苯丙烯酸

Its catalytic performance in Heck reaction of iodobenzene with ethyl acrylate was studied

研究了该催化剂对碘代苯与丙烯酸乙酯反应的催化性能及循环使用性能。

The Effect of different reaction conditions (solvent, reaction temperature, molar ratio of iodobenzene and acrylic acid, kind and amount of base, amount of catalyst, reaction time) on the yield was investigated. The suitable condition of the reaction was obtained.

考察了不同反应因素（溶剂、温度、原料比、缚酸剂及其用量、催化剂用量、反应时间）对反应的影响，确定了该催化剂对碘代苯与丙烯酸交叉偶联生成反式－肉桂酸的适宜反应条件。

The complex was characterized by FT-IR, XRD, BET, SEM and EDS. The resin-supported catalyst exhibited high catalytic activity in the Heck reaction and could be reused up to 17 times in NMP or 16 times in DMF at 90 ℃ in the Heck reaction of iodobenzene with acrylic acid.

该负载型催化剂对Heck反应表现出高的催化活性和很好的重复使用性能，于90℃的碘苯与丙烯酸的Heck反应中，在NMP溶剂中能重复使用17次，在DMF溶剂中能重复使用16次。

The novel catalysts of Cu supported on ZnO, MgO modified with KF were prepared by the conventional impregnation method, and applied for the first time to the Heck reactions of iodobenzene with n-butyl acrylate as a model reaction.

KF水溶液浸渍MgO或ZnO载体为改性载体制备了负载铜催化剂，以卤苯与丙烯酸正丁酯的反应为模型，考察了对Heck反应的催化性能。

The developed catalysts demonstrated good activities towards the Heck reaction of iodobenzene and methyl acrylate with about 90% yield, easy separation after reaction and reusability. The metal leaching was not apparent after four runs.

以碘代苯与丙烯酸甲酯的Heck反应为例，考察双腈基固载Pd的催化性能，肉桂酸甲酯的收率近90％，四次循环使用后催化活性没有明显的降低，Pd的析出并不严重，该催化剂易回收使用。

The results indicate that little conversion of iodobenzene was observed on unmodified carrier supported catalysts; and a conversion of 100% and a selectivity of above 98% to trans-isomers were found over 10%Cu/5%KF/ZnO, 20%Cu/10%KF/ZnO.

结果表明，对碘苯与丙烯酸正丁酯的Heck反应的催化性能，未改性催化剂基本没有活性，而改性后，10%Cu/5%KF/ZnO、20%Cu/10%KF/ZnO催化剂的催化转化率为100%和反式异构体的选择性为98%以上。

In order to enhance the compatibility of ABS/PP/CaCO3 composites, the effects of reactive blends of the composites were studied by using Haake rheometer. The effects of various assistant cross-linkingers, such as castor oil, triallyl isocyanurate, turpentine (JS-1) and glycol dimethacrylate, and the used amount of cross-linkinger-dicumyl peroxide on the torques of the melting composites were investigated.

为提高ABS/PP/CaCO3复合材料相容性，采用转矩流变仪观察了ABS/PP/CaCO3三元复合物反应性共混后的扭矩，考察了不同的助交联剂蓖麻油、异氰脲酸三烯丙酯、松香酯(JS-1)、二甲基丙烯酸乙二醇酯以及交联剂过氧化二异丙苯的用量对共混物的影响。

The first synthetic route uses 1,2,4-trimethoxybenzene and chloroacetonitrile in forming 2,4,5-trimethoxy-a-chlor-acetophenone under the anhydrous condition, then the intermediate condensates with papaverine forming the core pyrro[2,l-a]isoquinoline, followed by formation and lactonization to form the lactone ring. The second synthetic route uses prepared aldehyde with prepared ethyl nitroacetate by Knoevenagel condensation to obtain 2-Nitro-3-(2,4,5-tris-methoxy-phenyl)-acrylic acid ethyl ester and 2-Nitro-3-(2,4,5-tris-benzyloxy -phenyl)-acrylic acid ethyl ester etal intermediates. The lamellarin skeleton could arise from condensation of the papaverine and these intermediates by Michael reaction, the ester group is provided for subsequent lactonization. The third synthetic route uses coumarin or indan-l,3-dione derivatives and papaverine to form lamellarin under basic conditions.

第一条路线首先从1，2，4-三甲氧基苯出发与卤乙腈作用合成卤代芳酮中间体，然后与罂粟碱反应合成开链片螺素，最后经乙酰化、去保护、成内酯环得到片螺素；第二条路线由制备的芳醛和制备的硝基乙酸乙酯经缩合得到2-硝基-3-芳基丙烯酸乙酯，然后由该中间体与罂粟碱反应，在完成关环的同时也引入酯基，最后去保护、成内酯环得到片螺素；第三条路线是由香豆素或茚二酮出发，经溴代后的中间体与罂粟碱反应，得到片螺素的基本框架。

Silver nanoparticles with average particle size ranging from 2 to 131nm were manipulatively synthesized starting from silver nitrate using 10 kinds of different functional group-containing organic modifiers, such as polyvinylpyrrolidone, tween-80, sodium dodecyl sulfate, sodium polyacrylate, polyethylene glycol, D-sorbitol, sodium dodecyl sulfonate, sodium dodecylbenzene sulfonate, polyvinyl alcohol, cetyltrimethylammonium bromide, at room temperature.

摘 要：选择10种含有不同官能团的有机物为表面修饰剂，如聚乙烯吡咯烷酮、吐温-80、十二烷基硫酸钠、聚丙烯酸钠、聚乙二醇、山梨醇、十二烷基磺酸钠、聚乙烯醇、十二烷基苯磺酸钠和十六烷基三甲基溴化铵等，在室温下进行了平均粒径在2～131nm范围内纳米银颗粒的控制合成研究。

Synthesized polymerizable photosensitive monomer diazo naphthoquinone sulfonate hydroxyethyl methacrylate ether was characterized by infrared spectroscopy and 1H NMR.

田丰，于媛媛，汪长春*摘要：利用红外光谱和核磁共振(1H NMR)对所制备的光敏可聚合单体重氮萘醌苯磺酸甲基丙烯酸羟乙酯进行了表征。

The split between the two groups can hardly be papered over.

这两个团体间的分歧难以掩饰。

This approach not only encourages a greater number of responses, but minimizes the likelihood of stale groupthink.

这种做法不仅鼓励了更多的反应，而且减少跟风的可能性。