苄胺

Macroporous tributyl amine aminating strongly basic anion exchange resin-a phase transfer catalyst with high catalytic activity for nucleophilic substitution,which was screened out via combinatorial chemistry method –was used to catalyze the nucleophilic substitution reactions for synthesis of benzyl acetate,benzyl propionate,benzyl butyrate and benzyl valerate.

用组合化学方法筛选出的对无外加碱条件下的亲核取代催化活性最高的聚合物季铵盐–三丁胺胺化强碱性阴离子交换树脂为相转移催化剂，催化合成了乙酸苄酯、丙酸苄酯、丁酸苄酯、戊酸苄酯等羧酸苄酯。

Objective: To study the effects of the benzylamine compounds on antifungal activities after introducing large substitutes to the α-C of side chain of naphthalene ring.

目的：研究在萘环侧链α位引入大基团对苄胺类化合物抗真菌活性的影响。

In summary, 15 new N--2-(4, 6-dimethoxypyrimidin-2-yl-oxy)benzylamine derivatives with high herbicidal activity are obtained.

4氧桥双取代嘧啶苄胺类化合物也是一类具有高除草活性的化合物，在75 g ai／hm~2低剂量下，化合物主要表现出芽后除草活性。

The introduction of large substitutes to the α-C of side chain of the naphthalene ring reduces the antifungal activitie s of benzylamine compounds.

在萘环侧链α位引入大基团降低了苄胺类化合物的抗真菌活性。

The good herbicidal activity can not be observed at low dosage of 75 g ai/hm~2 for N-(mono-ester substituted phenyl)-2-(4, 6-dimethoxy-pyrimidin-2-yloxy)benzylamine derivatives in post-emergent and pre-emergent application.

主要研究结果如下：(1)氧桥单取代卤素嘧啶苄胺类化合物是一类具有高除草活性的化合物，在75 g ai／hm~2低剂量下，一些化合物表现出良好的芽后和芽前除草活性。

The high post-emergent and pre-emergent herbicidal activity at low dosage of 75 g ai/hm~2 can be found for some N-(mono-substituted phenyl)-2-(4, 6-dimethoxypyrimidin-2-yloxy)benzylamine derivatives.

2氧桥单取代羧酸酯嘧啶苄胺类化合物在75 g ai／hm~2低剂量下，芽后和芽前除草活性不高。

In the forth chapter, the mechanism of pyrimidine benzylamine compounds is studied by the conventional bioassay and biochemical methods based on probe compound 104-4. The results presented here indicated that the addition of 5 mg/L of 3 branched-amino acids to sorghum seedling cultures incubated in the presence of 104-4 completely alleviated herbicide-induced stem growth inhibition, but each of Val, Ile and Leu single is only partly effective in reversing 104-4-induced growth inhibition at the same concentrations.

通过先导结构优化策略的实施，筛选出15个高除草活性的4，6-二甲氧基-2-取代嘧啶苄胺类候选化合物，在此基础上，对一些候选化合物进行作物安全性评价试验，实验结果提示化合物103-1和化合物105-3在低剂量下对某些作物有良好的选择性，可作为优选化合物进入田间小区试验。

The epoxidised cashew nut shell oil acrylate oligomer for UV curing materials was synthe- sized using epoxidised cashew nut shell oil and acrylic acid as main raw materials,N,N-dimethyl- benzylamine as catalyst and p-hydroxyanisole as inhibitor.

以N，N-二甲基苄胺作催化剂、对羟基苯甲醚作阻聚剂，环氧化腰果壳油和丙烯酸为主要原料合成了一种新型的紫外光固化预聚物——环氧化腰果壳油丙烯酸酯。

This work, concentrated on the asymmetric allylation of aldehydes controlled by different chiral auxiliaries prepared from rotational pure tartaric acid, can be divided into three parts.The first part aims to review the developments of chiral drugs and asymmetric synthesis, from which derived the present research topic backgrounds and works.Synthesis and applications of allylation from aldehydes are the second part of the thesis. By optimizing the reaction conditions, such as solvents, temperature, time and chiral auxiliaries like N,N\'-dibenzyl tartamide, N,N\'-p-dimethylphenyl tartamide, N,N\'-o-dimethylphenyl tartamide, N,N\'-o-dichlorophenyl tartamide, N,N\'-a-dinaphyl tartamide, N,N\'-dicyclohexyl tartamide and N,N\'-diphenyl tartamide, ideal experimenttal conditions are obtained according to HPLC monitoring, as well as the auxiliaries\' recoveries experiments. Starting from benzaldehyde and 3-bromopropaldehyde, N,N\'-dibenzyl tartamide is considered the best auxiliary in this reaction.

本文介绍了醛的不对称烯丙基化反应，以光学纯酒石酸为原料，研究了不同构型手性配体在醛的烯丙基化反应中的立体选择性，全文共分三部分十个章节：第一部分对当前手性药物和手性技术进行了概述，并由此展开了本文的研究背景和任务；第二部分为有机合成部分，对醛的不对称烯丙基化反应进行了深入探讨，以苯甲醛为原料对反应条件进行优化，在优化的反应条件下对制备的七种可回收手性酰胺配体(N-苄基酒石酸二酰胺、N-对甲苯基酒石酸二酰胺、N-邻甲苯基酒石酸二酰胺、N-邻氯苯基酒石酸二酰胺、N-a-萘基酒石酸二酰胺、N-环己基酒石酸二酰胺和N-苯基酒石酸二酰胺)进行筛选，优化配体回收实验条件，最终确定出N-苄基酒石酸二酰胺在苯甲醛的不对称烯丙基化反应中具有较大优越性，结晶回收的手性配体光学纯度保持不变。

Second,α,β-unsaturated nitriles were synthesized by three kinds of methods., all the reactions of N-methylhydroxylamine, O-methylhydroxylamine, N-benzylhydroxylamine and O-benzylhydroxylamine withα,β-unsaturated nitriles were carried out, under different temperatures and different solvents. But no desired products were found, though some catalysis were also added.

在不同温度、不同溶剂的条件下，用所合成的α，β-不饱和腈与N-甲基羟胺、N-苄基羟胺、O-甲基羟胺和O-苄基羟胺分别进行反应，没有得到期望的产物，尝试加入了一些催化剂，也没有得到产物。

Now, however, all children continue in "comprehensive" schools, and the eleven-plus determines which courses of study the child will follow.

然而现在，所有的孩子都要在综合学校继续学习，所以这次考试只是决定他们将要学习哪些课程。

Cultivatable land , and led to a general recognition that development must not be carried at the cost of agriculture .

城区的迅速扩大在很多情况下侵占了宝贵的可耕地，使人们普遍认识到发展不能以牺牲农业为代价。