芳香

A novel BB'2-type aromatic triamine containing pyridine ring was successfully synthesized by catalytic reduction of the trinitro compound obtained by a modified Chichibabin reaction in acidic medium with hydrazine hydrate.

采用商品化的原料，在酸性介质中经改进的Chichibabin反应先合成含吡啶环的三硝基化合物，再用水合肼催化还原得到一种新型的含吡啶环BB'2型芳香三胺单体。

Two analogues of Trichosanthes trypsin inhibitor I with the Cys14- Cys26 or Cys8- Cys20 disulfide bonds replaced by Tys or Phe and two negative control analogues substitution serine for cysteine at 14 and 26 or 8 and 20 positions were synthesized, respectively. The C14F-C26Y mutant had 1/140 inhibitory activity of native Trichosanthes trypsin inhibitor I to trypsin.

第二章是对天花粉胰蛋白酶抑制剂的两对二硫键的作用进行了研究，二硫键在蛋白质的折叠和功能中有重要的作用，芳香族氨基酸的芳环之间形成π-π共轭能否部分补偿二硫键的作用？

This study is design and preparation of active peptide analogues of mung bean trypsin inhibitor Lys fragment, Trichosanthes trypsin inhibitor I, carcinoembryonic antigen peptide and aspartame using solid and liquid phase peptide synthesis methods.

本论文研究活性多肽类似物的设计、制备和功能，分为四个部分，采用多肽固相和液相合成的方法，分别合成了活性多肽绿豆胰蛋白酶抑制剂 Lys片段长链16肽、天花粉胰蛋白酶抑制剂、癌胚抗原肽、甜味肽等一系列类似物，并测定了这些类似物的生物活性，有以下新的研究结果：1、furin酶抑制剂的设计、制备和功能；2、芳香氨基酸芳环之间的π-π共轭能部分补偿二硫键的作用；3、癌胚抗原肽Gly4被L-Pro替代可增加与HLA-A2分子的结合；4、肽键对甜味肽保持甜味是必须的。

Three methods for trimellitic anhydride production including MGC,nitric aid oxidation,and liquid phase oxidation by air were compared.

比较了生产偏苯三酸酐的3种方法：芳香醛水溶液空气氧化法、硝酸氧化法和液相空气氧化法。

Due to the hemilability of the heteroaromatic functionalized cyclopentadienyl ligand, these complexes showed considerable activity and high selectivity for ethylene trimerization to 1-hexene.

由于这类芳香杂环-茂配体具有Hemilabile特性，因此，此类络合物显示了一定的乙烯三聚活性和高的三聚选择性。

Two novel aromatic diamines consisting of triphenylamine and 1,3,4-oxadiazole groups were successfully synthesized.

本研究成功合成二种含有三苯胺及1，3，4-恶二唑结构的新型芳香族二胺单体。

First, N'-(4-aminophenyl)-N'-4-(5-phenyl-1,3,4-oxadiazol-2-ylphenylbenzene-1,4-diamine was prepared and polymerization was carried out by direct polycondensation with a series of dianhydrides to obtain polyimides containig triphenylamine units in the main chain and 1,3,4-oxadiazole moieties as pendent group.

首先合成新型双胺N'-(4-aminophenyl)-N'-4-(5-phenyl-1，3，4-oxadiazol-2-ylphenylbenzene-1，4-diamine后，与一系的芳香族二酐进聚缩合反应，可制得一系列三苯胺为主链且1，3，4-恶二唑为侧链的聚醯亚胺。

A new tripodal aryl amide type ligand,1,1,1-tris{[(2′-benzylaminoformyl)phenoxyl]methyl}-p-toluene sulfonyl aminomethane,and its Eu(NO_3)_3,Tb(NO_3)_3 complexes have been synthesized.

合成了一个新的三足芳香酰胺型有机配体1，1，1-三[(2′-甲酰苄胺苯氧)甲基]对甲苯磺酰氨基甲烷，及其Eu(NO3)3和Tb(NO3)3的配合物，并通过元素分析、红外光谱、核磁共振氢谱和摩尔电导率进行了表征。

SAA ligand Lg could catalyze asymmetric addition of phenylacetylene to unactivated aromatic ketones in high yields (up to 83%) and high enantioslectivities (up to 83%ee).

SAA配体Lg用于催化炔基锌对未活化酮的不对称加成反应，对于芳香酮的催化反应，收率可达83%，对映体选择性可达83%ee。

New compounds of the type of unsymmetrically substituted ureas are synthesized by a series of reactions of preparing organic isocyanates by Curtius rearrangement with aromatic amine.

以3 苯基 2 丙烯酸为原料，用Curtius重排的方法合成异氰酸酯，直接与芳香胺作用，合成了5 种N 取代苯基 N′苯丙烯基脲类化合物。

On the other hand, the more important thing is because the urban housing is a kind of heterogeneity products.

另一方面，更重要的是由于城市住房是一种异质性产品。

Climate histogram is the fall that collects place measure calm value, cent serves as cross axle for a few equal interval, the area that the frequency that the value appears according to place is accumulated and becomes will be determined inside each interval, discharge the graph that rise with post, also be called histogram.

气候直方图是将所收集的降水量测定值，分为几个相等的区间作为横轴，并将各区间内所测定值依所出现的次数累积而成的面积，用柱子排起来的图形，也叫做柱状图。