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PBIOM or benzylimidazoleand CoP in chloroform solution were mixed to complex the imidazolyl residue of the ligands with the fifth coordination site of CoP under nitrogen atmosphere to get CoP complexes.

PBIOM或苄基咪唑中的咪唑基与CoP在溶液中配位,得到的CoP-PBIOM或CoP-BIm络合物具有快速、可逆的氧结合特性。

As our studies showed, silylation of mesoporous molecular sieves with alkoxysilane was an usual method of linking desired organical groups. However, as a result, the a lot of silanol groups still existed on the surface of mosoporous molecular sieves after silylation, which maybe affect the interface property and its catalystic activity. Based on this consideration, a novel method was proposed that a mixture of trichlorosilanes was used to silylate mesoporous molecular sieves, introducing both the further reactive group and hyhrophobic methyl group in one pot.

正如研究表明,通过硅氧烷与介孔分子筛表面的硅羟基反应是常见的键连有机基团的方法,但表面仍会剩余较多的硅羟基,硅羟基的存在会严重影响到介孔分子筛表面性质及催化活性,为此笔者提出采用混合的三氯化硅烷一步硅烷化介孔分子筛,在孔道内同时引入可进一步功能化的氯丙基或氯苄基和疏水性的甲基。

Goodcatalytic activities of the phosphine palladium complexes were observed incarbonylation of benzyl chloride with atmospheric CO. In some reactions the yieldof phenylacetic acid was 91% and the catalyst could be reused repeatedly in severaltimes.

这些钯配合物催化苄基氯的常压羰基化反应有较好的催化活性,有些反应中苯乙酸的产率可达91%,可重复使用,是一类环境友好的新型绿色催化剂。

Poly(p-vinylbenzyl succinimide) resin,which can be abbreviated to succinimide resin,was prepared by the reaction of chloromethylated polystyrene with succinimide in the presence of base. The succinimide resin was characterized by diffuse reflectance infrared Fourier transform spectrometry and elemental analysis.

摘 要:在碱性条件下,氯甲基化聚苯乙烯与丁二酰亚胺反应合成了聚(对乙烯基苄基丁二酰亚胺)树脂,采用元素分析、红外光谱对合成树脂的组成进行了表征。

A series of 3,3,6,6 tetramethyl 1,8 dioxo 9 aryl 1,2,3,4,5,6,7,8,9,10 decahydro acridines have been synthesized by the condensation of aromatic aldehydes, 5,5 dimethyl 1,3 cyclohexanedione and ammonium acetate in the presence of triethylbenzylammonium chloride as catalyst in water.

芳醛、5 ,5 二甲基 1,3 环己二酮与醋酸铵在三乙基苄基氯化铵催化下以水作为溶剂反应,生成一系列 3 ,3 ,6,6 四甲基 1,8 二氧代 9 芳基 1,2 ,3 ,4,5 ,6,7,8,9,10 十氢吖啶,与其它溶剂相比,水作为该反应的溶剂具有价格便宜,不易燃和无毒等优点,而且产率较高,产物的结构通过单晶X射线确

In the first part,we studied the nucleophilic addition reactions of aldehyde, amine,Zinc and benzyl bromide in one pot to afford homobenzyl and homoallyl amines in moderate to good yields.

第一部分的工作中,我们研究了Barbier型条件下醛,胺,锌粉,溴试剂一锅法的亲核加成反应。这种反应可以高效的得到高苄基和高烯丙基胺类化合物。

The carbon tube ubstituted by benzyl chloride which is manufactured in the invention can adopt free radical addition reaction.

在本发明中制备苄基氯取代的碳管可以采用自由基加成反应。

The experiment consist of two parts :the first one research nucleophilic addition of m-dinitrobenzene, nucleophilic reagent is benzyl cyanide; the second one synthesize 2,4-dihydorxybenzophenone from 2,4-dichlorobenzophenone and NaOH.

实验分为两部分:第一部分研究了间二硝基苯的亲核加成反应,亲核试剂为苄基腈;第二部分是用2,4-二氯二苯甲酮与氢氧化钠反应制备2,4-二羟基二苯甲酮。

A chiral phase transfer catalyst, N-benzyl quinine bromide, was synthesized from natural chiral compound. And 2,5-bimethyl-4-(3-nitrobenzene)-1,4-bihydrogenation pyridine-3--4-methyl formate (viz. nitrendipine) was synthesized by this chiral phase transfer catalysis, and characterized by elemental analysis, infrared spectrum,1H nuclear magnetic resornace, and X-ray single-crystal diffraction.Key words: ammonium; chiral phase transfer catalyser; crystal structure

通过对天然手性物质进行修饰合成手性相转移催化剂N-苄基溴化奎宁,并对目标分子2,5-二甲基-4-(3-硝基苯)-1,4-二氢吡啶-3-甲酸乙酯-5-甲酸甲酯进行不对称催化合成,并通过红外光谱和核磁共振氢谱对化合物进行了表征,用X射线单晶衍射法测定了该化合物的晶体结构。

Benzyl isopropyl ether also forms CCT complex with oxygen on the benzene ring like phenyl isopropyl ether, but it is easy to oxidize since charge transfer and 〓 transfer may occur at the methylene group adjacent to the benzene ring, which result in the oxidation of the methylene group.(4) The 〓-CCT complex and the initial dark oxidation mechanism of poly were studied.

虽然苄基异丙醚也以苯环与O〓形成CCT复合物,但它却容易发生暗氧化,这是由于与苯基相连的是亚甲基,此时电荷转移发生在苯环与亚甲基之间,引起亚甲基的氧化,而不是异丙基的氧化。

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Now, however, all children continue in "comprehensive" schools, and the eleven-plus determines which courses of study the child will follow.

然而现在,所有的孩子都要在综合学校继续学习,所以这次考试只是决定他们将要学习哪些课程。

Cultivatable land , and led to a general recognition that development must not be carried at the cost of agriculture .

城区的迅速扩大在很多情况下侵占了宝贵的可耕地,使人们普遍认识到发展不能以牺牲农业为代价。

Detailed Intrinsic Reaction Coordination calculations were carried out to guarantee the optimized transition-state structures being connected to the related tautomers.

同时,做了详尽的内禀反应坐标计算,以保证所得到的过渡态连接相应的始末异构体。