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Methods Phenylacetaldehyde was prepared from benzimidazolium salt and benzyl chloride by the addition-hydrolysis reaction of benzimidazolium salt with Grignard reagent.

方法以苯并咪唑盐和苄基氯为原料,利用苯并咪唑盐与Grignard试剂的加成-水解反应合成苯乙醛。

The organic montmorillonite VC18-MMT was prepared by the exchanging inorganic cations with vinylbenzyldimethyloctadecylammionun chloride which could be co-polymerized with styrene.The predispersion of VC18-MMT was realized via sonicating the suspension of the montmorillonite particles in emulsifier solution,and then the styrene was added into the system and the in situ emulsion polymerization was carried out to prepare PS/VC18-MMT nanocomposites.

以可与苯乙烯发生共聚的阳离子表面活性剂乙烯苄基二甲基十八烷基氯化铵为插层处理剂改性蒙脱土(VC18-MMT),有机蒙脱土在超声波强剪切作用以及乳化剂作用下预分散在乳化剂溶液中,然后引入苯乙烯单体进行原位乳液聚合制备聚苯乙烯/蒙脱土纳米复合材料。

The related feature of tribromide quaternary ammonium salt as selective bromide reagent was investigated by the reaction of acetophanone, propanone, phenol with self-made benzyl triethyl tribromide quaternary ammonium salt.

首次通过自制的苄基三乙基三溴季铵盐与苯乙酮、丙酮、苯酚等的反应,研究了三溴季铵盐作为选择性溴化剂的相关性能。

The present dissertation reviews the total synthesis of biotin, particularly on Hoffmann-La Roche\'s Lactone-Thiolactone approach. The Lactone-Thiolactone approach is presently the most competitive commercial route, which gives an excellent illustration of the gradual construction of the functionalized skeleton with the simultaneous solution of the stereochemical issues in a minimal number of steps.In 1970, Gerecke etc. of Roche Corp.

论文对生物素全合成的文献进行了综述,重点讨论了目前工业上最有竞争力的内酯—硫代内酯路线,展示了生物素是如何以最少的步骤去逐步构建目标产物的官能团骨架并同时解决立体化学问题的。1970年,Roche公司的Gerecke等报道了一条通过手性内酯,以较高收率并保持构型得到手性硫代内酯,从而直接合成d-生物素的方法后,该中间体内酯(3aS,6aR)-1,3-二苄基

Thiobarbituric acid was synthesized by sulfourea and diethyl malonate in sodium alcohol and 5-Arylidene thiobarbituric acid was prepared by the Knoevenagel condensation reaction from benzaldehyde and thiobarbituric acid.

采用丙二酸二乙酯和硫脲在乙醇钠存在下合成了硫代巴比妥酸,再分别采用固相反应和水相反应,由硫代巴比妥酸和苯甲醛经Knoevenagel缩合反应,制备了5-亚苄基硫代巴比妥酸。

In the aqueous solution, Cu precipitates with ammonium thiocyanate and tetradecyl benzyl dimethylammonium chloride .

研究发现,在水溶液中Cu与硫氰酸铵、氯化十四烷基二甲基苄基铵形成不溶于水的三元缔合物,在少量氯化钠存在下此三元缔合物沉淀浮于水相上层并与水分成界面清晰的两相,分相过程中Cu被定量浮选。

Using the cationic detergent benzyldimethyl -alkylammonium chloride instead of cytochrome C in spreading procedure, we have observed the binding site for EcoR Ⅰ on linear pBR322 DNA molecule in the presence of gluteraldehyde. The diameter of the bound EcoR Ⅰ molecules are 15nm which may be the tetrameric EcoR Ⅰ particles.

用低分子量阳离子去垢剂苯二甲基苄基氯化胺取代经典展层技术中的细胞色素C,汲取前人经验,建立了无蛋白展层技术,适用于蛋白质--DNA相互作用的电镜研究。

A new unsymmetrical ONO tridentate chain ligand N-(2′-hydroxyl) benzyl-ethanolamine has been synthesized and characterized by elemental analysis, IR and 1NMR.

宗汉兴 ,林瑞森,寇福平,解永树合成了不对称氮氧杂链型配体N-(2′-羟基苄基乙醇胺,通过元素分析、IR和1H NMR等手段进行了表征。

This research uses the triethyl phenmethyl ammonium chloride to make the catalyst, take double phenol A, the epichlorohydrine, the sodium hydroxide as raw material, to affected factors and so on effect allocated proportion, temperature, reaction time to conduct the full research.

本研究采用三乙基苄基氯化铵作催化剂,以双酚A、环氧氯丙烷、氢氧化钠为原料,对影响效果的配比、温度、反应时间等因素进行了充分的研究。

In this paper a series of multiblock copolymers were synthesized by polycondensation of poly , phthalic anhydride and epoxy resin in the presence of triethyl benzyl ammonium chloride as the catalyst.

以三乙基苄基氯化铵为催化剂,将聚乙二醇、邻苯二甲酸酐和环氧树脂进行共缩聚,制得聚乙二醇-环氧树脂系列多嵌段共聚体。

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