芳芳

Chapter 3: Synthesis of 2-aroyl-l,3,5-triaryl-4-carbethoxy-4-cyanocyclohexanols from chalcones with ethyl cyanoacetate is carried out in excellent yields with KF/basic alumina as catalyst under ultrasound irradiation.

第三章：研究了超声辐射下，以碱性氧化铝固载氟化钾为催化剂，利用查耳酮和氰乙酸乙酯合成2-芳酰基-1，3，5-三芳基-4-乙酯基-4-氰基环己醇。

The main compositions of LP are shorter chain carboxylic acid and their ethyl esters, furan derivatives, cyclopentanone, phenol derivatives, benzene derivatives, aromatic ketone, aromatic acid derivatives, longer chain carboxylic ethyl esters and sterides. After upgrading, the main indexes reach the standard of fuel oil.

结果表明，LP的主要成分包括短链或环状脂肪酸及其酯、呋喃衍生物、环戊烯衍生物、苯酚衍生物、苯衍生物、芳酮、芳酸及其乙酯、长链脂肪酸乙酯和甾族化合物，经提质其主要指标达到了燃料油的标准。

The technological advances of toluene disproportionation and transalkylation process,shape selective disproportionation of tolueneand dealkylation process of heavy aromatics, domestic and abroad, were reviewed.

综述了国内外芳烃联合装置中甲苯歧化与烷基转移工艺、甲苯择形歧化工艺和重芳烃脱烷基工艺近年来技术进展情况，并分析了各种技术的优势与不足之处。

Studing on samarium diiodide promoted asymmetric intramolecular reducing coupling reactions, we have made the resolution of the racemic biaryl dials by using enantiomeric N-tert-butanesulfinamine as the resolving reagent successfully and thus obtained a series of axially chiral biaryl dials with high enantiomeric excess.

中文摘要在二碘化钐促进的分子内不对称还原偶联反应中，我们不仅对联芳基二醛底物的合成路线进行了优化，还发现N-叔丁基亚磺酰胺辅基可以作为手性试剂，成功地对联芳基骨架二醛化合物进行拆分，得到高对映体过量的轴手性二醛类化合物。

The chapter two was focused on the samarium diiodide promoted organic reactions and their applications in organic synthesis, firstly, a new synthesis of highly substituted cyclopentadienes from a,β-alkynone promoted by samarium diiodide was investigated and the highly substituted cyclopentadienes were prepared in moderate to good yields under mild conditions. Secondly, the Michael addition and Michael-aldol tandem reaction of diorganyl diselenides or diorganyl disulfides with α,β-alkynones mediated by samarium diiodide were studied and a series of alkenylsulfides and alkenylselenides were prepared in good yields. Then the highly regioselecfive nucleophilic addition of the allylsamarium bromide to α,β-alkynones were explored. We found that the allylsamarium bromide reacts with α,β-alkynones to afford regiospecificly 1. 2-nucleophilic addition products in good yields under mild condition. At last we studied the coupling reaction of aryl halides promoted by NiCl〓/PPh〓/Sm〓.

第二章 研究了二碘化钐、金属钐促进的有机反应：1、二碘化钐促进下α，β-炔基酮的偶联环化反应，提供了一种制备多取代环戊二烯的新方法；2、二碘化钐促进下的二硫醚、二硒醚与α，β-炔基酮的Michael加成反应，为高产率地制备多取代的烯基硫或烯基硒化合物提供了方便可靠的新方法；3、二碘化钐促进下的二硫醚、二硒醚与α，β-炔基酮和醛、酮的Michael—aldol串联反应，提供了一种一锅法高产率地制备多取代的含硫的烯丙基醇或含硒的烯丙基醇类化合物的方便可靠的原子经济性的新方法；4、烯丙基溴化钐与α，β-炔基酮的高度区域选择性的1，2-亲核加成反应；5、NiCl〓/PPh〓/Sm〓促进的卤代芳烃的偶联反应-一种从各种卤代芳烃制备联苯类化合物的有效方法。

Utilizing 6 and several kinds of diazides prepared in our lab, polys containing 1,2,3-triazolyl and perfluorocyclobutane units were synthesized by "Click chemistry". Utilizing the polycondensation reaction between 6 and several commercially available aromatic diphenol or copolymerization reaction after adding another active aromatic dichloride, fluorinated polys containing phenylphosphine oxide units were synthesized. Utilizing the polycondensation reaction between 6 and several commercially available aromatic dianhydride, fluorinated polys containing PPO units were synthesized.Secondly, structure characterization of fluorinated polys.

