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芳烃化合物

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In our research on study chemical reaction of active methylene compounds and brom-acetophenone. Because of brom-acetophenone is compound that contain carbonyl and halogen ,which will take place electrophilic substitution and nucleophilic addition. When active methylene compounds are ethyl acetoacetate and β-diketone, controlling reaction condition, we have found that mono-substitution's production and di-substitution's. production is isolated; active methylene compounds are acetoacetanilide and acetoacetanilide derivate, pyrrolidin-2-one derivants were obtained by substitution and close-ring reaction .but there is no report about it.

本文是让活泼亚甲基类化合物与溴代苯乙酮发生化学反应,由于溴代苯乙酮是含有羰基的卤代烃结构,它可以发生亲电取代和亲核加成反应,当活泼亚甲基类化合物为乙酰乙酸乙酯和β-二酮时,控制反应条件可以发生单取代和双取代两种产物;当活泼亚甲基类化合物为乙酰乙酰芳胺类化合物来反应时,溴代苯乙酮中的羰基与氨基会发生分子内的关环反应生成吡咯烷-2-酮衍生物,这在以前的研究中是没有发现的。

In one embodiment, the invention is a system for initiating free radical polymerization comprising: a in one part, one or more amido-borate compounds containing one or more anionic amido-borate moieties comprising an organoborate wherein the boron atom is bonded to a nitrogen atom of ammonia or an organic compound containing one or more nitrogen atoms, such as a hydrocarbyl amine, a hydrocarbyl polyamine, or an aromatic heterocycle containing one or more nitrogen atoms and optionally containing one or more heteroatoms or heteroatom containing functional moieties, and one or more cationic counter ions and b in a second part, a liberating compound which reacts with the nitrogen atom bound to the boron atom upon contact with the amido-borate to form an organoborane radical.

在一个实施方案中,本发明是引发自由基聚合的体系,包括:a在一个部分中,一种或多种含有一个或多个包含有机硼酸根的阴离子酰氨基-硼酸盐部分和一个或多个阳离子抗衡离子的酰氨基-硼酸盐化合物,其中的硼原子键合到氨的氮原子或含一个或多个氮原子的有机化合物,例如烃基胺、烃基聚胺或含一个或多个氮原子和任选含一个或多个杂原子或含杂原子的官能部分的芳族杂环的氮原子上,和b在第二部分中,在与酰氨基-硼酸盐接触时与键合到硼原子上的氮原子反应形成有机硼烷基团的释放化合物。

It provides a route tothe compounds which contains three functional groups, two carbon-nitrogentriple bonds and one carbon-carbon double bond. In water, metallic indiumpromotes carbon-sulfur bond coupling reaction of aromatic sulfonyl chloride withsuitable organic halides to afford sulfones. In the last chapter, metallic tin mediated allylation of aldimines with allylbromide was revealed.

第三章,我们研究了在水相介质中金属铟促进的烯丙基溴对1,1-二氰基-2-芳基乙烯的Michael加成反应,生成一个含碳碳双键和二个碳氮叁键的三官能团化合物,另外,金属铟在水介质中还可以促进芳基磺酰氯与卤代烃发生碳硫键的偶联,生成砜。

Polycyclic aromatic hydrocarbons are a well-known group of carcinogenic compounds widely distributed in the environment.

多环芳烃是众所周知的广布在环境中的一类致化合物。

It is determined that the contents and distribution of pyrrolic compounds and dibenzothiophene are controlled by oil fraction during migration, which has potential significance in evaluating the oil migration and reservoir Filling direction.

杂环芳烃中的吡咯类化合物和二苯并噻吩具有显著的油气运移分馏效应,可以作为有效的油气运移与油藏充注方向的分子级示踪参数。

The others of pentacyclic triterpanoids and their aromatized triterpanes are existed, but much lower in content than that in Xundian, Liaohu, Shulan brown coal resins.

结果显示,昭通树脂烃中D-环单芳藿烷及17β,21β-藿烷为含量最高的特征化合物,其它五环三萜及芳构化物质虽有分布,但量极低。

In the second chapter, twelve compounds constructed by arenedisulfonates and metal ions such as alkali, alkaline earth and transition metal ions have been synthesized and structurally characterized.

第二章描述了在水溶液条件下芳烃二磺酸根离子与碱金属离子、碱土金属离子和过渡金属离子形成的十二个化合物的结构。

That polyring aromatised hydrocarbons, dehydroabietic acid, other tricyclic diterpanoic acids and pentacyclic triterpanoic acids are not existed or in a much low amount in Zhaotong brown coal resin is distinguished from those resins isolated in Xundian, Liaohu, Shulan brown coal waxes in China.

稠环芳烃、松香酸、去氢松香等环状化合物含量很低或不存在,是昭通褐煤蜡与国内其它褐煤蜡组成的重大差别。

The rate constants and yields of aromatic halides containing substitute s with different electrophilicities were investigated.

三氟乙酸钠在以CuI为催化剂的条件下与卤代芳烃进行取代反应,生成相应的三氟甲基化合物。

Have carried on testing service for nearly 200 hazardous substances, including Asbestos, PAHs, Phthalates, NP/NPEO, AZO, CFC/HCFC/Halons, PVC, PCB, PCT, PCN, CP, Mirex, TPT/TBT/TBTO, Formaldehyde, Heavy metals, can help your products in fully compliance with 'green purchase' request of international buyers.

开展除RoHS以外的近200种有害物质检测业务,包括石棉、多环芳烃、邻苯二甲酸盐、壬基苯酚/壬基苯酚乙氧基化合物、偶氮染料、氟氯烷烃/氢氯氟烷烃/海龙、聚氯乙烯、多氯联苯、多氯三联苯、多氯化萘、短链氯化石蜡、灭蚊灵、三苯基锡类/三丁基锡类/二的氧化物、甲醛、重金属等,涉及范围完全满足各国际买家的&绿色采购&要求。

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