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芳香化合物

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A new convenient synthesis of a series of 1-aryl-2-propanones using aromatic amine s as precursors, via diazo reaction and improved Meerwein arylation reaction under mild conditions, was achieved.

以芳香胺为原料,经重氮化和改进的Meerwein芳基取代反应,合成了一系列的1-芳基-2-丙酮,其中1-(3,5-二三氟甲基苯基)-2-丙酮是一个新化合物。

A new convenient synthesis of a series of 1-aryl-2-propanones using aromatic amines as precursors, via diazo reaction and improved Meerwein arylation reaction under mild conditions, was achieved. In addition, 1-[3,5-bisphenyl]-2-propanone is a new compound among the synthesized compounds. This approach is an efficient synthetic method for the aryl-propanones with the different substituting groups.

以芳香胺为原料,经重氮化和改进的Meerwein芳基取代反应,合成了一系列的1-芳基-2-丙酮,其中1-(3,5-二三氟甲基苯基)2-丙酮是一个新化合物改进后的方法简化了合成步骤,提高了收率,可方便地用于在苯环上具有不同取代基的芳基丙酮的合成。

The homocamptothecins with different substituted group in ring A and ring B can be obtained by the Friedlander condensation of the ring CDE with the acetals or 2-aminophenyl ketones.

以不同的缩醛与CDE环经Friedlander反应,可以得到A环上不同取代的高喜树碱类化合物,以缩酮或芳香酮反应,则可得到同时在A、B环取代的高喜树碱。

For the first time,our group found that lanthanide amides can initiate the Cannizarro disproportionation reaction of aromatic aldehydes.

我们小组首次发现了通过稀土胺基化合物引发芳香醛发生Cannizzaro-型歧化反应,生成相应的酰胺和醇。

The prime raw materials for azo pigment are a diazo component such as aromatic amine and a coupling component such as phenolic compound.

偶氮颜料的主要原料是一些重氮成份如芳香族胺和一些偶联成份如酚类化合物。

In the cut-throat world of perfume design and manufacturing, perfume is a complex chemical mixture of essential oils, aroma compounds, fixatives, solvents, beautiful bottles and celebrity-endorsed marketing.

在激烈的世界香水的设计和制造,香水是一个复杂的化学混合物香精油,芳香族化合物,固定剂,溶剂,美丽的瓶和名人赞同营销。

Development of solvents, phase-transfer catalysts and fluorides in synthetic reactions is reviewed.

卤素交换氟化反应是合成重要有机中间体含氟芳香族化合物的重要工业化方法。

The homologs of benzene are those containing an alkyl group or alkyl groups in place of one or more hydrogen atoms.

苯环上一个或多个氢原子被烷基基团所取代的化合物称为芳香族同系物。

The novel synthesis of the 2-hydroxyl α-arylglycines was realized through the Lewis acids promoted Friedel-Crafts reaction of phenols and N-tosyl imino ester in mild reaction conditions.

其中在路易酸TiCl〓促进下,酚类化合物和亚胺酯发生的傅克反应,可较高产率、较高区域选择性的得到2-羟基α-芳香甘氨酸衍生物。

"Toluene: Colourless, flammable , toxic liquid hydrocarbon aromatic compound (C6H5CH3), the methyl derivative of benzene."

甲苯:无色、易燃、有毒的液体烃芳香族化合物,是由苯衍生出甲基。

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With Death guitarist Schuldiner adopting vocal duties, the band made a major impact on the scene.

随着死亡的吉他手Schuldiner接受主唱的职务,乐队在现实中树立了重要的影响。

But he could still end up breakfasting on Swiss-government issue muesli because all six are accused of nicking around 45 million pounds they should have paid to FIFA.

不过他最后仍有可能沦为瑞士政府&议事餐桌&上的一道早餐,因为这所有六个人都被指控把本应支付给国际足联的大约4500万英镑骗了个精光。

Closes the eye, the deep breathing, all no longer are the dreams as if......

关闭眼睛,深呼吸,一切不再是梦想,犹如。。。。。。