芳基的

In this study, the electrical conductive composites (comprised of thermoplastic matrix resins-high density polyethylene, polyphenylene sulfide and polyarylethersuifone with cardo group, and conductive fillers-short carbon fiber, carhon black and graphite) are prepared and characterized in detail. The relation among composite structure and directalternating electric properties, some electric and magnetic parameters under X-band microwave and shielding effect, the mechanical behaviour are analysed. And furthermore, some relative experimental devices are developed.

本工作利用短切碳纤维、炭黑、石墨为导电填料填充热塑性树脂高密度聚乙烯、聚苯硫醚、酚酞型聚芳醚砜，制得具有良好导电性能和机械性能的导电性高分子复合材料，并以此为对象，研究了材料的稳恒电场和交变电场的基本特性与材料结构的关系，研究了在X波段微波场下的电磁参量及屏蔽效应，以及研究了复合材料及其基体树脂的力学行为，与此同时还建立了相应的表征测试手段。

A catalyst composition for the polymerization of propylene comprising one or more Ziegler-Natta procatalyst compositions comprising one or more transition metal compounds and one or more esters of aromatic dicarboxylic acid internal electron donors; one or more aluminum containing cocatalysts; a selectivity control agent comprising at least one silicon containing compound containing at least one C1-10 alkoxy group bonded to a silicon atom, and one or more activity limiting agent compounds comprising one or more aliphatic or cycloaliphatic carboxylic acids; alkyl-, cycloalkyl- or alkyl-ester derivatives thereof; or inertly substituted derivatives of the foregoing.

一种用于丙烯聚合的催化剂组合物，所述催化剂组合物包括：一种或多种齐格勒-纳塔主催化剂组合物，该主催化剂组合物包括一种或多种过渡金属化合物和一种或多种芳族二羧酸酯内部电子给体；一种或多种包含铝的助催化剂；选择性控制剂，该选择性控制剂包括至少一种包含硅的化合物，该化合物包括至少一种与硅原子连接的C 1-10 烷氧基；和一种或多种活性限制剂化合物，该活性限制剂包括一种或多种脂族或脂环族的单或聚羧酸类、其烷基-、环烷基-或烷基-衍生物、或上述惰性取代的衍生物。

A series of antimony mercaptide compounds which formula are Sb 〓 and Sb S (CH〓〓COOR 〓(R represents an alkyl or aryl, aralkyl, n=0～2) have been synthesized. A new synthetic method has been invented to solve the defect of abroad patent method which has complex technological conditions and singleness intermediate compounds. A new catalyst QL-1 and preactivated antimony trioxide and other means have been used to avoid neutralizing, washing, separating and other procedures of intermediate and simplifing process flow at the same time. According to this new technique, a series of antimony mercaptides and their intermediate products have been synthesized with high yield.

合成了结构为SbS(CH〓〓COOR〓及Sb〓（R为烃基或芳烷基，n=0～2）的一系列硫醇锑化合物，针对国外专利报道的合成工艺存在着工艺条件苛刻，同时需多步完成，操作复杂，而且中间体品种单一的缺陷，发明了一种一步法合成硫醇锑化合物的新工艺，采用QL-1催化剂，且将三氧化二锑预先活化，变固—液相反应为液—液相反应，同时可免除中间体的中和、洗涤、分离等工序，工艺流程简化，产品收率高，且能制得系列硫醇锑产品。

In this dissertation, I will represent my studies on the nitration of Chalcone derivatives, reaction of epoxide ketone, and the aromatization of 3,5-disubstitued 2-isoxazolines with nitric oxide.

本文主要研究了：(1)NO与查尔酮及其衍生物的硝化反应，反应以较高的产率得到了a-硝基化合物；(2)NO对环氧酮的开环反应，反应生成了顺式羟基硝酸酯；(3)3，5-二取代的-2-异恶唑啉在NO作用下可以发生芳环化反应，生成了对应的2-异恶唑化合物。

The cage effect of Gn potassium aqueous solution calculated by theα-cleavage photoreaction product distribution of substituted dibenzyl ketone was 14%, 18%, 22% and 42% for generations 1-4, respectively, which indicates that G4 takes a more close spherical shape with strong confine ability.

