苄基

The genera formulas of these compounds are as follows:The strobilurin derivatives were synthesized from substitutedβ-keto esters (2) as starting material which were prepared from substituted ketones (1) and dimethyl carbonate. The ester (2) and methyl hydrazine or substituted amidine were dissolved in methanol and the mixture was heated to reflux to obtain the substituted 5-hydroxy-1H-pyrazole (3) or 4-hydroxy-pyrimidine (4). The title compounds were prepared by reacting the intermediates (3 and 4) with substituted halomethylphenyls which contain four active group under basic conditions.

本论文所合成的strobilurin化合物均是以β-酮酸酯类化合物(2)为起始原料合成的，该中间体(2)是由酮类化合物(1)与碳酸二甲酯在碱性条件下反应生成的，中间体(2)与甲基肼或取代脒类化合物在甲醇中回流制得取代的1H-5-羟基吡唑(3)或4-羟基嘧啶(4)，中间体(3和4)再与包含四种活性基的苄卤中间体在碱性条件下制得目标化合物。

In summary, 4, 6-dimethoxy-2-substituted pyrimidine benzylamine is chosen as a lead compound based on the possibility of synthesis, optimization, and the herbicidal activity.

考虑到合成的可行性、分子结构的可修饰性和除草活性的大小，确定4，6-二甲氧基-2-取代嘧啶苄胺类化合物为除草剂的先导结构。

In the forth chapter, the mechanism of pyrimidine benzylamine compounds is studied by the conventional bioassay and biochemical methods based on probe compound 104-4. The results presented here indicated that the addition of 5 mg/L of 3 branched-amino acids to sorghum seedling cultures incubated in the presence of 104-4 completely alleviated herbicide-induced stem growth inhibition, but each of Val, Ile and Leu single is only partly effective in reversing 104-4-induced growth inhibition at the same concentrations.

通过先导结构优化策略的实施，筛选出15个高除草活性的4，6-二甲氧基-2-取代嘧啶苄胺类候选化合物，在此基础上，对一些候选化合物进行作物安全性评价试验，实验结果提示化合物103-1和化合物105-3在低剂量下对某些作物有良好的选择性，可作为优选化合物进入田间小区试验。

The mixed trimeric compounds containing one ferrocene unit, N,N'-bis(2-hydroxy-5-substituted benzylidene)ferrocenylmethylenediamine, have been synthesized directly through the reaction between 1 mol of ferrocenecarboxaldehyde and 2 mol of 5-substituted salicylaldehyde.

通过甲酰基二茂铁与取代水杨醛和氨反应，直接合成了含一个二茂铁的混合三聚产物， N，N'-二[2-羟基-5-取代苄烯]二茂铁甲二胺。

Preparation of p \|cyanobenzylbromides by the bromization of p\|methylbenzenenitrile with H 2O 2\|Br 2 was studied under irradn in the cyclohexane solvents.

研究了在过氧化氢的存在下，用液溴和过氧化氢溴化对甲苯腈制备对腈基苄溴的方法。

2S, 3S -2-methyl -3-benzoxyl butanal was obtained from cis-2-butene and acetaldehyde in 56. 3％ yield through Brown Crotylation, oxidization, etc.

以顺-2-丁烯、乙醛为原料，经Brown Crotylation反应、氧化反应等，得到了（2S，3S）-2-甲基-3-苄氧基丁醛，收率为56.3％。

Aqua, Sorbitol, PPG-1 PEG-9 Lauryl glycol ether, Hydrolyzed elastin, Hydrolyzed wheat gluten, Hydrolyzed collagen, Hydrolyzed glycosamino-glycans, Humulus lupulus, Propylene glycol, Triethanolamine, Sodium hydroxide, Carbomer, Maris limus extract, Ostrea extract, Imidazolidinyl urea, Parfum, Benzyl salicylate, Coumarin, Alpha isomethyl ionone, Hexyl cinnamal, Buthylphenylmethylpropionate, Linalol, Methylisothiazolinone, Methylchloroisothiazolinone.

水，山梨醇， PPG 公司- 1聚乙二醇- 9十二烷基醇醚，水解弹性蛋白，水解小麦面筋蛋白，水解胶原蛋白水解粘多糖，多聚糖，啤酒花提取物花，丙二醇，三乙醇胺，氢氧化钠，卡波姆，马里斯提取物，牡蛎提取物，咪唑烷基脲，香水，水杨酸苄酯，香豆素，阿尔法 l 紫罗兰酮，己基肉桂醛，丁苯基甲基丙醛，芳樟醇，甲基异噻唑啉酮，甲基氯异塞唑晽酮。

METHODS:This compound was synthesized via acylation and hydrogenization using aciclovir and CBZ-L-valine as meterial.

以阿昔洛韦和N-苄氧羰基-L-缬氨酸为原料，经酰化、催化氢解反应得到了新型抗疱疹病毒药物缬昔洛韦。

The intramolecular Reformatsky-type reaction of benzyl bromide and keto group is the key step.

其中关键步骤是苄溴与酮基的分子内Reformatsky型反应。

The synthetic route starts from penicillin G, peroxyacetic acid(8.5%) as Oxidizing Agent to get penicillin G sulfoxide; esterifided with p-nitrobenzyl bromine to synthesize penicillin G sulfoxide ester; we synthesize 3-exomethylenecepham sulfoxide ester with phthalimide potassium and 4A molecular sieve as acid scavenger to open the ring, SnCl_4 as catalyzation to close the ring. The yield is over 60%.

本研究采用的合成路线为：以青霉素G钾盐为原料，选用工业过氧化氢制备的过氧乙酸(22.3%)稀释至8.5%为氧化剂，氧化得青霉素亚砜；采用对硝基溴苄为酯化试剂，制备青霉素亚砜酯；以NCP(N-氯代邻苯二甲酰亚胺)为开环试剂，酞酰亚胺钾和4A型分子筛为酸清除剂，顺利开环；再经无水SnCl_4催化闭环得3-环外亚甲基头孢亚砜酯，最终产率在60%以上。

Now, however, all children continue in "comprehensive" schools, and the eleven-plus determines which courses of study the child will follow.

然而现在，所有的孩子都要在综合学校继续学习，所以这次考试只是决定他们将要学习哪些课程。

Cultivatable land , and led to a general recognition that development must not be carried at the cost of agriculture .

城区的迅速扩大在很多情况下侵占了宝贵的可耕地，使人们普遍认识到发展不能以牺牲农业为代价。