芳香化合物

In the part two, we reported the classical Knoevenagel condensation between aromatic aldehydes and acyclic active methylene compounds or cyclic active methylene compounds containing heteroatom such as (2-thio)barbituric acid, Meldrum's acid using ionic liquids as reaction medium.

在第二部分中我们研究了离子液体中开链活性亚甲基化合物、杂环类活性亚甲基化合物如(2-硫代)巴比妥酸、Meldrum's酸与芳香醛之间的Knoevenagel缩合反应。

The molecular charge distribution of the reactivator is affect the reactivating efficacy directly. Moreover its association with hydroximic acid dissociation constant pAa closely, and it will have a great impact on reactivating ability indirectly.(3) There is likely to exist front molecular interaction between Cholinesterase Reactivators and OPC-inhibited AChE, the action sites mainly lie on the aromatic ring, the substitute R and the hydroixic acid group. They act on the aromatic residues of AChE by Π-Π conjugation .(4) The reached results by Comparative Molecular Field Analysis is useful to design new higher efficacy derivatives for 1, 2, 4-oxadiazole class nonquaternary Cholinesterase Reactivators.

2复能剂分子的电荷分布直接影响复活活性，同时对肟酸解离常数pKa具有重要影响，间接影响复活能力；(3)复能剂与磷酰化酶可能存在前线轨道作用，作用部位可能主要在芳香环及其取代基R和肟基上，与AchE的芳香族残基发生л-л电子作用；(4)通过比较分子力场法研究可以指导1，2，4-oxadiazole类非季铵肟胆碱酯酶重活化剂新化合物的合成，可能得到活性更高的复能剂。

Malodor, volatile organic compounds and polycyclic ...

有机化合物及多环芳香烃碳氢化合物。

Separation of organic-organic mixtures by pervaporation is discussed with emphasis on the following aspects: pola...

其中，又重点报道了有机混合液分离的最新研究成果，将其分为：极性/非极性化合物、芳香烃/脂肪烃体系、芳香烃/脂环烃体系、同分异构体、多元体系和汽油脱硫等六部分进行了详细叙述。

Thirdly,in the view of some different results between the reaction of complexes(2)、(3)and[(Me_3Si)_2N]_3LnLi_3 with aromatic aldehydes, the reaction of 2 equiv of aromatic aldehydes with 1 equiv of lithium amide(1) catalyzed by the YCl_3 was subsequently studied,and better yields of the corresponding amides and alcohols can be isolated.These results indicated that the enolate ligand in complexes(2)、(3)may have impact on the Cannizzaro disproportionation reaction.

第三，鉴于上述配合物2、3和[(Me_3Si_2)2_N]_3LnLi_3与芳香醛反应结果上的一些差别，我们又以三氯化钇为催化剂，将两当量的芳香醛与一当量化合物1的锂盐直接进行反应，结果以较好的产率得到了相应的酰胺和醇，这说明配合物2、3中所含的乙烯醇基可能对此Cannizzaro-型歧化反应存在一定的影响。

Laccases are able to oxidise both phenolic and nonphenolic compounds. They have broad ranges of subsrate specificity. Therefore, they are very useful for applications on pulp bleaching, textile dye decolouration, effluent detoxification, bioremediation and biosensors.

由于漆酶能够氧化芳香类化合物和其它一些非芳香类有机物，具有广泛的底物特异性，因此在纸浆漂白、纺织品染料脱色、有毒废弃物的去除、生物修复和生物传感器等方面具有巨大的应用潜力。

In this dissertation, electrophilic reactions of Nitrosonium with imines, aza-Diels-Alder reactions of N-arylimines with a variety of electron rich olefinic compounds induced by NO~+, and photoreactions of N-nitrosodiphenylamine with aromatic amines were studied.

本文研究了：(1)NO~+与亚胺双健发生的亲电反应；(2)NO~+引发的芳香亚胺和富电子碳碳双键作为亲二烯体的氮杂Diels-Alder反应，高选择性地得到了一系列四氢喹啉的衍生物；(3)N—亚硝基二苯胺与芳香胺发生光化学反应得到了一系列偶氮苯类化合物。

This thesis aims at the studies on the synthesis routes of aromatic and unaromatic tricyclic diterpenoids.

本论文工作以芳香型三环二萜和非芳香型三环二萜的合成路线为研究对象，包括五部分：第一章三环二萜类化合物研究综述按照三环二萜的分类。。。

Accordingly, aromatic compounds can be divided into three groups and a delocalized π system itself is always destabilized, the dependence of aromatic ring current upon the CT was reveled, and ring rigidity has been defined as a new aromatic index.

据此，我们提出了芳环化合物新的分类准则，揭示了芳香环流起因的必要条件，定义环的刚度为芳香性一个新判据。发现，分子内基团间的局部作用同它们对分子整体性能的影响是完全相反的。

Separation of racemic mixtures of thirty-eight secondary aromatic alcohols and arylethanediols with different substituting group was achieved with HPLC by using Chiralcel OD and Chiralcel LJ as chiral stationary phase and hexane/2-propanol mixtures of different ratios as eluents. The chromatographic parameters of these racemates on OD and OJ columns were examined.

在ChiralcelOD和ChiralcelOJ两支多糖类手性固定相上，以各种不同配比的正己烷-异丙醇为洗脱剂对38种带有不同取代基的芳香仲醇及芳香乙二醇类手性化合物的对映体进行拆分，考察了这些外消旋体在这两支手性柱上的色谱行为。

With Death guitarist Schuldiner adopting vocal duties, the band made a major impact on the scene.

随着死亡的吉他手Schuldiner接受主唱的职务，乐队在现实中树立了重要的影响。

But he could still end up breakfasting on Swiss-government issue muesli because all six are accused of nicking around 45 million pounds they should have paid to FIFA.

不过他最后仍有可能沦为瑞士政府&议事餐桌&上的一道早餐，因为这所有六个人都被指控把本应支付给国际足联的大约4500万英镑骗了个精光。