研究结果表明，羧基为末端基团的芳醚树枝形聚合物Gn (n = 1-4)钾盐水溶液笼效应随代数增加而增大，从G1到G4，笼效应分别为14%、18%、22%和42%，树枝形聚合物3代到4代从开放结构变为近乎球形的封闭结构的显著变化使G4表现出明显高于其他三代的笼效应。

In order to study novel polyquinolines for their applications in the fields of electroluminescent devices and chemosensors, we synthesize polyquinolines containing phenylamine moiety for single-layer LEDs; moreover, we synthesize polyquinolines with different molecular structures to investigate their properties as fluorescent chemosensors.

中文题名聚喹啉的合成与表征副题名外文题名 Synthesis and characterization of novel polyquinolines 论文作者童辉导师王利祥学科专业高分子化学与物理研究领域\研究方向学位级别博士学位授予单位中国科学院长春应用化学研究所学位授予日期2002 论文页码总数152页关键词发光材料共轭聚合物荧光传感器电致发光聚合物聚喹啉馆藏号BSLW /2003 /O633 /17 本论文是以研究新型聚喹啉材料在电致发光和荧光传感器方面的应用为目的，将芳胺基元引入到聚喹啉主链上，以期使聚喹啉可用于单层电致发光器件中；同时通过合成不同分子结构的聚喹啉来考察其作为荧光传感器的性能和规律。

Low valent selenium and telluronium compounds have high reducing selectivity to be used to form carbon-hydrogen bonds as special reducing reagents.

低价硒、碲化合物具有良好的还原选择性，可用于多种碳-氢键的形成，碲叶立德和α-芳硒基取代的胂叶立德均可发生Wittig型反应，是形成碳-碳双键的重要方法。

Low valent selenium and telluronium compounds have high reducing selectivity to be used to form carbon-hydrogen bonds as special reducing reagents.

低价硒、碲化合物具有良好的还原选择性，可用於多种碳-氢键的形成，碲叶立德和α-芳硒基取代的胂叶立德均可发生Wittig型反应，是形成碳-碳双键的重要方法。

The application, proposed hydrotalcite-like compounds as a new type of environmentally friendly solid catalysts in the aldol condensation, nitrile hydrolysis, epoxide ring-opening reaction of the oxidation of aromatic compounds, alcohols oxidation, reduction of nitro compounds, and many other important reactions in organic synthesis has an important application potential, and with little pollution compared to conventional catalysts, easy separation of advantages of high reactivity.

叙述了水滑石类化合物作为固体酸碱催化剂、氧化还原反应催化剂、催化剂载体等方面的应用情况，提出了水滑石类化合物作为一类新型的环境友好的固体催化剂，在醇醛缩合、腈类水解、环氧化物的开环反应、芳烃类化合物的氧化、醇类氧化、硝基化合物的还原等许多重要的有机合成反应具有重要的应用前景，并且与传统催化剂相比具有污染小、易分离、反应活性高等优点。

Among the special nine pollutants, however, eight of them, including Hexachlorobenzene, N-Nitrosodi-N-propylamine, 3,3-dichlorobenzidine, 2,4,6-trichlorophenol, 2,3,4,5,6-pentachlorophenol, indeno (1,2,3-cd) pyrene, 4,4'-DDT and Heptachlor were in need of concern while another chemical: dibenzanthracene be of special concern. The sources of these chemicals were discussed and some control strategies were suggested based on the risk assessment.

结果表明，有18种有机污染物超过了USEPA的标准浓度要求，其中9种物质具有一定的生态风险，其中六氯苯、N-亚硝基二正丙胺、3，3'-二氯联苯胺、2，4，6-三氯酚、五氯酚、茚并(1，2，3-cd)芘、4，4'-滴滴涕、七氯在内的8种化合物具有一定的风险，而多环芳烃二苯并蒽需要引起更高警惕；在此基础上探讨了这些化合物的来源及作用，并提出了相应的防治建议。

Breath, muscle contraction of the buttocks; arch body, as far as possible to hold his head, right leg straight towards the ceiling (peg-leg knee in order to avoid muscle tension).

呼气，收缩臀部肌肉；拱起身体，尽量抬起头来，右腿伸直朝向天花板（膝微屈，以避免肌肉紧张）。

The cost of moving grain food products was unchanged from May, but year over year are up 8%.

粮食产品的运输费用与5月份相比没有变化，但却比去年同期高8％。