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芳基胺

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The results of UV absorption show that λ max is not sensitive to the electronic effects exerted by the substituent in the coupler moiety. The λ max has a small red-shift when the anilide aromatic ring in the coupler moiety is larger. This indicates that the conjugation effect of the anilide ring with chorosorb is not very significant. It is important to note that a red-shift of 60-130 nm was observed when the coupler component changed from a 2-hydroxy-3-naphthanilide to a 2hydroxy-11H-benzocarbazole-3-naphthanilide coupler. The red-shift may be due to the conjugation resulting from the carbazole ring.

对上述三个系列偶氮染料吸收光谱的研究结果表明,偶合基酰胺芳环共轭环的扩大对偶氮染料在可见光区最大吸收红移作用不是很显著;当偶合基萘环上共轭环扩大了一个咔唑环后,其偶氮染料在可见光区的最大吸收大幅红移,跨入近红外染料行列,这一结果对红外偶氮染料的设计合成具有重要的参照价值。

Some of yellow azo pigments have been synthesized by coupling of acetoacetarylide derivates with different substituted nitroaniline diazonium salts. The relationship between pigment structure and shade, m. p., and thermal stability, and the, effect of addition of surface active agent on coupling reaction product have been studied. TGA and differential thermal analysis in air of the pigments and the variance of visible spectra reflectance have also been determined.

以不同取代的硝基苯胺衍生物为重氮组分与乙酰基乙酰芳胺衍生物为偶合组分,合成数种黄色颜料,观察了不同表面活性剂对其偶合产物性能的影响;研究了颜料分子结构与色光、熔点及热稳定性之间的关系;测定了颜料热重曲线及加热试样对可见光反射性能的变化。

In our research on study chemical reaction of active methylene compounds and brom-acetophenone. Because of brom-acetophenone is compound that contain carbonyl and halogen ,which will take place electrophilic substitution and nucleophilic addition. When active methylene compounds are ethyl acetoacetate and β-diketone, controlling reaction condition, we have found that mono-substitution's production and di-substitution's. production is isolated; active methylene compounds are acetoacetanilide and acetoacetanilide derivate, pyrrolidin-2-one derivants were obtained by substitution and close-ring reaction .but there is no report about it.

本文是让活泼亚甲基类化合物与溴代苯乙酮发生化学反应,由于溴代苯乙酮是含有羰基的卤代烃结构,它可以发生亲电取代和亲核加成反应,当活泼亚甲基类化合物为乙酰乙酸乙酯和β-二酮时,控制反应条件可以发生单取代和双取代两种产物;当活泼亚甲基类化合物为乙酰乙酰芳胺类化合物来反应时,溴代苯乙酮中的羰基与氨基会发生分子内的关环反应生成吡咯烷-2-酮衍生物,这在以前的研究中是没有发现的。

Mannich reaction occurred directly between arylamine and pyrroli- zinone on hydrogen chloride/ethyl alcohol solution.

芳胺和吡里酮在氯化氢乙醇溶液中直接发生Mannich反应,但胺甲基化不是发生在羰基的α-位,而是发生在吡咯结构部分的5-位。

Objective To design and synthesize 7-anilino-3-cyano-5-alkylpyrazo [1, 5-a] pyrimidine derivatives and primarily evaluate their pharmacological activity.

目的 设计并合成7-芳胺基-3-氰基-5-烷基吡唑并[1,5-a]嘧啶类化合物,初步评价其药理活性。

Objective To design and synthesize 7-anilino-3-cyano-5-alkylpyrazolo[1,5-a]pyrimidine derivatives and primarily evaluate their pharmacological activity.

摘要目的设计并合成7-芳胺基-3-氰基-5-烷基吡唑并[1,5-a]嘧啶类化合物,初步评价其药理活性。

When the 3-keto glycosides was reduced by sodium borohydride, the D-allo configuration was considered the most probable since it has an equatorial arylamino group at C-2 position and reduction of the keto group was considerably less hindered to equatorial attack by borohydride ion to give an axial hydroxyl, than axial attack by borohydride to give an equatorial hydroxyl.

并对反应的立体化学问题进行了讨论,认为该反应的立体专一性是由于向下直立键上的1-位α-甲氧基和2-位向下平伏键上芳胺基大基团的共同影响,造成内侧进攻受阻,而使得氢负离子只能从外侧进攻的结果。

Myristic monoethanolamide ammonium sulfatewas synthesized from myristic acid and monoethanolamide with sulfamic acid as sulfating agent .

在芳烃类溶剂与羰基化合物催化剂存在下,以肉豆蔻酸和乙醇胺为原料,氨基磺酸作硫酸化剂,制备了肉豆蔻酸单乙醇酰胺硫酸酯铵盐。

This article reviews three kinds of methods for manufacture halogenated aromatic amine ,and the strong and weak points of the three reduction methods are pointed out.

本文综述了由卤代芳硝基物还原制备卤代芳胺的三种方法,并对几种还原方法的优缺点进行了对比和讨论,得出水合肼还原具有很好的应用前景。

These substituents are either small groups such as phenoxy groups,aryls,cyclic secondary amines,cyano groups,and halogens or large functional moieties such as PDI,Phthalocyanines, porphyrins,BODIPY,cyclodextrin,Fullerene,calixarene,and so on.

这在过去的工作中,人们把一些小分子的,如酚氧基、仲胺基、苯基、氰基以及卤素氟、氯、引入到PDI中,同时也把一些较大功能团,如PDI本身、卟啉、酞菁、环糊精、BODIPY、杯芳烃、富勒烯等和PDI连接在一起。

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