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It's found that the aromatic dinitro compounds can be monoreduced to nitroanilines in high selectivity, aromatic nitro compound s and muti.

本文旨在探索一种具有先进性和创造性的催化方法,利用一氧化碳在温和的条件下高选择性地还原芳香硝基化合物制备芳胺。

In order to study novel polyquinolines for their applications in the fields of electroluminescent devices and chemosensors, we synthesize polyquinolines containing phenylamine moiety for single-layer LEDs; moreover, we synthesize polyquinolines with different molecular structures to investigate their properties as fluorescent chemosensors.

本论文是以研究新型聚喹啉材料在电致发光和荧光传感器方面的应用为目的,将芳胺基元引入到聚喹啉主链上,以期使聚喹啉可用于单层电致发光器件中;同时通过合成不同分子结构的聚喹啉来考察其作为荧光传感器的性能和规律。

In order to study novel polyquinolines for their applications in the fields of electroluminescent devices and chemosensors, we synthesize polyquinolines containing phenylamine moiety for single-layer LEDs; moreover, we synthesize polyquinolines with different molecular structures to investigate their properties as fluorescent chemosensors.

中文题名聚喹啉的合成与表征副题名外文题名 Synthesis and characterization of novel polyquinolines 论文作者童辉导师王利祥学科专业高分子化学与物理研究领域\研究方向学位级别博士学位授予单位中国科学院长春应用化学研究所学位授予日期2002 论文页码总数152页关键词发光材料共轭聚合物荧光传感器电致发光聚合物聚喹啉馆藏号BSLW /2003 /O633 /17 本论文是以研究新型聚喹啉材料在电致发光和荧光传感器方面的应用为目的,将芳胺基元引入到聚喹啉主链上,以期使聚喹啉可用于单层电致发光器件中;同时通过合成不同分子结构的聚喹啉来考察其作为荧光传感器的性能和规律。

A triarylamine-based picolinic acid was synthesized through the Ullmann reaction and Negishi coupling reaction. Using this class of picolinic acid derivative as an auxiliary ligand and 1-phenylisoquinoline as a cyclometalated ligand, a cyclometalated iridium complex was also prepared.

通过Ullmann反应和Negishi偶联反应,合成了一种含三芳胺功能基的吡啶-2-甲酸衍生物;并以此为辅助配体、1-苯基异喹啉为环金属配体,设计合成了一种新型环金属铱配合物。

A triarylamine-based picolinic acid was synthesized through the Ullmann reaction and Negishi coupling reaction. Using this class of picolinic acid derivative as an auxiliary ligand and 1-phenylisoquino-line as a cyclometalated ligand, a cyclometalated iridium complex was also prepared.

通过Ullmann反应和Negishi偶联反应,合成了一种含三芳胺功能基的吡啶-2-甲酸衍生物;并以此为辅助配体、1-苯基异喹啉为环金属配体,设计合成了一种新型环金属铱配合物。

In the invention, normal reversible absorbing transfer material for solar energy which are mixture of cobalt chloride and sextic methyl tetramine, phthalandione lipid compound and trilateral methane lactone compound, said material are produced to micro cachet that colour changes as stemp, changing reversely in normal temp, then said micro cachet are compounded with common white silicate cement to produce the invention cement base material.

本发明采用对太阳能呈常温可逆吸收转换材料:氯化钴与六次甲基四胺混合物、邻苯二甲酸酯类化合物和三芳甲烷内酯类化合物,将上述材料制成微胶囊,再将所制出的常温可逆温致变色微胶囊与普通白色硅酸盐水泥复合,即可制备出常温可逆温致变色水泥基材料。

The intermediates 2a~2f of cyclic (1-arylseleno)glycerol phosphate and tegafur conjugates were synthesized by one-pot reaction of hexaethyl phosphorous triamide, activated by a catalytic amount of iodine, with (N3-tegafur)alkanol, 1-arylselenoglycerol and sulphur successively in refluxing benzene.

以碘作催化剂,无水苯为溶剂,六乙基亚磷酰三胺依次与羟乙基替加氟、1-芳硒基甘油及硫反应,得中间体硒代环甘油磷脂替加氟缀合物2a~2f。

Among the special nine pollutants, however, eight of them, including Hexachlorobenzene, N-Nitrosodi-N-propylamine, 3,3-dichlorobenzidine, 2,4,6-trichlorophenol, 2,3,4,5,6-pentachlorophenol, indeno (1,2,3-cd) pyrene, 4,4'-DDT and Heptachlor were in need of concern while another chemical: dibenzanthracene be of special concern. The sources of these chemicals were discussed and some control strategies were suggested based on the risk assessment.

结果表明,有18种有机污染物超过了USEPA的标准浓度要求,其中9种物质具有一定的生态风险,其中六氯苯、N-亚硝基二正丙胺、3,3'-二氯联苯胺、2,4,6-三氯酚、五氯酚、茚并(1,2,3-cd)芘、4,4'-滴滴涕、七氯在内的8种化合物具有一定的风险,而多环芳烃二苯并蒽需要引起更高警惕;在此基础上探讨了这些化合物的来源及作用,并提出了相应的防治建议。

We have studied a new aryloxypropanolamine derivative (PP-34) with more cardioselectivity and efficacy against ischaemia/reperfusion injury in rats.

我们研究了一种新的芳氧基丙醇胺衍生物(PP-34),在大鼠中具有更强的心脏选择性并对抗缺血/再灌注损伤更有效。

Using free radical 4-hydroxy-2,2,6,6-tetramethyl-1-piperidinyloxyl as catalyst, the phase transfer catalyzed method of oxidation of anilines to 15 symmetrical azobenzenes with a saturated solution of potassium ferricyanide in 2N aqueous potassium hydroxide and dichloromethane was described for the first time.

用2,2,6,6-四甲基-4-羟基-1-哌啶氮氧自由基为催化剂,芳胺类化合物在饱和铁氰化钾的氢氧化钾溶液和二氯甲烷的两相转移催化下合成了15 个对称取代偶氮苯。

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