利用化合物6同各种自制的二叠氮化合物，通过&Click chemistry&，合成了具有1，2，3-三唑环结构单元的全氟环丁基类聚芳醚；利用化合物22同各种商业化的芳香二元酚类化合物进行缩聚反应或者再加入另外一种活性芳香二氯代物进行三元共聚反应，制备了具有苯基氧膦结构单元的含氟聚芳醚；通过化合物25同各种商业化的芳香二元酸酐类化合物进行缩聚反应，得到了具有PPO结构单元的含氟聚醚酰亚胺。

It was found that the thermodynamically unfavourable isomerization of quadracyclane to norbornadiene could be accomplished in the presence of toluene or durene as a co-sensitizer.

首次发现在甲苯、杜苯等芳烃共敏化下，可以使原来不能进行的、热力学不利的四环烷→降冰片二烯异构化得以进行，并根据CIDNP结果提出这是由于生成了敏化剂/底物/芳烃三元基激络合物使反应的势能面改变造成的并促进单线态的系间窜跃。

Pseudocumene, mesitylene, 1,2,3-trimethylbenzene and durene among theheavy aromatic hydrocarbon from catalytic reformation in oil refinery areimportant fine chemical materials, they have not only high additional value butalso particularly useful property, therefore, the exploiting and utilizing the sourceof the heavy aromatic hydrocarbon are of large commercial benefit and promisingapplication future.

炼油厂催化重整装置重芳烃中偏三甲苯、均三甲苯、连三甲苯、均四甲苯等都是精细化工的重要原料，不仅附加价值高，而且具有独特的优良性能。因此开发利用重芳烃资源具有较大的经济价值和广泛的应用前景。

In this paper, by analysis of reservoir characteristic, lithology, sedimental environment and geological feature of Putaohua oil layer in Fang 3 area Songfangtun oilfield, Songliao basin, the authors discuss reservoir characteristics and its influence factors. Feldspathic sandstone and detritus sandstone are the main type of reservoir which is lithology has siltstone, fine sandstone etc.

摘 要：通过对松辽盆地宋芳屯油田芳3区块葡萄花油层砂岩储层岩性、物性、沉积环境及地质特征的研究，对葡萄花油层砂岩储层的物性特征及其影响因素进行了系统的分析，认为长石砂岩和岩屑质长石砂岩是主要砂岩类型，岩性有粉、细砂岩等，但以粉砂岩为主。

Sweet is the breath of morn, her rising sweet, With charm of earliest Birds; pleasant the Sun When first on this delightful Land he spreads His orient Beams, on herb, tree, fruit, and flour, Glistring with dew; fragrant the fertil earth [ 645 ] After soft showers; and sweet the coming on Of grateful Eevning milde, then silent Night With this her solemn Bird and this fair Moon, And these the Gemms of Heav'n, her starrie train: But neither breath of Morn when she ascends [ 650 ] With charm of earliest Birds, nor rising Sun On this delightful land, nor herb, fruit, floure, Glistring with dew, nor fragrance after showers, Nor grateful Eevning mild, nor silent Night With this her solemn Bird, nor walk by Moon, [ 655 ] Or glittering Starr-light without thee is sweet.

同你谈话，我总是忘掉了时间，以及季节的转换，任何时刻都感到高兴：早晨呼吸清鲜空气，和早鸟一同歌唱，觉得舒畅；初升的太阳，在愉快的大地上，抛撒他那蔷薇色的光线，照耀着草、木、花、果，带露晶莹；细雨阵阵过后，丰腴的土地流芳；夕暮来临时心旷神怡，接踵而至的是沉静的夜，她有严肃的鸟儿、美丽的月亮和繁星，天上的宝石。但没有你时，一切都觉变了样：晨风不鲜，早鸟的歌唱不欢，尽管有太阳照耀大地，有草木花果的露珠晶莹，有雨后的流芳，愉悦的夕暮来临，沉静的夜也带来她那严肃的鸟儿，在月亮或亮晶晶的星光下散步，这一切，若没有你便没有快乐。

However, as the name（read－only memory）implies, CD disks cannot be written onorchanged in any way.

然而，正如其名字所指出的那样，CD盘不能写，也不能用任何方式改变其内容。

Galvanizes steel pallet is mainly export which suits standard packing of European Union, the North America. galvanizes steel pallet is suitable to heavy rack. Pallet surface can design plate type, corrugated and the gap form, satisfies the different requirements.

镀锌钢托盘多用于出口，替代木托盘，免薰蒸，符合欧盟、北美各国对出口货物包装材料的法令要求；喷涂钢托盘适用于重载上货架之用，托盘表面根据需要制作成平板状、波纹状及间隔形式，满足不同的使用要求。