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Moreover, the polymeric arsine palladium(0) complex is an efficient catalyst for the carbonyl allylation of aldehydes and the coupling reaction of aryl halides with terminal alkynes or Grignard reagent.

该聚合物负载的胂钯(0)配合物还是醛的羰基烯丙基化及芳基卤化物与端炔、Grignard试剂的交叉偶联反应的有效催化剂。

In the IUPAC system, alkyl and aryl substituents and many functional groups are named as prefixes on the parent.

在系统命名法中,烷基、芳基取代基和许多官能团被命名为前缀并放在一个母体的前面

New compounds of the type of N--N'-(2,4-dichlorophenyloxyacetyl)-semicarbazides were synthesized by a series of reactions of preparing organic isocyanates by Curtius rearrangement with 2,4- dichloro aryloxyacetic acid hydrazide using one-pot procedures.

以芳香取代酸为原料,用Curtius重排的方法合成异氰酸酯,直接与2,4-二氯苯氧乙酰肼作用,一锅法合成了4种N-取代芳基-N'-(2,4-二氯苯氧乙酰基)氨基脲类化合物。

Nitrations of both hydroxyl- and acetamino-substituted porphyrins were found to take place at the adjacent position of the substituent in the very aryl ring, whereas nitro group was guided into para positions of unsubstituted phenyl ring during the nitration of nitro-substituted porphyrin.

结果表明,羟基和乙酰氨基卟啉的硝化反应发生在与该取代基处于同一芳环的meta位,而硝基卟啉进行硝化时,硝基取代于其他未取代苯环的para位。

Analytical results showed that the upper clear liquid of pyrolysis oils was mainly consisted of water-soluble substances,such as phenol,cresol,xylenol,sugars,hydantoins,morpholines,pyranones and pyridine derivatives compounds,etc.,while the lower sediment was mainly insoluble or hardly water-soluble substances,such as the big substituent phenolics(the number of substituent carbon atoms of which is greater than or equal to 2),aryl phosphate esters,fatty acid esters and nitrile compounds,and so on.

研究表明,热解油上层清液主要是一些较易溶于水的物质,如苯酚、甲酚、二甲酚、糖类、乙内酰脲类、吗啉类、吡喃酮类和吡啶类化合物等;而下层沉淀则主要为不溶或难溶于水的物质,如大取代基酚类(取代基碳原子数≥2)、磷酸三芳基酯类、脂肪酸酯类和腈类化合物等。

In this dissertation, after combining the high stability of C9 diaryl substituted fluorene derivatives with the high carrier mobility and hole-injection ability of pyrene, a series of novel blue-light-emitting materials were designed and synthesized.

在本论文中,将9位双芳基芴结构的高稳定性能和稠环芳烃芘的高载流子迁移率、空穴注入能力结合起来,设计、合成了一系列新型蓝光材料,并研究了它们的光电性能。

In the presence of catalytic rhodium acetate, ethyl 2-diazo-3-oxo-per fluoroalkanoates, reacted readily with nitriles to give a series of 5-fluoroalkyl substituted 1, 3oxazoles with high regio-selectivity through a metal carbenoid intermediate. The reactions of carbenoids with noncyclic vinyl ethers or cyclic vinyl ethers afforded dihydrofuroates in good to excellent yields. Interestingly, only vinyl C-H insertion compound was obtained concerning of the reaction of carbenoids with 2, 5dimethylfuran due to the steric hindrance of methyl group

醋酸铑分解2-重氮-3-氧代-全氟羧酸乙酯形成的金属卡宾作为1,3-偶极体,可以与一系列芳基或烷基取代的腈反应,高度区域选择性地生成一系列4-乙氧羰基-5-氟烷基取代的噁唑化合物;也可以与富电子的链状和环状的烯基醚反应,以优良的产率得到一系列氟烷基取代的二氢呋喃类化合物;而与2,5-二甲基呋喃的反应,由于甲基的位阻作用,只得到金属卡宾对呋喃3-位烯基碳氢键插入产物。

From the photophysical behaviors of 1, 3, 4-triaryl-2pyrazoline compound (TPP16) at low temperature, it can be considered that the twisted configuration between pyrazoline ring and the non-substituted phenyl group on the position 1 is the fluorescence configuration of conjugated system Ⅰ, and the twisted configuration between pyrazoline ring and P-nitrobenzene group is fluorescence configuration of conjugated system Ⅱ.

研究了1,3,4-三芳基-2-吡唑啉化合物TPP16在低温时的发光情况,发现:在低温77K下,共轭体系Ⅰ(苯基-N1-N2=C3-苯基)在非极性溶剂中不发荧光,在极性溶剂中有较强荧光发射;而共轭体系Ⅱ(N1-N2=C3-C4=对硝基苄叉)在非极性溶剂或极性溶剂中均有荧光发射,表明N1所联取代基与吡唑啉环相扭曲的构象是共轭体系Ⅰ的发光构象,而对硝基苄叉与吡唑啉环相扭曲的构象是共轭体系Ⅱ的发光构象。

This article reviews three kinds of methods for manufacture halogenated aromatic amine ,and the strong and weak points of the three reduction methods are pointed out.

本文综述了由卤代芳硝基物还原制备卤代芳胺的三种方法,并对几种还原方法的优缺点进行了对比和讨论,得出水合肼还原具有很好的应用前景。

In the presence of Pd_2, NaOMe, and EtOH, a variety of aryl iodides and aryl bromides were coupled with arylboronic acids smoothly in very short time.

Pd_2作为催化剂,NaOMe作为碱,EtOH作为溶剂,一系列的碘代和溴代芳烃都能在极短的时间内与芳基硼酸反应得到相应的交叉偶联产物。

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然而,正如其名字所指出的那样,CD盘不能写,也不能用任何方式改变其内容。

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