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Birch Reduction, one of the most powerful synthetic methodologies available to organic chemists, provides a bridge between aromatic and aliphatic compounds and makes a huge arsenal of aromatic derivatives readily available for construction of alicyclic molecules, which are possibly converted into various natural products.

Birch还原是联接芳香族和脂肪族化合物的桥梁,它使许多芳香族衍生物成为合成脂肪族化合物,尤其六元脂环天然产物的起始原料,因此Birch还原是有机合成中很有用的方法。

Over the past four decades, many dearomatization reactions have developed and applied for synthesis of alicyclic compounds con-taining six–membered carboncyclic moieties.

芳香族化合物稳定、易得,通过芳香族化合物的脱芳构化反应,制备官能化的脂肪六元碳环化合物,早以引起人们的广泛兴趣。

In this catalyst system, the Knoevenagel condensations of a series of aromatic aldehydes with malononitrile or ethyl cyanoacetate were programmed and a mechanism was postulated as well. When aromatic aldehydes reacted with ethyl cyanoacetate, the corresponding alkenes proved to be E-isomers by 1H NMR.

在该反应体系中考察了一系列芳香醛和丙二氰、氰基乙酸乙酯的缩合反应,并推测了Knoevenagel缩合反应的机理,芳香醛与氰基乙酸乙酯缩合产物经1H NMR检测为E式烯烃。

The cesium fluoride-mediated N,N-diarylation of 4-(biphenyl-4-oxy)aniline with 4-fluoronitrobenzene and subsequent reduction of the dinitro intermediate led to a new triphenylamine-based diamine monomer, 4,4'-diamino-4-(biphenylyl-4-oxy)triphenylamine.

以氟化铯为媒介将此苯胺与 4-fluoronitrobenzene 进行芳香族亲核取代反应,随后再进行dinitro中间体的还原反应,制得ㄧ种新型具有三苯胺结构的芳香族二胺单体4,4'-diamino-4-(biphenylyl-4-oxy)triphenylamine。

This thesis aims at the studies on the synthesis routes of aromatic and unaromatic tricyclic diterpenoids.

本论文工作以芳香型三环二萜和非芳香型三环二萜的合成路线为研究对象,包括五部分:第一章三环二萜类化合物研究综述按照三环二萜的分类。。。

The cokes are come from aromatics, colloids, asphaltene and Carbenes which are polycondensated and dehydrogenated. The processing of coking in the system are as follows: aromatics-→colloids-→asphaltene-→Carbenes-→cokes.(4) Coking can be avoided in the plasma reactor by feeding coal powder of 40~60 mesh (30%) and coal powder of less than 140 mesh (70%).

3结焦主要发生在等离子体反应较高温区,由煤中的芳香分、胶质、沥青质和碳青质缩聚脱氢形成;装置结焦形成的大体途径为:芳香分-→胶质-→沥青质-→碳青质-→焦质。

The o-aminobenzaldehyde ethylene acetals can be synthesized from corresponding o-nitrobenzaldehyde by reducing the nitro-group after the protection of carbonyl by ethylene. 2-Aminophenyl ketone ethylene ketal can also be prepared from 2-nitrophenyl ketones by this method.

邻氨基苯甲醛乙二醇缩醛可以由含不同取代基的邻硝基苯甲醛经羰基以乙二醇缩醛保护后还原硝基得到,邻氨基芳香酮乙二醇缩酮可以同样的方法由邻硝基芳香酮得到。

The reaction of 3 with aryl aldehyde oximes afforded exclusively the product 4 under the PTC conditions.

在相转移催化条件下,3与芳香醛肟反应得到单一的产物4,与芳香酮肟反应则生成4和5的混合物。

Molecular orbital analysis, nucleus-independent chemical shift analysis and natural bonding orbital analysis showed that they have aromaticity or non-aromaticity.

通过分子轨道分析、核独立化学位移分析以及自然键轨道分析,说明B〓和B〓是具有三个π电子的非芳香体系;B〓是具有两个π电子的芳香体系。

The chemistry of transition-metal-containing aromatic compounds is attracting increasing research interests because they show the aromaticity as well as the reactivities of organometallics.

金属杂芳香化合物由于兼具金属有机化合物和芳香化合物的性质而日益引起人们的研究兴趣。

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推荐网络例句

On the other hand, the more important thing is because the urban housing is a kind of heterogeneity products.

另一方面,更重要的是由于城市住房是一种异质性产品。

Climate histogram is the fall that collects place measure calm value, cent serves as cross axle for a few equal interval, the area that the frequency that the value appears according to place is accumulated and becomes will be determined inside each interval, discharge the graph that rise with post, also be called histogram.

气候直方图是将所收集的降水量测定值,分为几个相等的区间作为横轴,并将各区间内所测定值依所出现的次数累积而成的面积,用柱子排起来的图形,也叫做柱状图。

You rap, you know we are not so good at rapping, huh?

你唱吧,你也知道我们并不那么擅长说唱,对吧?