester product which has inherent viscosity of 0. 65-0. 85dl/g, fine pellucidity and is suitable in the application of engineering plastics.

本发明是通过对普通大有光聚酯切片进行醇解,得到对苯二甲酸乙二酯低聚物,以此低聚物为母液,在常压下使PTA与混合二元醇进行酯化反应和缩聚反应,制备得到了特性粘数在0.65-0.85dl/g且具有良好透明性的适用于工程塑料领域应用的改性共聚酯产品。

Ingredients: Water,Glycerin,Caprylic/Capric Triglyceride,Myristyl Myristate,Butyrospermum Parkii Butter,Glyceryl Stearate,Panthenol,Betaine,Dimethicone,Hydrolyzed Collagen,Allantoin,Polysorbate-60,Carbomer,Xa-nthan Gum,Parfum,Triethanolamine,Tocopheryl Acetate,Hyaluronic Acid,Methyl Paraben,Propyl Paraben,Creatine,Tetrasodium Edta,Phenoxyethanol,Caprylyl Glycol,Sorbic.

成分: 去离子水,甘油,辛酸/葵酸三甘油酯,肉豆蔻酸肉豆蔻酯,乳木果油,硬脂酸甘油酯,泛醇,甜菜碱,聚二甲基硅氧烷,水解胶原蛋白,尿囊素,聚山梨醇酯-60,卡波姆,汉生胶,香精,三乙醇胺,生育酚乙酸酯,透明质酸,对羟基苯甲酸甲酯,对羟基苯甲酸丙酯,肌酸,乙二胺四乙酸四钠,苯氧乙醇,辛二醇,山梨酸。

A novel planar chiral diferrocenylimine-diols 6 was synthesized by the condensation of R, S(subscript p-1-(2-diphenyl hydroxyl methyl) ferrocenylethylamine [R, S(subscript p-4] with phthaldehyde in anhydrous ethanol, and was crystallographically characterized.

通过R,S(下标 p-1-(2-二苯基羟甲基)二茂铁乙胺[R,S(下标 p-4]和对苯二甲醛在无水乙醇中的缩合反应合成了一种新型平面手性双二茂铁亚胺二醇化合物6,并经X-射线衍射分析它的晶体结构。

Cuspidate with 33% identity and 50% similarity to taxadien-5α-ol-O-acetyltransferase, 34% identity and 52% similarity to 10-deacetylbaceatin Ⅲ-10-O-acetyltransferase, and 33% identity and 49% similarity to taxane 2α-O-benzoyltransferase, respectively, moreover, it contained the conserved HXXXDG motif that is found in other transacylases, this sequence element has been suggested to function in acyl group transfer from acyl CoA to the substrate alcohol.

No.AF448807)在氨基酸水平与大部分植物来源的酰基转移酶具有较大的同源性,其中与东北红豆杉紫杉二烯-5α-醇-乙酰转移酶的一致性达33%、相似性达50%,与东北红豆杉紫杉10-去乙酰巴卡亭Ⅲ-10-0-乙酰转移酶的一致性达34%、相似性达52%,与东北红豆杉紫杉二烯2α-0-苯甲酰转移酶的一致性达33%、相似性达49%,并且在TS4的氨基酸序列中还发现酰基转移酶家族成员特有保守序列HXXXDG,这个序列单元被认为在将酰基CoA转移至醇类底物的过程中发挥作用。

Ethanethiol,thiophene and dibenzothiophene as the model sulfur compounds were analysed by FPD in the gasoline.

选择乙硫醇、噻吩和二苯并噻吩作为汽油中的目标检测硫化物,采用火焰光度检测器进行分析。

Results Eleven compounds were obtained and identified as sarcodonin A, scabronine B, 3β-hydroxy-5α, 8a-epidioxyergosta-6, 22-dien,(22E, 24R)-ergosta-7, 22-diene-3β, 5α, 6β-triol,(22E, 24R)-ergosta-7, 22-diene-3β-ol, benzoic acid, 4-hydroxylben-zaldehyde, 4-monopropanoylbenzenediol, ethy1-β-D-glucopyranoside, thioacetic anhydride,(2S, 2'R, 3S, 4R)-2-(2-hydroxyoctadecanoylamino) docosane-1, 3, 4-triol.

结果共分离鉴定了11个化合物,分别是:sarcodonin A、scabronine B、3β羟-5α,5α-过氧麦角甾-6,22-二烯-3β-醇、(22E,24R)-麦角甾-7,22-二烯-3β,5α,6β三醇、(22E,24R)-麦角甾-7,22-二烯-3β-醇、苯甲酸、对羟基苯甲醛、对羟基苯甲酸乙酯、乙基-β-D-吡喃葡萄糖苷、硫代乙酸酐、(25,2'R,3S,4R)-2-(2-羟基-十八碳酰胺)二十二碳烷-l,3,4-三醇。

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