苄叉二氯

The kinetic of hydrolysis of benzal chloride was studied by using a new kind of phase transfer catalyst in this paper.

摘 要：研究了在新型相转移催化剂作用下苄叉二氯水解反应过程的动力学。

The kinetic of hydrolysis of benzal chloride was studied by using a new kind of phase transfer catalyst in this paper.

研究了在新型相转移催化剂作用下苄叉二氯水解反应过程的动力学。

The highest mole ratio of benzal chloride and reaction time at different tempe.

根据模型，得到苄叉二氯在反应体系中能达到的最高摩尔组成为0.7和不同温度下的反应时间，为苄叉二氯的生产工艺条件的确定提供了可靠依据。

The proper hydrolysis reaction temperature of benzal chloride was 1000C and the initial quality rate of water phase and organic phase was 2∶1,reaction time was 3 hours.

苄叉二氯的水解方法已经有很多报道[1，2]，主要的方法有酸性水解法、碱性水解法、酸碱联合水解法和催化水解法。

The two step reaction activity energies were 28.14 kJ/mol and 58.37 kJ/mol in the temperature range from 95 ℃ to 125 ℃,and the model values and experimental values tally well. The highest mole ratio of benzal chloride and reaction time at different tempe...

根据模型，得到苄叉二氯在反应体系中能达到的最高摩尔组成为0.7和不同温度下的反应时间，为苄叉二氯的生产工艺条件的确定提供了可靠依据。

The study on the technology and kinetics of chlorination of benzyl chloride is rather essential to the design of reactive distillation column in that the new technology about combination of reaction and distillation is used in the production of benzal chloride.

因为拟采用新型反应精馏耦合技术进行苄叉二氯的生产，研究氯化苄氯化工艺和动力学对于反应精馏塔的设计很有必要。

Using benzyl chloride and chlorine as starting materials, benzal chloride is prepared through photo-chlorination in loop reactor.

采用环流反应器、以氯化苄和氯气为原料进行光氯化反应，制备苄叉二氯；将制得的苄叉二氯粗品进行真空精馏得到高纯度的精品；然后用一种新型醇胺类相转移催化剂，分别以盐酸和水作为介质，在 90～ 110℃水解后得到了高纯度的苯甲醛。

The hydrolyzation of benzal chloride is the heterogeneous phase gas-liquid-liquid reaction. A new kind of phase transfer catalyst was adapted and the study on the feasibility of hydrolyzation of benzal chloride, reaction technology and kinetics was carried out in order to get rid of heavy metal pollution caused by zinc catalysis.

苄叉二氯的水解是一个非均相气－液－液反应，为避免原有锌盐催化剂可能造成的重金属污染，采用一种新型相转移催化剂，进行了苄叉二氯水解反应可行性、反应工艺及动力学的研究。

The simplified peseudo-first-order kinetic model for hydrolyzation of benzal chloride was proposed according to the character of hydrolyzation reaction and the apparent reaction rate constant and activity energy was obtained. The activity energy is 17.73KJ/mol in the temperature range from 900C to 1100C and the model values and experimental values tally well.

根据水解反应的特点，提出了简化的苄叉二氯水解反应拟一级动力学模型，经参数估计，得出了水解反应的宏观反应速率常数和活化能，在900C～1100C温度范围内，反应活化能为E1＝17.73kJ/mol，模型计算值与实验值吻合较好。

The procedure of benzal chloride and benzylchloride was obtained by chlorination toluene, then through catalytic acidic hydrolysis and oxidation, produced benzaldehyde.

本文研究了甲苯氯化得到苄叉二氯和氯化苄混合物，然后经催化酸解氧化制备苯甲醛，并探讨了氯化催化酸解及氧化的反应条件。

Now, however, all children continue in "comprehensive" schools, and the eleven-plus determines which courses of study the child will follow.

然而现在，所有的孩子都要在综合学校继续学习，所以这次考试只是决定他们将要学习哪些课程。

Cultivatable land , and led to a general recognition that development must not be carried at the cost of agriculture .

城区的迅速扩大在很多情况下侵占了宝贵的可耕地，使人们普遍认识到发展不能以牺牲农业为代价。