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The average relativeerror was 3.63%, less much than mostly used group-contribution methods for alkyne, chlorine derivative, iodine derivative, especially for alkane, bromine derivative, aromatic hydrocarbon, alicyclic hydrocarbon and sulfur-containing organic compounds.

对4068种有机物的正常沸点进行了估算,其平均相对误差为3.63%,总体估算精度明显优于相比较的基团贡献法,对炔烃、氯衍生物、碘衍生物,尤其是对烷烃类、溴衍生物、芳烃、脂环烃和含硫化合物的估算误差明显减小。

Some typical oxidation reactions of alkane ,olefin,and arene in supercritical CO2(scCO2)are introduced in this review.

介绍了有关烷烃、烯烃、芳烃化合物在超临界CO2介质中进行的氧化反应。

Aromatic A hydrocarbon derived from,or characterized by the presence of the benzene ring

芳烃 由苯环衍生出的、或因含有苯环而具有其特性的烃化物。

It is used to obtain saturated hydrocarbon and aromatic hydrocarbon before C9 through chromatographic analysis on reservoir samples with a temperature of 90℃.

该技术通过对储层样品进行90℃温度条件下的色谱分析得到C9以前的饱和烃及芳烃

Aromatic A hydrocarbon derived from,or characterized by thepresence of the benzene ring

芳烃 由苯环衍生出的、或因含有苯环而具有其特性的烃化物。

The develop-ment of ligands expands the scope of substrates, improves reaction selectivity and realizes the amination of the cheaper and available aryl chlorides. The application of weak base improves the compatibility of functional groups. Pd-catalyzed amination of aryl halides are used in the synthesis of arylamine.

配体的发展扩展了底物的适用范围,提高了反应的选择性,实现了廉价易得的氯代芳烃的胺化,弱碱的使用提高了官能团的兼容性,因此Pd催化芳胺化广泛应用于合成芳胺类化合物。

Chapter 2 presents our studies on aromatic amide-derived phosphine applied to room temperature Suzuki cross-coupling of unactivated aryl chlorides with aryl boronic acids.

第二章主要研究了芳基酰胺衍生的膦配体在不活泼的氯代芳烃同芳基硼酸在室温下的Suzuki偶联反应中的应用。

Results The two OHCB species in the defined consortia 22CO-6+PY97S and JZ9B+PY97S exhibited strong syntrophic effects in the oil biodegradation process. And the degradation rates of oil were increased from 27.81% and 83.52% to 64.03% and 86.89%, respectively. The consortia could degrade aliphatic and aromatic fraction at the same time, including high molecular weight-PAHs chrysene and its alkyl derivatives.

构建的降解菌群22CO-6+PY97S和JZ9B+PY97S中2种专性解烃菌具有明显的协同效应,它们可以使原油降解率从27.81%、83.52%分别提高到64.03%和86.89%,并且可以同时降解石油中的烷烃、芳香烃组分,包括高分子量多环芳烃chrysene及其衍生物。

0Mol%. The catalytic system combining Pd 〓, imidazolium salt and pyridine has been employed in the cross-coupling of unactive aryl chlorides with malononitrile.

对大多数溴代芳烃而言,无论芳环上取代基是吸电子的,还是给电子取代基,均可高产率地制备得到相应的α—芳基丙二腈化合物(产率>85%)。

Base played a crucial role in this reaction: in the Pd2/L1 catalyzed α-arylation of ethy malonate, K3PO4 is the base of choice; in the α-arylation of ethyl acetoacetate, K2CO3 is the most effectiv base.

在这类催化反应中,碱的选择具有重要的影响:以K3PO4为碱,Pd2/L1催化体系在丙二酸二乙酯的α-芳基化中,富电子溴代芳烃显示较好的活性;Pd2/L1催化的乙酰乙酸乙酯α-芳基化时,以K2CO3为碱,催化体系显示较好的活性,这个催化体系可控制反应得到α-芳基乙酰乙酸乙酯,而不是脱乙酰基的产物。

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